Development of super functional alcoholic chemical hydride method and its application to the catalytic reduction of aromatic nuclei
| Project/Area Number |
16K15100
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Chemical pharmacy
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| Research Institution | Gifu Pharmaceutical University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 白金炭素 / 水素キャリアー / アルコール / 水 / 水素製造 / ケミカルハイドライド / メチルシクロヘキサン / マイクロ波 / 水素キャリア / 有機反応学 / 有機ハイドライド / 芳香核還元反応 |
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| Outline of Final Research Achievements |
The development of new hydrogen production methods has been widely studied to establish safe, efficient and environmentally friendly alternative energy resources. Hydrogen gas can be conventionally produced by a steam reforming of methane under harsh reaction conditions with CO2 generation. Alcohols are prospective candidates as CO2-free hydrogen storages since the dehydrogenation from alcohols relatively easily proceeds of low energy. We have found that the dehydrogenation of alcohol could smoothly and quantitatively proceed by the use of a heterogeneously catalyzed flow reaction system with microwave irradiation as a direct-heating source. The combination of flow reaction system and microwave irradiation extremely effectively facilitated the hydrogen production in comparison with the batch system.
Furthermore, we have also developed an efficient hydrogenation method of aromatic nuclei via the direct hydrogen transfer process from 2-propanol without external addition of hydrogen gas.
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Report
(3 results)
Research Products
(31 results)
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[Journal Article] Synthesis Based on Silicon-Hydrogen Bond Activation Using Gold and Platinum on Carbon in Water or Heavy Water2016
Author(s)
Yoshinari Sawama, Masahiro Masuda, Naoki Yasukawa, Ryosuke Nakatani, Shumma Nishimura, Kyoshiro Shibata, Tsuyoshi Yamada, Yasunari Monguchi, Hiroyasu Suzuka, Yukio Takagi, and Hironao Sajiki
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Journal Title
J. Org. Chem.
Volume: 81
Issue: 10
Pages: 4190-4195
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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