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Fabrication of Modified MXene and Its Application to Air-Cell Electrode

Research Project

Project/Area Number 16K14390
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionKyushu University

Principal Investigator

Hayashi Katsuro  九州大学, 工学研究院, 教授 (90397034)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsメクセン / ナノシート / 電気化学 / 窒化 / ドーピング / 炭素材料 / マキシン / シート状化合物 / MXene / 炭化物 / 電子顕微鏡 / 酸素還元
Outline of Final Research Achievements

W-doped MXene nanosheet has been prepared from W-doped MAX precursors by the selective etching. It is elucidated that doped W preferably occupies the Ti site that is exposed to the surface when converted to MXene. Formation of titanium carbonitride with a lamellar structure by heating MXene in nitrogen atmosphere has been investigated. It is elucidated that the lamellar titanium carbonitride is formed via the three steps reactions including: desorption of the surface functional groups; transformation of MXene into titanium carbonitride; and its recrystallization. Sulfur-carbon compound with amorphous structure has been synthesized by selective extraction of titanium from Ti2SC MAX and applied to a cathode of Na-ion battery.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 Other

All Int'l Joint Research (1 results) Presentation (14 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results)

  • [Int'l Joint Research] KMUST(中国)

    • Related Report
      2017 Annual Research Report
  • [Presentation] シート状化合物 Ti3C2Tx を前駆体とした特異構造を有する窒化チタンの作製2018

    • Author(s)
      西見 和真, 長谷川 丈二, 赤松 寛文, 林 克郎
    • Organizer
      第56回セラミックス基礎科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属炭化物ナノシートMXeneへの遷移金属元素ドーピング2017

    • Author(s)
      嶋 一成, 長谷川 丈二, 稲田 幹, 榎本 尚也, 林 克郎
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      日本大学駿河台キャンパス(東京都千代田区)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Research-status Report
  • [Presentation] Transition metal doping into Ti3AlC2 to fabricate new composition transition metal carbide nanosheet with anionic Functional groups2017

    • Author(s)
      Kazunari SHIMA,Kei KAWAHARA,Kazuma NISHIMI,George HASEGAWA,Miki INADA,Katsuro HAYASHI
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design(ISEPD2017)
    • Place of Presentation
      沖縄自治会館(沖縄県那覇市)
    • Year and Date
      2017-02-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Transition metal(Cr,Mn,and Fe)doping intoTi3AlC2 to fabricate doped-Mxene2017

    • Author(s)
      K.Shima,K.Kawahara,M.Inada,N.Enomoto,K.Hatyashi
    • Organizer
      41st International Conference and Expo on Advanced Ceramics and Composites
    • Place of Presentation
      Hilton Daytona Beach and Oceancenter
    • Year and Date
      2017-01-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水熱炭化カーボンスフィアのマイクロ-メソ-マクロ孔制御とキャパシタ特性2017

    • Author(s)
      岡崎 亮太, 稲田 幹, 長谷川 丈二, 榎本 尚也, 林 克郎
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター(岡山県岡山市)
    • Year and Date
      2017-01-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Transition metal doping into Ti3AlC2 to fabricate new composition transition metal carbide nanosheet with anionic Functional groups2017

    • Author(s)
      Kazunari Shima, Kei Kawahara, Kazuma NISHIMI, George Hasegawa, Miki Inada, Katsuro Hayashi
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design(ISEPD2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MAX相化合物を前駆体とした硫黄/炭素複合材料の合成およびNaイオン電池における充放電挙動の評価2017

    • Author(s)
      河原 圭, 稲田 幹, 長谷川 丈二, 榎本 尚也, 林 克郎
    • Organizer
      第55回セラミックス基礎科学討論会
    • Related Report
      2017 Annual Research Report 2016 Research-status Report
  • [Presentation] Transition metal(Cr,Mn,and Fe)doping into Ti3AlC2 to fabricate doped-Mxene2017

    • Author(s)
      K. Shima, K. Kawahara, M. Inada, N. Enomoto, K. Hatyashi
    • Organizer
      41st International Conference and Expo on Advanced Ceramics and Composites
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Transition metal doping into Ti3AlC2 to fabricate new composition transition metal carbide nanosheet with anionic Functional groups2017

    • Author(s)
      Kazunari SHIMA, Kei KAWAHARA, Kazuma NISHIMI, George HASEGAWA, Miki INADA, Katsuro HAYASHI
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design(ISEPD2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属炭化物ナノシートMXeneへの遷移金属元素ドーピング2017

    • Author(s)
      嶋 一成,長谷川 丈二,稲田 幹,榎本 尚也、林 克郎
    • Organizer
      日本セラミックス協会 2017年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 表面官能基制御を目指したMXeneへの遷移金属元素ドーピング2017

    • Author(s)
      嶋 一成,長谷川 丈二,稲田 幹,赤松 寛文、林 克郎
    • Organizer
      複合アニオンキックオフミーティング(2017年5月)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ti3C2 MXeneの昇温脱離挙動と新規窒化物材料の生成2017

    • Author(s)
      西見 和真, 長谷川 丈二, 稲田 幹, 赤松 寛文, 林 克郎
    • Organizer
      複合アニオンキックオフミーティング(2017年5月)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属炭化物ナノシートMXeneへの遷移金属ドーピングと表面官能基制御2017

    • Author(s)
      嶋 一成,長谷川 丈二,稲田 幹,赤松 寛文、林 克郎
    • Organizer
      複合アニオントピカル会議(2017年8月)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] W をドープした Ti3AlC2の作製と金属炭化物ナノシートへの転換2017

    • Author(s)
      嶋 一成,長谷川 丈二,稲田 幹,赤松 寛文、林 克郎
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2019-03-29  

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