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Synthetic methods of heteroatom-doped graphene through photoirradiation

Research Project

Project/Area Number 16K17519
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionKyoto University

Principal Investigator

Utsunomiya Toru  京都大学, 工学研究科, 助教 (70734979)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsグラフェン / 原子層薄膜 / 光照射 / グラフェン誘導体 / 真空紫外光 / シリコン / 光還元 / 窒素 / 表面・界面物性
Outline of Final Research Achievements

Photoreduction of graphene oxide (GO) has been known to be attractive for synthesizing the graphene-derivatives with high-throughput. We have reported the vacuum ultraviolet light irradiation processes for synthesizing the reduced graphene oxide (rGO) under high vacuum. In this study, we tried to synthesize the heteroatom-doped rGO through the chemical reaction between precursor and GO, followed by the VUV light irradiation. The VUV irradiation to nitrogen doped GO sheets results in the pyridinic N formation, and in the decrease of the sheet thickness. These results indicates that the wavelength can control the photochemical modification of GO.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (25 results)

All 2018 2017 2016

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (18 results) (of which Int'l Joint Research: 7 results)

  • [Journal Article] Fabrication of reduced graphene oxide micro patterns by vacuum-ultraviolet irradiation: From chemical and structural evolution to improving patterning precision by light collimation2017

    • Author(s)
      Tu Yudi、Nakamoto Hiroshi、Ichii Takashi、Utsunomiya Toru、Khatri Om Prakash、Sugimura Hiroyuki
    • Journal Title

      Carbon

      Volume: 119 Pages: 82-90

    • DOI

      10.1016/j.carbon.2017.04.008

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhancing the electrical conductivity of vacuum-ultraviolet-reduced graphene oxide by multilayered stacking2017

    • Author(s)
      Tu Yudi、Utsunomiya Toru、Ichii Takashi、Sugimura Hiroyuki
    • Journal Title

      Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena

      Volume: 35 Issue: 3

    • DOI

      10.1116/1.4982722

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Immobilization of Reduced Graphene Oxide on Hydrogen-Terminated Silicon Substrate as a Transparent Conductive Protector2017

    • Author(s)
      Tu Yudi、Utsunomiya Toru、Kokufu Sho、Soga Masahiro、Ichii Takashi、Sugimura Hiroyuki
    • Journal Title

      Langmuir

      Volume: 33 Issue: 41 Pages: 10765-10771

    • DOI

      10.1021/acs.langmuir.7b01688

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vacuum ultraviolet trimming of oxygenated functional groups from oxidized self-assembled hexadecyl monolayers in an evacuated environment2017

    • Author(s)
      Soliman Ahmed I.A.、Utsunomiya Toru、Ichii Takashi、Sugimura Hiroyuki
    • Journal Title

      Applied Surface Science

      Volume: 416 Pages: 971-979

    • DOI

      10.1016/j.apsusc.2017.04.037

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Decoration of reduced graphene oxide by gold nanoparticles: an enhanced negative photoconductivity2017

    • Author(s)
      Wang Qi、Tu Yudi、Ichii Takashi、Utsunomiya Toru、Sugimura Hiroyuki、Hao Lifeng、Wang Rongguo、He Xiaodong
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 38 Pages: 14703-14709

    • DOI

      10.1039/c7nr05143c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vacuum-ultraviolet promoted oxidative micro photoetching of graphene oxide2016

    • Author(s)
      Yudi Tu, Toru Utsunomiya, Takashi Ichii, and Hiroyuki Sugimura
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: - Issue: 16 Pages: 10627-10635

    • DOI

      10.1021/acsami.6b00994

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photochemical Preparation of Alkoxy Self-Assembled Monolayers on Si from 1,2-Epoxyalkane Molecules2016

    • Author(s)
      Ahmed I. A. Soliman, Sho Kokufu, Toru Utsunomiya, Takashi Ichii, and Hiroyuki Sugimura
    • Journal Title

      Chemistry Letters

      Volume: - Issue: 5 Pages: 561-563

    • DOI

      10.1246/cl.160064

    • NAID

      130005150475

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 重水素ランプ照射による酸化グラフェンの光還元2018

    • Author(s)
      岡本 克文,米田 真,屠 宇迪,宇都宮 徹,一井 崇,杉村 博之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化グラフェン,酸化グラフェン還元体を触媒としたSi基板のケミカルエッチング2018

    • Author(s)
      石塚 隆高,宇都宮 徹,一井 崇,杉村 博之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Tribological study of alcohol-assisted photochemical reduction of graphene oxide2018

    • Author(s)
      Kunhua Yu,Makoto Yoneda, Yudi Tu,Toru Utsunomiya,Takashi Ichii,Hiroyuki Sugimura
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 光照射による窒素ドープグラフェンの作製と電気特性評価2017

    • Author(s)
      宇都宮徹,曽我正寛,屠宇迪,一井崇,杉村博之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 厚さ低減=還元? 酸化グラフェンの構造に関する新たな知見2017

    • Author(s)
      屠宇迪,宇都宮徹,一井崇,杉村博之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Heteroatom-doping to graphene oxide through the photo-irradiation techniques2017

    • Author(s)
      Toru Utsunomiya, Masahiro Soga, Yudi Tu, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      Symposium on Surface Science & Nanotechnology -25th Anniversary of SSSJ Kansai-
    • Place of Presentation
      Kyoto International Community House (KOKOKA), Kyoto, JAPAN
    • Year and Date
      2017-01-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] High-resolution patterning of graphene oxide on Si substrate by vacuum-ultraviolet photoreduction2017

    • Author(s)
      Yudi Tu,Toru Utsunomiya,Takashi Ichii,Hiroyuki Sugimura
    • Organizer
      Symposium on Surface Science & Nanotechnology -25th Anniversary of SSSJ Kansai-
    • Place of Presentation
      Kyoto International Community House (KOKOKA), Kyoto, JAPAN
    • Year and Date
      2017-01-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Heteroatom-doping to graphene oxide through the photochemical treatments using vacuum ultraviolet light2017

    • Author(s)
      Toru Utsunomiya, Masahiro Soga, Makoto Yoneda, Yudi Tu, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Correlation of chemical state and adhesion force to nanotribological properties of graphene oxide2017

    • Author(s)
      Kunhua Yu,Yudi Tu,Toru Utsunomiya,Takashi Ichii,Hiroyuki Sugimura
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化グラフェンの真空紫外光アシスト液相還元2017

    • Author(s)
      米田真,屠宇迪,宇都宮徹,一井崇,杉村博之
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Fabrication of Reduced Graphene Oxide Micro Patterns by Vacuum-ultraviolet Irradiation: from Chemical and Structural Evolution to Improving Patterning Precision2017

    • Author(s)
      Yudi Tu, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      Recent Progress in Graphene & 2D Materials Research (RPGR2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Vacuum-ultraviolet Photochemical Fabrication of Micro Conductive Reduced Graphene Oxide Patterns: Light Collimation to Improve Patterning Precision2017

    • Author(s)
      Yudi Tu, Toru Utsunomiya, Takashi Ichii, Om Prakash Khatri, Hiroyuki Sugimura
    • Organizer
      Grapchina2017 - International Graphene Innovation Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] VUV光化学反応による酸化グラフェンのヘテロ原子ドーピング2016

    • Author(s)
      曽我正寛,屠宇迪,宇都宮徹,一井崇,杉村博之
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学ポートアイランドキャンパス(神戸市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸化グラフェンの熱アシスト光還元2016

    • Author(s)
      屠宇迪,宇都宮徹,一井崇,杉村博之
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学ポートアイランドキャンパス(神戸市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] VUV-photoassisted Chemical Doping on Graphene Oxide2016

    • Author(s)
      Masahiro Soga, Yudi Tu, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      AVS 63rd International Symposium & Exhibition
    • Place of Presentation
      Music City Center, Nashville, Tennessee, USA
    • Year and Date
      2016-11-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhancing the Electrical Conductivity of VUV-reduced Graphene Oxide by Multilayered Stacking2016

    • Author(s)
      Yudi Tu,Toru Utsunomiya,Takashi Ichii,Hiroyuki Sugimura
    • Organizer
      AVS 63rd International Symposium & Exhibition
    • Place of Presentation
      Music City Center, Nashville, Tennessee, USA
    • Year and Date
      2016-11-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 酸化グラフェンのVUVデュアルドーピング2016

    • Author(s)
      曽我正寛,屠宇迪,宇都宮徹,一井崇,杉村博之
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] KMnO4/H+二次酸化による酸化グラフェンの蛍光増強2016

    • Author(s)
      屠宇迪,宇都宮徹,一井崇,杉村博之
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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