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Improvement of performance of oxidation resitance of Al2O3 scale by microstructual control

Research Project

Project/Area Number 16K14436
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Material processing/Microstructural control engineering
Research InstitutionHokkaido University (2017-2018)
Tokyo Institute of Technology (2016)

Principal Investigator

Hayashi Shigenari  北海道大学, 工学研究院, 准教授 (10321960)

Co-Investigator(Kenkyū-buntansha) 米田 鈴枝  地方独立行政法人北海道立総合研究機構, 産業技術研究本部工業試験場, 研究職員 (30806005)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsアルミナスケール / 組織制御 / 活性元素 / 結晶粒粗大化 / 高温酸化 / 耐熱合金 / 酸化スケールの組織制御 / 保護性アルミナ皮膜 / 内部酸化 / 相変態
Outline of Final Research Achievements

The effect of Al, Cr and Reactive elements(REs) on the microstructure of alumina scale was investigated in order to enhance the oxidation resistance of an alumina scale by microstructure control.
The grain size of alumina scale became smaller with higher Al and Cr contents in alloys. The effect of those elements on the grain size of alumina is attributed to an increase of rate of nucleation due to higher supersaturation of alumina in the subsurface region. RE addition was also found to decrease the grain size of alumina. It was found that RE, which is segregated at grain boundaries of alumina suppresses the grain coarsening during high-temperature oxidation.
In order to form the alumina scale with lower growth rate, it is proposed that the alloys must have proper composition which allows to form the coarse alumina grains from the very initial oxidation.

Academic Significance and Societal Importance of the Research Achievements

耐熱合金を高温過酷環境下から守るためにはアルミナやクロミア等の保護性酸化スケールが必要である。これまでの耐熱合金の耐酸化性向上に関する合金設計は、酸化スケールを早期に形成し、それを長時間安定に維持させることに主眼が置かれていた。
本研究成果は、アルミナスケールの耐酸化性に関する特性を向上させるためにはその組織を制御することが必要であることを示すとともに、合金元素がアルミナスケールの組織に及ぼす影響を材料学的に明らかにした。高温酸化で形成する酸化スケールの特性向上に組織制御を提案した本成果は学術的に高い意義を持つ。本成果は耐熱合金の設計にも直接繋がることから、高温材料分野に対する貢献度は高い。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (9 results)

All 2019 2018 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results)

  • [Journal Article] The Transition from Transient Oxide to Protective Al2O3 Scale on Fe-Cr-Al Alloys during Heating to 1000°C2017

    • Author(s)
      Suzue Yoneda, Shigenari Hayashi, and Shigeharu Ukai
    • Journal Title

      Oxidation of Metals

      Volume: アクセプト

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Factors affecting the microstructure of therally grown Al2O3 scale2019

    • Author(s)
      Shigenari Hayashi
    • Organizer
      Gordon research conference High temperature corrosion
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 放射光を用いたin-situ高温X線回折の高温酸化研究への適用2018

    • Author(s)
      林 重成
    • Organizer
      日本金属学会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] アルミナ皮膜の組織に及ぼすZr添加の影響2018

    • Author(s)
      前田 透真、林重成、鵜飼重治
    • Organizer
      日本金属学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] FeCrAl合金の遷移酸化挙動に及ぼすZrの影響2018

    • Author(s)
      前田 透真、林重成、鵜飼重治
    • Organizer
      日本金属学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Effect of Zr Additon on Mictrostructual Development of Alumina Scale Formed on FeCrAl Alloys2018

    • Author(s)
      Toma Maeda, Shigenari Hayashi, Shigeharu Ukai
    • Organizer
      International Symposium on High-Temperature Oxidation and Corrosion 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アルミナ皮膜の組織に及ぼすZr添加の影響2018

    • Author(s)
      前田透真、米田鈴枝、林 重成
    • Organizer
      日本金属学会春期講演大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 放射光を用いたin-situ高温X線回折の高温酸化研究への適用2018

    • Author(s)
      林 重成
    • Organizer
      日本金属学会春期講演大会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Fe-Cr-Al合金上の保護性アルミナ皮膜の成長と初期酸化挙動の関係2016

    • Author(s)
      米田鈴枝, 林重成,鵜飼重治
    • Organizer
      日本金属学会 秋季講演大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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