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Development of nanofiborous CO2 sorbents for sorption-enchanced production of hydrogen

Research Project

Project/Area Number 16K14465
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

Mukai Shin  北海道大学, 工学研究院, 教授 (70243045)

Co-Investigator(Kenkyū-buntansha) 荻野 勲  北海道大学, 工学研究院, 准教授 (60625581)
岩村 振一郎  北海道大学, 工学研究院, 助教 (10706873)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords化学工学 / 反応・分離工学 / エネルギー / 環境技術 / 環境材料 / セラミックス / 反応・分離 / 吸着 / 触媒 / 触媒・化学プロセス
Outline of Final Research Achievements

In this work, we aimed at the synthesis of high-temperature CO2 adsorbents from nanosheets derived from MgAl double layered hydroxides, which will be potentially used to intensify the existing hydrogen production processes. In addition, we aimed at the synthesis of fiborous CO2 sorbents that can be readily molded into filters. As a result, we succeeded in preparing nanofiborous materials a few hundreds nm in diameter. In addition, through CO2 sorption experiments conducted in both batch and flow systems, we found that Mg/Al mixed oxides obtained by heat treatment in flowing nitrogen adsorbed CO2 up to 8-times higher than those obtained by heat treatment in flowing air. This research has brought important insights into how to improve the performance of Mg/Al mixed oxides as high-temperature adsorbents.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (27 results)

All 2018 2017 2016

All Journal Article (10 results) (of which Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (17 results) (of which Int'l Joint Research: 10 results,  Invited: 2 results)

  • [Journal Article] The impact of thermal activation conditions on physicochemical properties of nanosheet-derived Mg-Al mixed oxides2018

    • Author(s)
      Isao Ogino, Rei Tanaka, Shuichiroh Kudo, Shin R. Mukai
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 263 Pages: 181-189

    • DOI

      10.1016/j.micromeso.2017.12.014

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cost-effective synthesis of activated carbons with high surface areas for electrodes of nonaqueous electric double layer capacitors2018

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Journal Title

      Separation and Purification Technology

      Volume: 印刷中 Pages: 174-180

    • DOI

      10.1016/j.seppur.2018.04.022

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CO2 Separation in a Flow System by Silica Microhoneycombs Loaded with an Ionic Liquid Prepared by the Ice-Templating Method2017

    • Author(s)
      Yoshida, Seiichiro; Takahashi, Kazuya; Kudo, Shuichiro; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 10 Pages: 2834-2839

    • DOI

      10.1021/acs.iecr.6b05001

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Optimization of Practical Activation Depth for Effective CO2 Activation Using PMMA-templated Carbons with a Tailorable Pore System of Meso- and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      Journal of Porous Materials

      Volume: 24 Issue: 6 Pages: 1497-1506

    • DOI

      10.1007/s10934-017-0389-y

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PMMA-Templated Carbon Gel Monoliths with Independently Tunable Micro-, Meso-, and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 4 Pages: 315-323

    • DOI

      10.1252/jcej.16we313

    • NAID

      130006837170

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Optimization of Practical Activation Depth for Effective CO2 Activation Using PMMA-templated Carbons with a Tailorable Pore System of Meso- and Macropores2017

    • Author(s)
      Mori, Takeshi; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      J. Porous Mater.

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorption of Phenol in Flow Systems by a Monolithic Carbon Cryogel with a Microhoneycomb Structure2016

    • Author(s)
      Yoshida, Seiichiro; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      Adsorption

      Volume: 22 Issue: 8 Pages: 1051-1058

    • DOI

      10.1007/s10450-016-9799-4

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] New Method for Introducing Mesopores into Carbon Microhoneycombs Using Dextran2016

    • Author(s)
      Iwamura, Shinichiroh; Kitano, Kohei; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 231 Pages: 171-177

    • DOI

      10.1016/j.micromeso.2016.05.031

    • NAID

      120006502477

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of the Mesopores of Carbon Supports on the CO Tolerance of Pt2Ru3 Polymer Electrolyte Fuel Cell Anode Catalyst2016

    • Author(s)
      Narischat, Napan; Takeguchi, Tatsuya; Mori, Takeshi; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.; Ueda, Wataru
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: 41 Issue: 31 Pages: 13697-13704

    • DOI

      10.1016/j.ijhydene.2016.05.272

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] 酸化グラフェン由来の多孔質炭素の合成2016

    • Author(s)
      荻野 勲,向井 紳
    • Journal Title

      ケミカルエンジニアリング

      Volume: 61 Pages: 327-331

    • Related Report
      2016 Research-status Report
  • [Presentation] Effects of Thermal Activation Conditions on Physicochemical Properties of Nanosheet-derived Mg-Al Mixed Oxides2018

    • Author(s)
      Rei Tanaka, Isao Ogino, Shin R. Mukai
    • Organizer
      International Zeolites and Microporous Crystals 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Impact of Thermal Activation Conditions on Physicochemical Properties of Nanosheet-derived Mg-Al Mixed Oxides2018

    • Author(s)
      Rei Tanaka, Isao Ogino, Shin R. Mukai
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン液体を薄膜状に担持したマイクロハニカムによるCO2分離2017

    • Author(s)
      高橋 和也、吉田 誠一郎、工藤 修一郎、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第 25 回化学工学・粉体研究発表会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2017-01-27
    • Related Report
      2016 Research-status Report
  • [Presentation] Mechanistic Study of the Facilitated Removal of SDAs from MWW-type Layered Zeolitic Precursors by DMF and Ethylene Glycol2017

    • Author(s)
      Ogino, Isao; Shirobe, Taichi; Mukai, Shin R.
    • Organizer
      The 3rd Euro-Asia Zeolite Conference
    • Place of Presentation
      Bali (Indonesia)
    • Year and Date
      2017-01-22
    • Related Report
      2016 Research-status Report
  • [Presentation] CO2 Adsorption Characteristics of Nano-fiberized Mg/Al Mixed Metal Oxides for Sorption-Enhanced Water Gas Shift Reaction2017

    • Author(s)
      Rei Tanaka, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Organizer
      Hokkaido University- Chulalongkorn University Learning Satellite Program
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Simplified Model for Simulation of Photocatalytic Systems with TiO2-SiO2 Microhoneycombs2016

    • Author(s)
      Urkasame, Kasama; Yoshida, Seiichiro; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Organizer
      The 10th International Conference on Multi-functional Materials and Applications
    • Place of Presentation
      Khon Kaen(Thailand)
    • Year and Date
      2016-12-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Adsorption of Water Contaminants in Continuous Flow Systems Using Carbon Cryogels with a Microhoneycomb Structure2016

    • Author(s)
      Yoshida, Seiichiro; Iwamura, Shinichiro ; Ogino, Isao ; Mukai, Shin R.
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] A Mixed-Solvent Approach to Delaminate Layered Zeolitic Precursors2016

    • Author(s)
      Ogino, Isao; Shirobe, Taichi; Mukai, Shin R.
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Research-status Report
  • [Presentation] On the Influence of Mass Transport in Sulfonated Carbon Catalysts Derived from Various Carbon Sources on Liquid-Phase Esterification Reactions2016

    • Author(s)
      Suzuki, Yukei; Ogino, Isao; Mukai, Shin R.
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 混合溶媒を用いたゼオライト層状前駆体の層剥離に関する詳細検討2016

    • Author(s)
      白部 大知、荻野 勲、向井 紳
    • Organizer
      化学工学会 第48回秋季大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] 炭素系固体酸触媒の液相反応への利用:表面の親疎水性と細孔構造が触媒活性へ与える影響2016

    • Author(s)
      鈴木 佑啓、荻野 勲、向井 紳
    • Organizer
      化学工学会 第48回秋季大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Enhancing the Performance of Anode Catalysts for PEFCs Using Carbon Gels as the Support2016

    • Author(s)
      Satoh, Kodai; Tsuchiya, Takanori; Iwamura, Shinichiro; Ogino, Isao; Mukai, Shin R.
    • Organizer
      11th Conference on Sustainable Development of Energy, Water and Environment Systems
    • Place of Presentation
      Lisbon(Portugal)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Carbon Gel Based Pt/C Catalysts with a High Sintering Tolerance2016

    • Author(s)
      Satoh, Kodai; Tsuchiya, Takanori; Iwamura, Shinichiro; Ogino, Isao; Mukai, Shin R.
    • Organizer
      CARBON2016
    • Place of Presentation
      Pennsylvania(USA)
    • Year and Date
      2016-07-10
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Sulfonated Carbon Catalysts Synthesized from Various Carbon Sources2016

    • Author(s)
      Ogino, Isao; Suzuki, Yukei; Mukai, Shin R.
    • Organizer
      16th International Congress on Catalysis
    • Place of Presentation
      Beijing (China)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] A Mixed-Solvent Approach to Delaminate Lamellar Precursors of MWW-type Molecular Sieves2016

    • Author(s)
      Shirobe, Taichi; Ogino, Isao; Mukai, Shin R.
    • Organizer
      Pre-symposium of 16th International Congress on Catalysis (16th ICC-Pre) & 2nd International Symposium of Institute for Catalysis
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2016-06-30
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] カーボンゲルの構造制御と触媒反応への応用2016

    • Author(s)
      向井 紳
    • Organizer
      触媒学会千葉地区講演会
    • Place of Presentation
      千葉大学(千葉市)
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Unique Monolithic Porous Carbons with a Tunable Hierarchical Pore System of Micro-, Meso- and Macropores2016

    • Author(s)
      Mukai, Shin R.
    • Organizer
      HU-NTU-CERMAV Joint Symposium on Functional Materials 2016
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2019-12-27  

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