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THz carrier dynamics in single-molecule junctions

Research Project

Project/Area Number 16K17481
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanostructural physics
Research InstitutionThe University of Tokyo

Principal Investigator

YOSHIDA KENJI  東京大学, 生産技術研究所, 助教 (50738599)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsテラヘルツ / 量子ナノ構造 / 量子物性 / 単一分子接合 / カーボンナノチューブ / 単一分子 / ナノ構造物性 / 量子ドット / ナノエレクトロニクス / 近藤効果 / 物性実験 / メゾスコピック系 / マイクロ・ナノデバイス
Outline of Final Research Achievements

Characteristic physical energies in single-molecule junctions lie in the terahertz frequency regime. They are expected to strongly interact with THz photons and THz electromagnetic waves have an impact on carrier dynamics in single-molecule junctions. However, experimental reports of electron transport in single-molecule junctions have so far been done in the DC regime, and the carrier dynamics has not been clear yet. In this research, we fabricated single-molecule transistors and analyzed THz-induced photocurrents generated by irradiating external THz electromagnetic fields onto the devices. By using this spectroscopic method, we successfully observed center-of-mass oscillation of organic molecules, which is a demonstration of THz spectroscopy at the single-molecule level. Furthermore, we applied the same method to single carbon-nanotube molecules and succeeded in observing THz-intersublevel transisions.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (38 results)

All 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (33 results) (of which Int'l Joint Research: 15 results,  Invited: 3 results)

  • [Int'l Joint Research] DGIST(韓国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] パリ高等師範学校(フランス)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Quantum Dots Formed in Three-dimensional Dirac Semimetal Cd3As2 Nanowires2018

    • Author(s)
      M. Jung, K. Yoshida., K. Park, X.-X. Zhang, C. Yesilyurt, Z. B. Siu, M. B. A. Jalil, J.W. Park, J. Park, N. Nagaosa, J. Seo, and K. Hirakawa
    • Journal Title

      Nano Letters

      Volume: 18 Issue: 3 Pages: 1863-1868

    • DOI

      10.1021/acs.nanolett.7b05165

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electric-field control of conductance in metal quantum point contacts by electric-double-layer gating2017

    • Author(s)
      K. Shibata, K. Yoshida, K. Daiguji, H. Sato, T. Ii, and K. Hirakawa
    • Journal Title

      Applied Physics Letters

      Volume: 111 Issue: 15 Pages: 153104-153104

    • DOI

      10.1063/1.4995318

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stochastic resonance in bistable atomic switches2017

    • Author(s)
      K. Yoshida, and K. Hirakawa
    • Journal Title

      Nanotechnology

      Volume: 28, no. 12 Issue: 12 Pages: 125205-125205

    • DOI

      10.1088/1361-6528/aa5ee1

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Coupling a terahertz cavity to a carbon nanotube quantum dot2018

    • Author(s)
      F. Valmorra, K. Yoshida, L. Contamin, T. Cubaynes, M. Dartiailh, M. Desjardins, S. Massabeau, K. Hirakawa, J. Mangeney, A. Cottet, and T. Kontos
    • Organizer
      DPG Spring Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Rotation effect in endohedral metallofullerene Ce@C82 single-molecule transistors2018

    • Author(s)
      唐九君、杜少卿、吉田健治、張亜、平川一彦
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] テラヘルツ分光による単一カーボンナノチューブ量子ドットの電子状態の評価2018

    • Author(s)
      鶴谷拓磨、吉田健治、矢島史彬、清水麻希、本間芳和、平川一彦
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 単一カーボンナノチューブ量子ドットのテラヘルツ分光2018

    • Author(s)
      吉田健治、鶴谷琢磨、矢島文彬、清水麻希、本間芳和、平川一彦
    • Organizer
      新学術領域「ハイブリッド量子科学」第六回領域会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属内包Ce@C82単一分子トランジスタにおける分子回転効果2018

    • Author(s)
      唐九君、杜少卿、吉田健治、張亜、平川一彦
    • Organizer
      新学術領域「ハイブリッド量子科学」第六回領域会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] Coupling a terahertz cavity to a carbon nanotube quantum dot2018

    • Author(s)
      F. Valmorra, K. Yoshida, L. Contamin, T. Cubaynes, M. Dartiailh, M. Desjardins, S. Massabeau, K. Hirakawa, J. Mangeney, A. Cottet, T. Kontos
    • Organizer
      新学術領域「ハイブリッド量子科学」第六回領域会議
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Sensing a single atom in a single Ce@C82 endohedral metallofullerene by terahertz radiation2017

    • Author(s)
      S. Du, Y. Zhang , K. Yoshida, K. Hirakawa
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜、横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Ionic Liquid Gating of Metal Contacts: Effect of Cation Size2017

    • Author(s)
      C. Li, K. Yoshida, K. Shibata, S. Ono, and K. Hirakawa
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜、横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 単一分子伝導のテラヘルツダイナミクス2017

    • Author(s)
      平川一彦、杜少卿、吉田健治、張亜、濱田幾太郎
    • Organizer
      新学術領域ハイブリッド量子科学 第4回領域会議
    • Place of Presentation
      理化学研究所、和光市
    • Year and Date
      2017-02-27
    • Related Report
      2016 Research-status Report
  • [Presentation] Terahertz Spectroscopy of Single Molecules Using Nanogap Metal Electrodes2017

    • Author(s)
      S. Du, K. Yoshida, Y. Zhang, I. Hamada, K. Hirakawa
    • Organizer
      新学術領域ハイブリッド量子科学 第4回領域会議
    • Place of Presentation
      理化学研究所、和光市
    • Year and Date
      2017-02-27
    • Related Report
      2016 Research-status Report
  • [Presentation] Terahertz spectroscopy of single molecules and single atoms2017

    • Author(s)
      K, Hirakawa, S. Du, K. Yoshida, C.Tang, and Y. Zhang
    • Organizer
      ngle atoms”, 4th International Symposium on Microwave/Terahertz Science and Applications (MTSA 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Terahertz spectroscopy of single molecules and single atoms far beyond the diffraction limit2017

    • Author(s)
      K, Hirakawa, S. Du, K. Yoshida, and Y. Zhang
    • Organizer
      Russia-Japan-USA-Europe Symposium on Fundamental & Applied Problems of Terahertz Devices & Technologies (RJUSE TeraTech 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Terahertz spectroscopy of a single atom in a fullerene cage2017

    • Author(s)
      S. Du, Y. Zhang, K. Yoshida, and K. Hirakawa
    • Organizer
      International Symposium on Hybrid Quantum Systems 2017 (HQS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Terahertz Spectroscopy of Carbon Nanotube Quantum Dots Performed by Detecting THz-induced Photocurrent in the Single Electron Transistor Geom2017

    • Author(s)
      T. Tsurugaya, K. Yoshida, F. Yajima, M. Shimizu, Y. Homma, S.Q. Du, Y. Zhang, and K. Hirakawa
    • Organizer
      International Symposium on Hybrid Quantum Systems 2017 (HQS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Terahertz spectroscopy of a single atom in a fullerene cage2017

    • Author(s)
      S. Du, Y. Zhang, K. Yoshida, and K. Hirakawa
    • Organizer
      42 International Conference on Infrared, Millimeter and Terahertz Waves (IRMMW-THz 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] erahertz dynamics of electron-vibron coupling in single molecules with tunable electrostatic potential2017

    • Author(s)
      S. Du, K. Yoshida, Y. Zhang, I. Hamada, and K. Hirakawa
    • Organizer
      The 20th International Conference on Electron Dynamics in Semiconductors, Optoelectronics and Nanostructures (EDISON20)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] テラヘルツ電磁波を用いた金属内包Ce@C82 フラーレン分子内の単一Ce 原子の観測2017

    • Author(s)
      S.Q. Du, Y. Zhang、吉田健治、C.C. Tang、平川一彦
    • Organizer
      新学術領域「ハイブリッド量子科学」 第五回領域会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナノギャップ電極を用いた単一カーボンナノチューブのテラヘルツ分光2017

    • Author(s)
      鶴谷拓磨、吉田健治、矢島史彬、清水麻希、本間芳和、平川一彦
    • Organizer
      新学術領域「ハイブリッド量子科学」 第五回領域会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] Terahertz spectroscopy of a single atom in a fullerene cage2017

    • Author(s)
      杜少卿、張亜、吉田健治、唐九君、平川一彦
    • Organizer
      第8回 光電子融合ワークショップ--若手による成果報告
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ptナノギャップ接合におけるトンネル磁気抵抗効果2017

    • Author(s)
      吉田健治、平川一彦
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ボウタイアンテナ型電極を用いたカーボンナノチューブ単一電子トランジスタへのテラヘルツ光集光とその光応答2017

    • Author(s)
      鶴谷拓磨、吉田健治、矢島史彬、清水麻希、本間芳和、平川一彦
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Seeing single molecules with long wavelength terahertz radiation2016

    • Author(s)
      K. Hirakawa, S. Du, K. Yoshida, and Y. Zhang
    • Organizer
      Workshop University of Tokyo/ENS
    • Place of Presentation
      Paris, France
    • Year and Date
      2016-11-16
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 強磁性ナノ接合における近藤効果の観測2016

    • Author(s)
      吉田健治、平川一彦
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ:新潟コンベンションセンター、新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] InP(311)B 面上に成長したInAs 量子ドットの電気伝導特性2016

    • Author(s)
      和田直樹、張亜、吉田健治、赤羽浩一、平川一彦
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ:新潟コンベンションセンター、新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気化学エッチングにより作製した金属量子ポイントコンタクトの電界変調2016

    • Author(s)
      阿部千夏、柴田憲治、吉田健治、平川一彦
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ:新潟コンベンションセンター、新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Nanomechanical oscillation in single-C60 transistors investigated by time-domain terahertz spectroscopy2016

    • Author(s)
      S. Du, Y. Zhang, K. Yoshida, and K. Hirakawa
    • Organizer
      the 8th Edition of the International Conference on Molecular Electronics (ElecMol)
    • Place of Presentation
      Paris, France
    • Year and Date
      2016-08-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Vibron-assisted tunneling in single Ce@C82 molecule transistors investigated by terahertz spectroscopy2016

    • Author(s)
      S. Du, Y. Zhang, K. Yoshida, and K. Hirakawa
    • Organizer
      the 33rd International Conference on the Physics of Semiconductors (ICPS2016)
    • Place of Presentation
      Beijing, China
    • Year and Date
      2016-07-31
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electric-field tuning of conductance in metal quantum point contacts”, the 19th International Conference on Superlattices2016

    • Author(s)
      K. Shibata, K. Yoshida, and K. Hirakawa
    • Organizer
      the 19th International Conference on Superlattices, Nanostructures and Nanodevices (ICSNN 2016)
    • Place of Presentation
      Hong Kong, China
    • Year and Date
      2016-07-25
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Stochastic resonance in an atomic switch2016

    • Author(s)
      K. Yoshida, and K. Hirakawa
    • Organizer
      the 19th International Conference on Superlattices, Nanostructures and Nanodevices (ICSNN 2016)
    • Place of Presentation
      Hong Kong, China
    • Year and Date
      2016-07-25
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Terahertz spectroscopy of single Ce-doped C82 molecules using sub-nm-scale gap electrodes2016

    • Author(s)
      S. Du, K. Yoshida, Y. Zhang, and K. Hirakawa
    • Organizer
      the 43rd International Symposium on Compound Semiconductors (ISCS2016)
    • Place of Presentation
      富山国際会議場、富山市
    • Year and Date
      2016-06-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photon-Assisted Tunneling in Single-Molecule Transistors Induced by Terahertz Radiation Enhanced in the Sub-nm Gap Electrodes2016

    • Author(s)
      K. Yoshida, K. Shibata, and K. Hirakawa
    • Organizer
      CIQM Frontiers in Quantum Materials and Devices Workshop, RIKEN Wako Campus
    • Place of Presentation
      理化学研究所、和光市
    • Year and Date
      2016-06-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Terahertz spectroscopy of single molecules using sub-nm scale gap electrodes2016

    • Author(s)
      S. Du, Y. Zhang, K. Yoshida, and K. Hirakawa
    • Organizer
      CIQM Frontiers in Quantum Materials and Devices Workshop, RIKEN Wako Campus
    • Place of Presentation
      理化学研究所、和光市
    • Year and Date
      2016-06-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ナノギャップ金属電極とテラヘルツナノサイエンス2016

    • Author(s)
      平川一彦、吉田健治、張亜、杜少卿、柴田憲治
    • Organizer
      第140回微小光学研究会「微小光学から見る『光と電波の境界領域』」
    • Place of Presentation
      日本女子大学、文京区、東京
    • Related Report
      2016 Research-status Report
    • Invited

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Published: 2016-04-21   Modified: 2019-03-29  

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