Ultra-High-Resolution Separation of Alloy Cluster and Their Characterization
| Project/Area Number |
16K17480
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanostructural chemistry
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| Research Institution | Rikkyo University (2017)
Tokyo University of Science (2016) |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 配位子保護金属クラスター / 合金クラスター / 高分解能分離 / 高速液体クロマトグラフィー / チオラート保護金クラスター / 異性体 / 精密分離 / クラスター / ナノ粒子 |
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| Outline of Final Research Achievements |
Ligand-protected metal clusters, whose diameter is ~nm has been attracted as building block of functionalized future nanomaterials, because they have size-dependent properties like photoluminescence or catalytic activity, which are not shown in bulk metal. This work demonstrated the development of technique for ultra-high-resolution separation of mixture containing various composition of ligand-protected clusters obtained in the synthesis process, by using high-performance liquid chromatography. By applying our separation method, the mixture of gold-silver alloy cluster, whose some gold atoms in gold cluster were replaced with silver atoms, were separated into each clusters with individual composition for the first time. In addition, it has been revealed that our method can separate the isomers, whose doping-site of silver atoms are different.
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Report
(3 results)
Research Products
(29 results)
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[Journal Article] [Pt17(CO)12(PPh3)8]n+ (n = 1, 2): Synthesis and Geometric and Electronic Structures2017
Author(s)
L. V. Nair, S. Hossain, S. Wakayama, S. Takagi, M. Yoshioka, J. Maekawa, A. Harasawa, B. Kumar, Y. Niihori, W. Kurashige, Y. Negishi
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Journal Title
THE JOURNAL OF PHYSICAL CHEMISTRY
Volume: C
Issue: 20
Pages: 11002-11009
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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