Fabrication of quantum cellular automaton by using charge degrees of freedom in molecules
| Project/Area Number |
16K17489
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Nanomaterials chemistry
|
|---|
| Research Institution | University of Hyogo |
|---|
Principal Investigator |
Keishiro Tahara 兵庫県立大学, 物質理学研究科, 助教 (50622297)
|
|---|
| Project Period (FY) |
2016-04-01 – 2018-03-31
|
| Project Status |
Completed (Fiscal Year 2017)
|
| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
|---|
| Keywords | 分子内電荷移動 / 混合原子価 / 金属錯体 / 非イノセント配位子 / カテコール / フェロセン / レドックス活性 / 超分子 |
|---|
| Outline of Final Research Achievements |
Mixed-valence compounds have attracted great interest from the viewpoint of molecular quantum cellular automaton (QCA). In this study, we regard molecular mixed-valence compounds involving two redox-active components as QCA half-cells and aim to obtain insight into controlling charge distributions as information. We constructed homo- and hetero-conjugates by covalently linking redox-active organic and/or organometallic components and clarified the effects of the types of redox-active components and bridging moieties on intramolecular charge transfer. We also explored a chemical method to introduce guest anions as external charges.
|
Report
(3 results)
Research Products
(10 results)
