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Room temperature atomic layer deposition on protain particles

Research Project

Project/Area Number 16K17494
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionYamagata University

Principal Investigator

Kensaku Kanomata  山形大学, 有機材料システム研究推進本部, 助教 (60771243)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords室温原子層堆積 / 多重内部反射型赤外吸収分光 / 加湿アルゴンプラズマ / X線光電子分光 / タンパク質 / 生体模擬材料 / 室温原子原子層堆積 / X線光電子分光法 / 大気圧プラズマ / その場観察 / 微粒子
Outline of Final Research Achievements

We have investigated surface reaction observation in room temperature atomic layer deposition (RT-ALD) on resin films, which has not been reported. In one instance, the RT-ALD process of silicon oxide on an acrylic resin film is observed by infrared absorption spectroscopy. It is found that the behavior is different from that on a Si substrate. In addition, for development of iron oxide RT-ALD process for magnetic drug delivery, adsorption and oxidation processes of precursor on a Si substrate was observed, and the iron oxide RT-ALD process design was performed. In the future, we try to apply a biocompatible titanium oxide coat and the iron oxide coat that might be expected to have magnetic properties on the powder, and develop it into a contrast agent for MRI and core-shell fine particles for drug delivery.

Academic Significance and Societal Importance of the Research Achievements

本研究では、室温原子層堆積の分野において、それまで未踏であった有機膜上の原料分子の吸着過程と酸化過程を多重内部反射型赤外吸収分光によって動的に観察する研究を進めた。有機膜の一例として、アクリル樹脂をSi基板上に塗布し、酸化シリコンの原料分子の吸着と酸化過程が両者で異なることを見出している。実際にアクリル膜上とSi基板上で酸化シリコンの室温原子層堆積を行うとアクリル膜上では、一定のサイクル数まで膜が堆積しない、インキュベーションタイムが見られた。これより、有機膜上では堆積条件を調整する必要があることが分かった。この知見は、樹脂材料へのガスバリアコートの際のプロセス設計に有用であると考えられる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (23 results)

All 2019 2018 2017 2016

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results) Presentation (18 results) (of which Int'l Joint Research: 13 results)

  • [Journal Article] Surface reaction kinetics of room temperature atomic layer deposition of ZnO observed by in situ IR absorption spectroscopy2019

    • Author(s)
      Yoshida Kazuki、Saito Kentaro、Miura Masanori、Kanomata Kensaku、Hirose Fumihiko
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 37 Issue: 2 Pages: 020922-020922

    • DOI

      10.1116/1.5079465

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room-temperature atomic layer deposition of SnO2 using tetramethyltin and its application to TFT fabrication2018

    • Author(s)
      Kentaro Tokoro, Shunsuke Saito, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad Shigeru Kubota, Fumihiko Hirose
    • Journal Title

      IEICE TRANSACTIONS on ELECTRONICS

      Volume: 印刷中

    • NAID

      130006729734

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Room-Temperature Atomic Layer Deposition of Aluminum Silicate and its Application in Dye sensitized Solar Cells2017

    • Author(s)
      Takahiro Imai, Yoshiharu Mori, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Journal Title

      Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films

      Volume: 36 Issue: 1

    • DOI

      10.1116/1.5002716

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Room temperature atomic layer deposition of TiO2 on gold nanoparticles2017

    • Author(s)
      K. Tokoro, K. Kanomata, B. Ahammad, S. Kubota, F. Hirose)
    • Journal Title

      J. Vac. Sci. Technol. A

      Volume: 35 Issue: 1

    • DOI

      10.1116/1.4971398

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Room-temperature atomic layer deposition of ZrO2 using tetrakis(ethylmethylamino)zirconium and plasma-excited humidified argon2016

    • Author(s)
      K. Kanomata, K. Tokoro, T. Imai, P. Pansila, M. Miura, B. Ahmmad, S. Kubota, K. Hirahara, F. Hirose
    • Journal Title

      Applied Surface Science

      Volume: 387 Pages: 497-502

    • DOI

      10.1016/j.apsusc.2016.06.122

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 赤外吸収分光を用いた樹脂膜上への室温原子層堆積過程のその場観察2019

    • Author(s)
      鹿又健作、吉田一樹、齋藤健太郎、三浦正範、有馬ボシールアハンマド、久保田繁、平原和弘、廣瀬文彦
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 室温原子層堆積法を用いたNb2O5積層コーティングの耐腐食特性2019

    • Author(s)
      吉田一樹、三浦正範、英傑、鹿又健作、廣瀬文彦
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 低温イットリア原子層堆積法の開発2019

    • Author(s)
      齋藤健太郎、鹿又健作、三浦正範、有馬ボシールアハンマド、久保田繁、廣瀬文彦
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Room-Temperature Atomic Layer Deposition of Aluminum Silicate for Molecule Sorption2018

    • Author(s)
      Yoshiharu Mori, Takahiro Imai, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota
    • Organizer
      233rd ECS Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thin film transistors using nanothick oxide channel for UV sensors2018

    • Author(s)
      K. Yoshida, K. Kikuchi, S. Saito, M. Miura, K. Kanomata, F. Hirose
    • Organizer
      AWAD 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Zeolite Thin Films by Room-temperature Atomic Layer Deposition2018

    • Author(s)
      Yoshiharu Mori, Yusuke Noguchi, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      ALD 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Low Temperature Atomic Layer Deposition of Yttrium Oxide using Plasma Excited Humidified Argon2018

    • Author(s)
      Kentaro Saito, Kentaro Tokoro, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      ALD 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 室温原子層堆積法を用いて形成したアルミナ膜による金属表面の耐腐食コート2017

    • Author(s)
      鹿又健作, 石川誠, 三浦正範, 有馬ボシールアハンマド, 久保田繁, 平原和弘, 廣瀬文彦
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Room-temperature atomic layer deposition for anticorrosion coatings2017

    • Author(s)
      Kensaku Kanomata, Makoto Ishikawa, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      8th International Workshop on Nanostructure & Nanoelectronics
    • Place of Presentation
      東北大学 電気通信研究所
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Room-temperature atomic layer deposition for nano particles and their applications to electronics devices2017

    • Author(s)
      Fumihiko Hirose, Ko Kikuchi, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota
    • Organizer
      8th International Workshop on Nanostructure & Nanoelectronics
    • Place of Presentation
      東北大学 電気通信研究所
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Room-Temperature Atomic Layer Deposition of Al2O3 for Anticorrosion Coating on Metal Surfaces2017

    • Author(s)
      Kensaku Kanomata, Makoto Ishikawa, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Kazuhiro Hirahara, Fumihiko Hirose
    • Organizer
      231st ECS Meeting
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Au Core-TiO2 Shell Nanoparticles Produced By RT Atomic Layer Deposition2017

    • Author(s)
      Fumihiko Hirose, Kensaku Kanomata, Masanori Miura, Ko Kikuchi, Bashir Ahmmad, Shigeru Kubota
    • Organizer
      231st ECS Meeting
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Room-temperature Atomic Layer Deposition of Al2O3 for Anticorrosion Coationgs2017

    • Author(s)
      Kensaku Kanomata, Makoto Ishikawa, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      ALD 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Room Temperature Atomic Layer Deposition of AlxSi1-xO and its Application for Dye Sensitized Solar Cells2017

    • Author(s)
      Takahiro Imai, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      ALD2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 赤外吸収分光を用いた樹脂膜上における室温原子層堆積過程の観察2017

    • Author(s)
      鹿又健作、三浦正範、有馬ボシールアハンマド、久保田繁、平原和弘、廣瀬文彦
    • Organizer
      第37回表面科学学術講演大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Room-temperature atomic layer deposition of zirconium oxide using plasma excited water vapor2016

    • Author(s)
      Kentaro Tokoro, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      ALD 2016 Ireland 16th International Conference on Atomic Layer Deposition
    • Place of Presentation
      コンベンションセンターダブリン(アイルランド)
    • Year and Date
      2016-07-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] RT plasma-excited atomic layer depostion of TiO2 on Au nanoparticles2016

    • Author(s)
      Ko Kikuchi, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      ALD 2016 Ireland 16th International Conference on Atomic Layer Deposition
    • Place of Presentation
      コンベンションセンターダブリン(アイルランド)
    • Year and Date
      2016-07-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] RT Atomic Layer Deposition of ZrO2 By Using Plasma Excited Water Vapor2016

    • Author(s)
      K. Kanomata, K. Tokoro, T. Imai, P. P. Pansila, M. Miura, B. Ahmmad, S. Kubota, K. Hirahara, F. Hirose
    • Organizer
      229th ECS Meeting
    • Place of Presentation
      ヒルトンサンディエゴベイフロント&サンディエゴコンベンションセンター(アメリカ合衆国)
    • Year and Date
      2016-05-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2020-03-30  

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