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Re-establishments of Actinide Chemistry on basis of Phthalocyanine complexes : Application to nuclear medicine and Single molecular analysis.

Research Project

Project/Area Number 16K14533
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nuclear engineering
Research InstitutionTohoku University

Principal Investigator

Yamamura Tomoo  東北大学, 金属材料研究所, 准教授 (20281983)

Co-Investigator(Kenkyū-buntansha) 福田 貴光  大阪大学, 理学研究科, 准教授 (40344741)
大槻 勤  京都大学, 原子炉実験所, 教授 (50233193)
笠松 良崇  大阪大学, 理学研究科, 講師 (70435593)
白崎 謙次  東北大学, 金属材料研究所, 技術専門職員 (70447176)
鷲山 幸信  福島県立医科大学, 公私立大学の部局等, 准教授 (80313675)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsフタロシアニン / アクチノイド / アルファ放射体核医薬 / 核医薬
Outline of Final Research Achievements

UPc2 complexes were successfully prepared by using the newly-developed heating-block method. Phthalocyanine complexes were successfully purified and its single crystals were obtained by sublimation process. Also, single crystals of [UPc]+ were prepared by electrolysis and the purified complex of superphthalocyanine UO2SPc were prepared. These sublimation transferring method process were developed for samples for AFM. All the processes were designed to be dealt in the glove-box for alpha-emitters.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (6 results)

All 2018 2017 2016

All Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Presentation] ウランフタロシアニン錯体の合成と磁化測定2018

    • Author(s)
      渡邊博仁、福田貴光、白崎謙次、山村朝雄
    • Organizer
      原子力学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis and Magnetic Measurement of Uranium Phthalocyanine (UPc2)2017

    • Author(s)
      H. Watanabe, T. Fukuda, K. Shirasaki, T. Yamamura
    • Organizer
      Actinides2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Electrochemical Study of Uranium Superphthalocyanine Complex2017

    • Author(s)
      T. Yamamura, H. Watanabe, T. Fukuda, K. Shirasaki
    • Organizer
      Actinides2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 227Thを用いた核医薬の検討2016

    • Author(s)
      北林和真、山村朝雄、古谷昌、大田卓、鷲山幸信
    • Organizer
      原子力学会東北支部交流会
    • Place of Presentation
      東北大学片平キャンパス
    • Year and Date
      2016-12-12
    • Related Report
      2016 Research-status Report
  • [Presentation] アクチノイドを中心金属としたフタロシアニン錯体の合成と物性測定2016

    • Author(s)
      渡邊博仁、福田貴光、白崎謙次、山村朝雄
    • Organizer
      東北大学金属材料研究所講演会
    • Place of Presentation
      東北大学片平キャンパス
    • Year and Date
      2016-11-24
    • Related Report
      2016 Research-status Report
  • [Presentation] EDTMPおよびDOTMPのTh(IV)錯体の構造と安定度定数2016

    • Author(s)
      北林和真、山村朝雄、古谷昌、大田卓、鷲山幸信
    • Organizer
      東北大学金属材料研究所講演会
    • Place of Presentation
      東北大学片平キャンパス
    • Year and Date
      2016-11-24
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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