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Study on photoresponsive wettability switching by combination of topological surface structure and photo-generated carrier control

Research Project

Project/Area Number 16K17505
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nano/Microsystems
Research InstitutionRitsumeikan University

Principal Investigator

Kobayashi Taizo  立命館大学, 理工学部, 准教授 (20557433)

Research Collaborator KONISHI Satoshi  立命館大学, 理工学部, 教授
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords酸化チタン / ルチル型結晶構造 / 表面幾何学構造 / Cassie-Baxter表面 / 光触媒 / 光応答性 / 濡れ性スイッチング / 結晶構造 / バイアス電圧 / 超撥水性 / 超親水性 / 超撥水性/超親水性スイッチング / 微細加工 / マイクロ・ナノデバイス / 表面・界面物性 / 電子・電気材料
Outline of Final Research Achievements

Since surface tension becomes more dominant physical factor in microfluidic phenomenon, capillary pumping has been utilized as a passive liquid manipulation mechanism for lab-on-a-chip applications. In this project, widening of switching range of photoresponsive wettability on TiO2 photocatalyst was studied by applying topological micro-structure to its surface. The wettability reversal time was shorten from 180 min to 6 min by employing micro pillar array with T-shaped cross-sectional structure. Also, the rutile-TiO2 surface prepared by sputtering at higher substrate temperature (>500 C) showed wider and faster photoresponsive wettability change under UV irradiation with DC-bias voltages at around 0.9V.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (11 results)

All 2018 2017 2016 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 5 results) Remarks (2 results)

  • [Journal Article] Photoresponsive wettability switching of TiO2-coated micropillar arrays with different geometries of overhang roofs2017

    • Author(s)
      Kobayashi Taizo、Maeda Hironobu、Konishi Satoshi
    • Journal Title

      Micro&Nano Letters

      Volume: 12 Issue: 8 Pages: 540-544

    • DOI

      10.1049/mnl.2017.0121

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Patterning of wettability using the photocatalytic decomposition of hydrophobic SAM on the TiO2 pattern2017

    • Author(s)
      H. Maeda, T. Kobayashi, and S. Konishi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 結晶Seを用いたヘテロ接合フォトダイオードの光応答性へのデバイス作製条件の影響2018

    • Author(s)
      足立悠輔、小林大造
    • Organizer
      電気学会全国大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Acceleration of Wettability Switching on TiO2 Thin Films by Combination of UV Irradiation and DC-bias Voltages2018

    • Author(s)
      Taizo Kobayashi and Satoshi Konishi
    • Organizer
      Asia-Pacific Conference of Transducers and Micro-Nano Technology 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optically-driven gas generator by photovoltaic assisted photoelectrolysis using SE/TiO2 heterojunction structure2017

    • Author(s)
      Kobayashi Taizo、Konishi Satoshi
    • Organizer
      19th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoresponsive wettability switching on TiO2-coated micro pillar array with different geometric overhang roofs2016

    • Author(s)
      T. Kobayashi, H. Maeda, and S. Konishi
    • Organizer
      International Symposium on Micro-Nano Science and Technology 2016 (MNST2016)
    • Place of Presentation
      東京大学(東京都・文京区)
    • Year and Date
      2016-12-17
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Patterning of wettability using the photocatalytic decomposition of hydrophobic SAM on the TiO2 pattern2016

    • Author(s)
      H. Maeda, T. Kobayashi, and S. Konishi
    • Organizer
      29th International Microprocesses and Nanotechnology Conference (MNC2016)
    • Place of Presentation
      ANAクラウンプラザ京都(京都府・京都市)
    • Year and Date
      2016-11-11
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 反応性スパッタ法によるTiO2薄膜を用いたバイオケミカルデバイス用機能表面の開発2016

    • Author(s)
      小林大造, 小西聡
    • Organizer
      第33回「センサ・マイクロマシンと応用システム」シンポジウム
    • Place of Presentation
      平戸市文化センター(長崎県・平戸市)
    • Year and Date
      2016-10-24
    • Related Report
      2016 Research-status Report
  • [Presentation] Sputter-deposited TiO2 thin films with immobilized lactate dehydrogenase for potentiometric lactate sensing2016

    • Author(s)
      T. Kobayashi, and S. Konishi
    • Organizer
      Asia-Pacific Conference of Transducers and Micro-Nano Technology
    • Place of Presentation
      金沢文化ホール(石川県・金沢市)
    • Year and Date
      2016-06-28
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks]

    • URL

      http://research-db.ritsumei.ac.jp/Profiles/113/0011263/profile.html

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://research-db.ritsumei.ac.jp/Profiles/113/0011263/profile.html

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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