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Control of characteristic properties and high-density packing for printing type of multi-element lead-free soldering nanoparticles synthesized by supercritical crystallization reaction

Research Project

Project/Area Number 16K14466
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionTohoku University

Principal Investigator

Smith Richard  東北大学, 環境科学研究科, 教授 (60261583)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsナノ粒子 / 超臨界流体
Outline of Final Research Achievements

Lead-free soldering nanoparticles are the important materials for luminescent materials or printing type high-density packing. However, it has been challenging to synthesize lead-free particles due to their oxidative properties. In this work, continuous supercritical crystallization process was chosen for the synthesis of SnO2 nanoparticles (SnO2NPs) and Sn-Ag-Cu alloy nanoparticles (SACNPs) because it is considered to be promising as an efficient synthesis method. The influence of experimental conditions, such as reaction temperature, residence time and molar ratio of PVP/Sn was assessed and the grain growth mechanism for SnO2NPs was studied. Then, with the intention of SACNPs formation, adding Ag and Cu precursors as complex metal species and formic acid (FA) as a reducing agent, the influence of reaction conditions on particle formation was studied to elucidate to search for the possibility of synthesizing low melting point solder particles under hydrothermal condition.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (5 results)

All 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results)

  • [Journal Article] Synthesis of ferroelectric K1-xNaxNb1-yTayO3 nanoparticles using a supercritical water flow system2017

    • Author(s)
      K. Okada, H. Hayashi, M. Takesue, M. Watanabe, R. L. Smith, Jr.
    • Journal Title

      Journal of Supercritical Fluids

      Volume: 123 Pages: 101-108

    • DOI

      10.1016/j.supflu.2016.12.018

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Influence of precursor species and their thermal stability on continuous supercritical hydrothermal synthesis of polyvinylpyrrolidone-capped zero-valent copper nanoparticles2017

    • Author(s)
      Yuki Kurihara, Takuya Morioka, Masafumi Takesue, Masaru Watanabe, Richard L. Smith, Jr.
    • Organizer
      The 5th International Symposium & Exhibition on Aqua Science and Water Resources (ISASWR'17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Methodology of using mixed-solvents for developing green chemical processes2017

    • Author(s)
      Richard L. Smith, Jr.
    • Organizer
      The 5th International Symposium & Exhibition on Aqua Science and Water Resources (ISASWR'17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Strategies for Using Mixed-solvents in Supercritical Fluid Science and Technology2017

    • Author(s)
      Alif Duereh, Yuya Hiraga, Richard L. Smith, Jr.
    • Organizer
      6th European Meeting on Supercritical Fluids (EMSF)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Aspects of mixed-solvents for reactions and separations2016

    • Author(s)
      R. L. Smith, Jr.
    • Organizer
      平成 28 年度化学系学協会東北大会
    • Place of Presentation
      いわき明星大学(福島・いわき)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Research-status Report
    • Invited

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Published: 2016-04-21   Modified: 2019-03-29  

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