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Development of novel biosorption based on design of cell surfaces for separation of rare earths

Research Project

Project/Area Number 16K14462
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKyushu University

Principal Investigator

GOTO MASAHIRO  九州大学, 工学研究院, 教授 (10211921)

Research Collaborator KUBOTA FUKIKO  九州大学, 工学研究院, 助教
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsレアメタル / 希土類 / リサイクル / バイオソープション / イオン交換 / 吸着樹脂 / バイオ吸着 / 金属分離 / 吸着剤 / メタルリサイクル / 都市鉱山 / 希土類分離 / 金ナノ粒子 / 生物吸着 / 分離工学 / 細胞吸着 / 大腸菌 / 分子認識
Outline of Final Research Achievements

Biosorption has recently attracted much attention as an alternative to conventional techniques for the recovery of rare earth elements (REEs). In this study, the surface of Escherichia coli (E. coli) was chemically modified to improve its performance as a biosorbent for REEs. The diglycolic amic acid group, which shows high affinity to REEs, was introduced by succinylation of the amine groups on the surface of the E. coli. Adsorption curves using the chemically modified E. coli were characteristic of the diglycolic amic acid group. The adsorption performance for transition metal ions was not affected by the chemical modification. These results suggest that modification of E. coli with a functional group with high affinity to REEs increases the effectiveness of adsorption. The maximum uptakes of REEs on the modified E. coli were increased to double. Chemical modification of E. coli is an effective method for enhancing the adsorption performance for REEs.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 2016

All Journal Article (7 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 7 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] A polymer inclusion membrane composed of the binary carrier PC-88A and Versatic 10 for the selective separation and recovery of Sc2018

    • Author(s)
      M. Sharif, W. Yoshida, F. Kubota, S.D. Kolev, M. Goto
    • Journal Title

      RSC Adv.

      Volume: 8 Issue: 16 Pages: 8631-8637

    • DOI

      10.1039/c7ra12697b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Recovery of gold ions from discarded mobile phone leachate by solvent extraction and polymer inclusion membrane (PIM) based separation using an amic acid extractant2018

    • Author(s)
      F. Kubota, R. Kono, W. Yoshida, M. Sharaf, S.D. Kolev, M. Goto
    • Journal Title

      Sep. Purif. Technol.

      Volume: in press Pages: 156-161

    • DOI

      10.1016/j.seppur.2018.04.031

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solvent extraction of Pt(IV), Pd(II), and Rh(III) with the ionic liquid trioctyl(dodecyl) phosphonium chloride2018

    • Author(s)
      M. L. Firmansyah, F. Kubota, M. Goto
    • Journal Title

      J. Chem. Technol. Biotechnol.

      Volume: - Issue: 6 Pages: 1714-1721

    • DOI

      10.1002/jctb.5544

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] レアメタルの高度分離技術2017

    • Author(s)
      後藤雅宏、吉田航
    • Journal Title

      化学工業

      Volume: 68 Pages: 346-351

    • NAID

      40021171650

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biocatalytic Formation of Gold Nanoparticles Decorated with Functional Proteins inside Recombinant <i>Escherichia coli</i> Cells2016

    • Author(s)
      Y. Hosomomi, T. Niide, R. Wakabayashi, M. Goto, N. Kamiya
    • Journal Title

      Analytical Sciences

      Volume: 32 Issue: 3 Pages: 295-300

    • DOI

      10.2116/analsci.32.295

    • NAID

      130005131633

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Diglycolic amic acid-modified E. coli as a biosorbent for the recovery of rare earth elements2016

    • Author(s)
      Y. Hosomomi, R. Wakabayashi, F. Kubota, N. Kamiya, M. Goto
    • Journal Title

      Biochem. Eng. J

      Volume: 113 Pages: 102-106

    • DOI

      10.1016/j.bej.2016.06.005

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Development of High-Efficient Ion Exchange Materials by Utilizing Biological Functions and Biomaterials2016

    • Author(s)
      後藤雅宏
    • Journal Title

      Journal of Ion Exchange

      Volume: 27 Issue: 3 Pages: 33-41

    • DOI

      10.5182/jaie.27.33

    • NAID

      130005416231

    • ISSN
      0915-860X, 1884-3360
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 大腸菌を利用した希土類金属の回収2017

    • Author(s)
      細樅侑貴穂、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      化学工学会年会第82回年会
    • Place of Presentation
      芝浦工業大学
    • Year and Date
      2017-03-09
    • Related Report
      2016 Research-status Report
  • [Presentation] 資源循環型社会を構築するためのレアメタルの分離技術2017

    • Author(s)
      後藤雅宏
    • Organizer
      日本学術会議公開シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 日本発のレアメタル分離用の抽出剤開発2017

    • Author(s)
      後藤雅宏
    • Organizer
      分離技術会年会2017
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 細胞表層の界面修飾によるレアメタル分離剤の開発2017

    • Author(s)
      後藤雅宏、細樅侑貴穂
    • Organizer
      第33回日本イオン交換研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] The design of the cell surface of E. coli to recovery metal ions2016

    • Author(s)
      Y. Hosomomi, F. Kubota, R. Wakabayashi, N. Kamiya, M. Goto
    • Organizer
      25th Int. Symp. on Chem. Eng.,
    • Place of Presentation
      宮崎国際会議場
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属イオン回収に向けた大腸菌の表層設計法の開発2016

    • Author(s)
      細樅侑貴穂、久保田富生子、若林里衣、神谷典穂、後藤雅宏
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      宮崎国際会議場
    • Year and Date
      2016-09-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Modification of E. coli for the development of a biosorbent of rare earth elements2016

    • Author(s)
      Y. Hosomomi, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      北海道大学
    • Year and Date
      2016-06-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] Application of Ionic Liquids on Rare Earth Green Separation and Utilization2016

    • Author(s)
      F. Kubota, J.Yang, M. Goto
    • Total Pages
      326
    • Publisher
      Springer
    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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