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Enrichment of carbon dioxide by humidity and temperature swing adsorption process for agricultural greenhouses

Research Project

Project/Area Number 16K15012
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Agricultural environmental engineering/Agricultural information engineering
Research InstitutionKanazawa University

Principal Investigator

Kodama Akio  金沢大学, 機械工学系, 教授 (30274690)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords農業工学 / 二酸化炭素 / 園芸作物 / 光合成 / 吸着 / 炭酸塩 / 再生可能エネルギー / 除湿 / 植物 / 二酸化炭素排出削減
Outline of Final Research Achievements

In general, CO2 adsorption capacity of the thermally regenerative conventional desiccant wheels is normally small or disappeared by adsorbed water vapor. Then, CO2 absorption ability of KHCO3 and NaHCO3 is attractive. Prepared KHCO3 and NaHCO3 wheels indicated relatively high CO2 and H2O removal performance. However, as time went by, the performance was getting worse. It has been reported that chemical reaction of K2CO3 with aluminum produces a substance which has high thermal stability. But, this study concluded that destruction and re-bonding of K2CO3 particle during temperature swing was also a reason for the performance decrease, basing on thermogravimetric analysis and microscope observation. For the carbon dioxide supply system for agricultural greenhouses, this gives an important guideline towards establishment of the operating method for not causing performance decrease, and a rotor production method.

Academic Significance and Societal Importance of the Research Achievements

環境負荷の小さいオンサイト型の二酸化炭素施用法を確立し、作物収量の増加によって農業の生産性向上と競争力増強に貢献しようとするものである。燃焼系装置が導入し難い植物工場等への導入も容易である。水蒸気共存下でも二酸化炭素除去能を有し、また安全性の高い炭酸塩の利用が望ましい。本研究では、温度スイング操作における炭酸塩の反応機構と性能低下要因をおおよそ明らかにできた。これは、性能低下を引き起こさないための運転方法およびロータ担体への添着・含浸方法の確立に向けて重要な指針を与えるものである。希薄二酸化炭素の除去濃縮プロセスの実現は、農業だけでなく、空調の省エネルギー化にも貢献できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (12 results)

All 2019 2018 2017 2016 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Adsorption-Desorption Behavior of Water Vapor and Heat-Flow Analysis of FAM-Z01-coated Heat Exchanger2019

    • Author(s)
      Tsujiguchi T., Osaka Y.., Kumita M., Kodama A.
    • Journal Title

      International Journal of Refrigeration

      Volume: 印刷中 Pages: 3-10

    • DOI

      10.1016/j.ijrefrig.2019.03.011

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental investigation on the CO2 separation performance from humid flue gas by TSA process2018

    • Author(s)
      Osaka Y., Tsujiguchi T., Kodama A.
    • Journal Title

      Separation and Purification Technology

      Volume: 207 Pages: 77-82

    • DOI

      10.1016/j.seppur.2018.06.008

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Feasibility Study of Simultaneous Heating and Dehumidification Using an Adsorbent Desiccant Wheel with Humidity Swing2017

    • Author(s)
      Tsujiguchi T., Osaka Y., Kodama A.
    • Journal Title

      Applied Thermal Engineering

      Volume: 117 Pages: 437-442

    • DOI

      10.1016/j.applthermaleng.2017.02.067

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Feed Gas Condition and Regeneration Temperature on the Separation Performance of Thermal Swing Continuous CO<sub>2</sub> Adsorber using a Honeycomb Adsorbent Rotor2017

    • Author(s)
      下茂野香名江,井上宏志,岡野浩志,児玉昭雄
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 43 Issue: 2 Pages: 81-87

    • DOI

      10.1252/kakoronbunshu.43.81

    • NAID

      130005464626

    • ISSN
      0386-216X, 1349-9203
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 吸着を利用した連続分離/エネルギー変換操作2018

    • Author(s)
      児玉昭雄
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Cyclic sorption / desorption behavior of the low concentration CO2 in K2CO3 / Na2CO3 honeycomb2017

    • Author(s)
      K. Shimono, H. Okano, A. Kodama
    • Organizer
      11 th International Conference on Separation Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of desiccant wheel with carbon dioxide removal capability2017

    • Author(s)
      M. Kuida, T. Tsujiguchi, Y. Osaka, A. Kodama, K. Shimono, H. Okano
    • Organizer
      11 th International Conference on Separation Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 吸着材ハニカムロータの除湿挙動とデシカント空調システムの高度化2017

    • Author(s)
      児玉昭雄
    • Organizer
      化学工学会金沢大会2017
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] K2CO3/Na2CO3担持ハニカムにおける低濃度CO2の収脱着挙動2017

    • Author(s)
      下茂野香名江,岡野浩志,児玉昭雄
    • Organizer
      化学工学会東京大会2017
    • Related Report
      2017 Research-status Report
  • [Presentation] Biogas separation by temperature and concentration swing adsorption process using carbon molecular sieve2016

    • Author(s)
      Isoda M., Osaka Y., Tsujiguchi T., Kodama A.
    • Organizer
      Innovative Materials for Processes in Energy Systems IMPRES2016
    • Place of Presentation
      Taormina, Sicily, Italy
    • Year and Date
      2016-10-23
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Influence of water vapor contained in simulated biogas on the separation performance of VSA process employing Carbon Molecular Sieve2016

    • Author(s)
      Nakatsuka H., Zainol N. I. B., Osaka Y., Tsujiguchi T., Kodama A.
    • Organizer
      Innovative Materials for Processes in Energy Systems IMPRES2016
    • Place of Presentation
      Taormina, Sicily, Italy
    • Year and Date
      2016-10-23
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks] 金沢大学理工研究域機械工学系環境科学研究室

    • URL

      http://www.me.se.kanazawa-u.ac.jp/gijutsu/index.html

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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