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Development of fine wire for mass production to achieve the precision of less than 1 nm

Research Project

Project/Area Number 16K14439
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Material processing/Microstructural control engineering
Research InstitutionNational Institutes for Quantum and Radiological Science and Technology (2017-2019)
Osaka University (2016)

Principal Investigator

Yamamoto Hiroki  国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 主幹研究員(定常) (00516958)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords材料・加工 / 半導体微細化 / ナノ加工 / ナノ材料 / 材料加工・処理 / 自己組織化 / 半導体超微細化 / 表面・界面物性
Outline of Final Research Achievements

In order to realize mass production of semiconductor device, fine wire with less than 10 nm is required to achieve with the precision of less than 1 nm and less exposure dose. In this study, uniform and ultra fine metal particles were synthesized in organic solvent and solution using gamma ray or chemical reduction. Their size were uniform and less than 10 nm and they were used as building blocks. Also, the controlled array of metal nanoparticles such as gold or silver on the resulting water-soluble dithiol self-assembled monolayer (SAM) nanopatterns such as line and space and dots was successfully obtained. Moreover, the aggregation process of metal nanoparticles in solid polymer thin films was investigated using atomic force microscope and scanning electron microscope. From these studies, the knowledge for realization of fine wire with less than 10 nm for mass production was obtained.

Academic Significance and Societal Importance of the Research Achievements

本研究は固体表面や界面および、固体ポリマー薄膜中での金属アグリゲーションの現象を解明する点で、学術的に高い意義がある。本研究の精度1 nm以下の量産細線技術の開発で得られた研究成果は、最先端の半導体リソグラフィでも現在のところ開発の糸口さえ掴めていない11 nm以下の加工を1nm以下の精度で行うことができる新しい微細加工技術および微細加工材料の開発につながり、将来のナノテクノロジーあるいはナノサイエンスの産業応用の実現に繋がるナノ配線のような新規微細加工技術として期待される。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (23 results)

All 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (5 results) Journal Article (5 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results)

  • [Int'l Joint Research] Université Paris-Sud/CNRS(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Birmingham(英国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Université Paris-Sud/CNRS(フランス)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Université Paris-Sud/CNRS(France)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Université Paris-Sud(France)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Lamellar Orientation of a Block Copolymer via an Electron-Beam Induced Polarity Switch in a Nitrophenyl Self-Assembled Monolayer or Si Etching Treatments2020

    • Author(s)
      Yamamoto Hiroki、Dawson Guy、Kozawa Takahiro、Robinson Alex P. G.
    • Journal Title

      Quantum Beam Science

      Volume: 4 Issue: 2 Pages: 1-10

    • DOI

      10.3390/qubs4020019

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Role of Metal Sensitizers for Sensitivity Improvement in EUV Chemically Amplified Resist2018

    • Author(s)
      Hiroki Yamamoto, Yannick Vesters Jing Jiang Danilo De Simone Geert Vandenberghe
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 31 Issue: 6 Pages: 747-751

    • DOI

      10.2494/photopolymer.31.747

    • NAID

      130007603657

    • ISSN
      0914-9244, 1349-6336
    • Year and Date
      2018-12-15
    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sensitizers in extreme ultraviolet chemically amplified resist: mechanism of sensitivity improvement2018

    • Author(s)
      Yannick Vesters Jing Jiang, Hiroki Yamamoto Danilo De Simone Takahiro Kozawa Stefan De Gendt Geert Vandenberghe
    • Journal Title

      J. Micro/Nanolith. MEMS. MOEMS

      Volume: 17 Issue: 04 Pages: 1-1

    • DOI

      10.1117/1.jmm.17.4.043506

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Study on Resist Performance of Noria Derivatives Modified with Various Protection Ratios of Acetal Moieties by means of Extreme Ultraviolet Irradiation2017

    • Author(s)
      H. Yamamoto, H. Kudo, and T. Kozawa
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 30 Issue: 6 Pages: 627-631

    • DOI

      10.2494/photopolymer.30.627

    • NAID

      130006309146

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Metal Nanoparticles and Patterning in Polymeric Films Induced by Electron Nanobeam2017

    • Author(s)
      Hiroki Yamamoto, Takahiro Kozawa, Seiichi Tagawa, Muneyuki Naito, Jean-Louis. Marignier, Mehran Mostafavi, and Jacqueline Belloni
    • Journal Title

      J. Phys. Chem. C

      Volume: 121 Issue: 9 Pages: 5335-5340

    • DOI

      10.1021/acs.jpcc.6b12543

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 電子線誘起による自己組織化単分子膜の極性変化を用いた ブロック共重合体のラメラ方向制御2019

    • Author(s)
      山本 洋揮
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 自己組織化単分子膜の極性変化を用いたポリスチレン-ポリメチルメタクリレート ブロック共重合体のラメラ配向2019

    • Author(s)
      山本 洋揮
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 電子線誘起による高分子薄膜における金属ナノ粒子の合成と パターニングに関する研究2019

    • Author(s)
      山本 洋揮、古澤孝弘、 田川精一、マリグリナージャンルイ 、モスタファビメラン、ジャックリンベローニ
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Role of Metal Sensitizers for Sensitivity Improvement in EUV Chemically Amplified Resist2018

    • Author(s)
      Hiroki Yamamoto, Yannick Vesters Jing Jiang Danilo De Simone Geert Vandenberghe
    • Organizer
      The 35th International Conference of Photopolymer Science and Technology
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 電子線誘起による高分子薄膜における金属ナノ粒子の合成とパター ニングに関する研究2018

    • Author(s)
      山本 洋揮、古澤孝弘、 田川精一、マリグリナージャンルイ 、モスタファビメラン、ジャックリンベローニ
    • Organizer
      次世代リソグラフィワークショップ2018
    • Related Report
      2018 Research-status Report
  • [Presentation] 放射線化学によるポリマーフィルムへの金属ナノパターン形成2018

    • Author(s)
      山本洋揮
    • Organizer
      第61回放射線化学討論会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Synthesis of Metal Nanoparticle and Patterning in Polymeric Films Induced by Electron Beam2018

    • Author(s)
      Hiroki Yamamoto, Takahiro Kozawa, Seiichi Tagawa, Jean-Louis Marignier, Mehran Mostafavi, and Jacqueline Belloni
    • Organizer
      SPIE Advanced Lithography 2018
    • Related Report
      2017 Research-status Report
  • [Presentation] Study on Resist Performance of Noria Derivatives Modified with Various Protection Ratios of Acetal Moieties by means of Extreme Ultraviolet Irradiation2017

    • Author(s)
      Hiroki Yamamoto, Hiroto Kudo, and Takahiro Kozawa
    • Organizer
      The 34th International Conference of Photopolymer Science and Technology
    • Related Report
      2017 Research-status Report
  • [Presentation] トップダウン・ボトムアップ技術の融合による金属ナノ粒子の位置制御2017

    • Author(s)
      山本洋揮、大沼明、大谷文章、古澤孝弘
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Nanofabrication method for two dimensional controlled array of core-shell nanoparticles in large scale fabrication by using self-assembled Au@SiO2 nanoparticle in solvent intaerface2017

    • Author(s)
      H.Yamamoto, A. Lehoux, B. Ohtani, T. Kozawa
    • Organizer
      The 43rd International Conference on Micro and Nanoengineering
    • Related Report
      2017 Research-status Report
  • [Presentation] Synthesis of Metal Nanoparticles and Patterning in Polymeric Films Induced by Electron Nanobeam2017

    • Author(s)
      Hiroki Yamamoto, Takahiro Kozawa, Seiichi Tagawa, Jean-Louis Marignier, Mehran Mostafavi, and Jacqueline Belloni
    • Organizer
      The 30th Miller Conference on Radiation Chemistry
    • Related Report
      2017 Research-status Report
  • [Presentation] Fabrication of High Aspect Ratio Nanostructure by Using ClF3-Ar Neutral Cluster Etching2016

    • Author(s)
      Hiroki Yamamoto, Toshio Seki, Jiro Matsuo, Kunihiko Koike, Takahiro Kozawa
    • Organizer
      38th International Symposium on Dry Process
    • Place of Presentation
      Hokkaido, Japan
    • Year and Date
      2016-11-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Study on Resist Performance of Noria Derivatives Modified with Various Protection Ratios of Acetal Moieties for EUV lithography2016

    • Author(s)
      Hiroki Yamamoto, Hiroto Kudo, and Takahiro kozawa
    • Organizer
      2016 International Symposium on Extreme Ultraviolet Lithography
    • Place of Presentation
      Hiroshima, Japan
    • Year and Date
      2016-10-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2021-02-19  

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