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Direct observation of infrared-stimulated hydrogen transfer in proton conducting oxides with positively charged muons

Research Project

Project/Area Number 16K17544
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Quantum beam science
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

Ito Takashi  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 原子力科学研究所 先端基礎研究センター, 研究副主幹 (10455280)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsミュオン / プロトン拡散 / 光誘起現象 / プロトン伝導 / 量子ビーム
Outline of Final Research Achievements

Infrared-irradiated muon spin relaxation measurements on KTaO3, SrTiO3, and rutile TiO2 were performed in the D1 area of J-PARC MLF to verify the infrared-stimulated proton transfer effect in proton conducting oxides that was proposed on the basis of infrared pump-probe studies. In this study, positively charged muons were used as a pseudoisotope of hydrogen and were implanted into the oxide samples to investigate the possible infrared-stimulated effect on their diffusion properties. A high-power xenon flash lamp was adopted as a source of infrared light. However, the infrared-stimulated effect on muon diffusion was not detected under this condition possibly due to insufficient light intensity. Further experiments are required with an upgraded light source.

Academic Significance and Societal Importance of the Research Achievements

本研究を通して、固体酸化物における赤外誘起水素拡散促進効果を検証するための実験的枠組みが確立し、今後解決すべき課題が明確になった。また、本研究課題の実施にあたりJ-PARC MLF D1エリアに整備した赤外照射ミュエスアール測定系は、本課題に限らず光誘起現象のミュエスアール研究に広く応用できるものであり、同施設における新たな研究の可能性を拓くという点において学術的意義が認められる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (10 results)

All 2019 2018 2017 2016

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Excited configurations of hydrogen in the BaTiO3-xHx perovskite lattice associated with hydrogen exchange and transport2017

    • Author(s)
      T. U. Ito, A. Koda, K. Shimomura, W. Higemoto, T. Matsuzaki, Y. Kobayashi, and H. Kageyama
    • Journal Title

      Phys. Rev. B

      Volume: 95 Issue: 2

    • DOI

      10.1103/physrevb.95.020301

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electronic Structure of Hydrogen Donors in Semiconductors and Insulators Probed by Muon Spin Rotation2016

    • Author(s)
      Koichiro Shimomura and Takashi U. Ito
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 85 Issue: 9 Pages: 091013-091013

    • DOI

      10.7566/jpsj.85.091013

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] n型SrTiO3中における擬似水素同位体ミュオニウムの電子状態2019

    • Author(s)
      伊藤孝,髭本亘,幸田章宏,下村浩一郎
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 常磁性金属におけるミュオン拡散の精密測定手法2018

    • Author(s)
      伊藤孝
    • Organizer
      金属中の水素の拡散と局在の現状と展開
    • Related Report
      2018 Annual Research Report
  • [Presentation] Contrasting roles of hydrogen in stoichiometric/oxygen-deficient SrTiO3: insights from MuSR spectroscopy2018

    • Author(s)
      伊藤孝
    • Organizer
      酸化物中における水素の存在状態と機能に関する研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Metastable configurations of hydrogen in the BaTiO3-xHx oxyhydride associated with hydrogen exchange and transport2017

    • Author(s)
      T. U. Ito, A. Koda, K. Shimomura, W. Higemoto, T. Matsuzaki, D. Tomono, Y. Kobayashi, and H. Kageyama
    • Organizer
      14th international conference on muon spin rotation, relaxation, and resonance
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electronic structure and dynamics of muonium in perovskite band insulators2017

    • Author(s)
      T. U. Ito, A. Koda, K. Shimomura, and W. Higemoto
    • Organizer
      14th international conference on muon spin rotation, relaxation, and resonance
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 薄膜成長用基板からのμSR信号:超低速ミュオンによる薄膜物性測定のための基礎研究2017

    • Author(s)
      伊藤孝,髭本亘,幸田章宏,下村浩一郎
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] LaAlO3における不純物水素の電子状態:疑似水素同位体ミュオニウムによる研究2017

    • Author(s)
      伊藤孝,髭本亘,幸田章宏,下村浩一郎
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学(大阪府豊中市)
    • Related Report
      2016 Research-status Report
  • [Presentation] ペロブスカイト型チタン酸化物誘電体における水素関連欠陥の電子状態2017

    • Author(s)
      伊藤孝
    • Organizer
      2016年度量子ビームサイエンスフェスタ
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2016 Research-status Report
    • Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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