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Establishment of the Novel Molecular Manipulation Technique using Localized Surface Plasmon Resonance

Research Project

Project/Area Number 16K17848
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

Minamimoto Hiro  北海道大学, 理学研究院, 助教 (80757279)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsプラズモン / 電気化学反応 / 化学反応制御技術 / 局在プラズモン / 表面増強ラマン散乱 / 分子制御技術 / ナノ界面
Outline of Final Research Achievements

In the present investigation, we have tried to establish the novel molecular manipulation method using localized surface plasmon resonance. Recently, several theoretical studies have expected that very small particles or molecules can be optically trapped in the strong optical field due to its spatial gradient. Based on this fact, we have attempted to observe the plasmonic molecular trapping behavior via surface-enhanced Raman scattering measurements. Furthermore, for the arbitrary control of the molecular trapping behavior, we have introduced the electrochemical method into the system which can control the molecular adsorption state at the metal surface. The present achievements would indicate the possibility for the realization of the future molecular control method and the arbitrary control of the localized chemical reactions.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (53 results)

All 2018 2017 2016

All Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (44 results) (of which Int'l Joint Research: 13 results,  Invited: 4 results) Book (1 results)

  • [Journal Article] Nanoscale Control of Plasmon-active Metal Nanodimer Structures via Electrochemical Metal Dissolution Reaction2018

    • Author(s)
      S. Oikawa, H. Minamimoto, X. Li, K. Murakoshi
    • Journal Title

      Nanotechnol.

      Volume: 29 Issue: 4 Pages: 045702-045702

    • DOI

      10.1088/1361-6528/aa9e78

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Active Tuning of Strong Coupling States between Dye Excitons and Localized Surface Plasmons via Electrochemical Potential Control2018

    • Author(s)
      F. Kato, H. Minamimoto, F. Nagasawa, Y. Yamamoto, T. Itoh, K. Murakoshi
    • Journal Title

      ACS Photon.

      Volume: 5 Issue: 3 Pages: 788-796

    • DOI

      10.1021/acsphotonics.7b00841

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sensitive Raman Probe of Electronic Interaction between Monolayer Graphene and Substrate under Electrochemical Potential Control2018

    • Author(s)
      R. Zhou, S. Yasuda, H. Minamimoto, K. Murakoshi
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 2 Pages: 2322-2328

    • DOI

      10.1021/acsomega.7b01928

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] In-situ Electrochemical Surface-Enhanced Raman Scattering Observation of Molecules Accelerating the Hydrogen Evolution Reaction2017

    • Author(s)
      Y. Yonezawa, H. Minamimoto, F. Nagasawa, M. Takase, S. Yasuda, K. Murakoshi
    • Journal Title

      J. Electroanal. Chem.

      Volume: 800 Pages: 7-12

    • DOI

      10.1016/j.jelechem.2017.04.049

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Control of Strong Coupling States Between Localized Surface Plasmons and Molecule Excitons for Raman Enhancement2017

    • Author(s)
      H. Minamimoto, F. Kato, F. Nagasawa, M. Takase, K. Murakoshi
    • Journal Title

      Faraday Discuss.

      Volume: 205 Pages: 261-269

    • DOI

      10.1039/c7fd00126f

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Electrochemical Tuning of Optical Property of Single Au Nano-bridged Structure via Electrochemical Under Potential Deposition2017

    • Author(s)
      S. Oikawa, H. Minamimoto, K. Murakoshi
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 8 Pages: 1148-1150

    • DOI

      10.1246/cl.170427

    • NAID

      130005906941

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Plasmonic Field Focused to Molecular Size2017

    • Author(s)
      H. Minamimoto, S. Oikawa, X. Li, K. Murakoshi
    • Journal Title

      Chem. Nano. Mat.

      Volume: 3 Issue: 12 Pages: 843-856

    • DOI

      10.1002/cnma.201700149

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visualization of Active Sites for Plasmon-Induced Electron Transfer Reactions using Photoelectrochemical Polymerization of Pyrrole2016

    • Author(s)
      H. Minamimoto, T. Toda, R. Futashima, X. Li, K. Suzuki, S. Yasuda, K.Murakoshi
    • Journal Title

      J. Phys. Chem. C

      Volume: 120(29) Issue: 29 Pages: 16051-16058

    • DOI

      10.1021/acs.jpcc.5b12727

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 同位体存在下における電気化学水素発生反応の分子挙動の解明2018

    • Author(s)
      南本大穂, 村越 敬
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電気化学的アプローチによる新規光-物質相自在制御の試み2018

    • Author(s)
      南本大穂, 加藤郁也, 村越 敬
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of Electrochemical Doping on Raman Spectrum of Single-Layer Graphene coupled with Metal Nanostructures2017

    • Author(s)
      J. Zhang, R. Zhou, H. Minamimoto, K. Murakoshi
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Research-status Report
  • [Presentation] Enhanced Photocurrent Generation of Size-Dependent PbS Quantum Dots by Coupling with Plasmonic Gold Nanoparticles2017

    • Author(s)
      X. Li, H. Minamimoto, S. Yasuda, K. Murakoshi
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Research-status Report
  • [Presentation] グラフェン/金属ナノ複合光電変換電極の界面電子状態評価2017

    • Author(s)
      安田健介, 南本大穂, 周 睿風, 保田 諭, 村越 敬
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気化学的アプローチによる金属ナノ構造のプラズモニック特性制御2017

    • Author(s)
      南本大穂, 及川隼平, 保田 諭, 村越 敬
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 表面増強ラマン散乱測定による電気化学水素発生下の水分子挙動の観測2017

    • Author(s)
      南本大穂, 村越 敬
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Research-status Report
  • [Presentation] Effect of Electrochemical Doping on Raman Spectra of Graphene Prepared on Various Substrates2017

    • Author(s)
      R. Zhou, H. Minamimoto, S. Yasuda, K. Murakoshi
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 新規光物質相の電気化学in-situ表面増強ラマン分光評価の試み2017

    • Author(s)
      加藤郁也, 南本大穂, 村越 敬
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気化学手法によるプラズモニック金属ナノ構造の光学特性自在制御2017

    • Author(s)
      及川隼平, 南本大穂, 村越敬
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 2次元金属ナノ微粒子配列構造における表面格子共鳴モードの電気化学制御2017

    • Author(s)
      柴崎ありす, 木村夏実, 及川隼平, 南本大穂, 村越 敬
    • Organizer
      化学系学協会北海道支部2017年冬季研究発表会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2017-01-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 金属ナノ構造担持p型半導体電極によるプラズモニック水素発生2017

    • Author(s)
      藤井桃子, 安田健介, X. Li, 南本大穂, 村越敬
    • Organizer
      化学系学協会北海道支部2017年冬季研究発表会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2017-01-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Plasmon Active Site for Nanosized Polymerization2017

    • Author(s)
      H. Minamimoto, J. Zhang, X. Li, K. Murakoshi
    • Organizer
      The 4th Optical Manipulation Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fine Tuning of Plasmonic Properties for Au Nano-Structures by Electrochemical Metal Dissolution/Deposition2017

    • Author(s)
      H. Minamimoto, S. Oikawa, K. Murakoshi
    • Organizer
      the 8th International Conference on Metamaterials, Photonic Crystals and Plasmonics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Surface-Enhanced Raman Scattering Measurements Monitoring Isotopic Effect on Hydrogen Evolution Reaction2017

    • Author(s)
      H. Minamimoto, K. Murakoshi
    • Organizer
      2017 International Workshop on Electrofield Interfaces for Energy Conversions
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Observation of Water/Deuterium Molecules on Hydrogen Evolution Process via Surface Enhanced Raman Scattering Measurements2017

    • Author(s)
      H. Minamimoto, K. Murakoshi
    • Organizer
      The 28th International Conference on Photochemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Observation of Isotopic Effect on Hydrogen Evolution Process using In-situ Electrochemical Surface Enhanced Raman Scattering2017

    • Author(s)
      H. Minamimoto, K. Murakoshi
    • Organizer
      the 8th International Conference on Metamaterials, Photonic Crystals and Plasmonics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 局所反応活性サイトの可視化による電気化学水素発生反応の同位体効果の解明2017

    • Author(s)
      南本大穂, 村越 敬
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 表面増強ラマン散乱測定を用いた電気化学水素発生反応における同位体効果の解明2017

    • Author(s)
      南本大穂, 村越 敬
    • Organizer
      第11回分子化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電気化学手法を用いたプラズモニック金属ナノ構造の極限幾何形状制御2017

    • Author(s)
      南本大穂, 及川隼平, 村越 敬
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 表面増強ラマン散乱を用いた固液界面における水素発生プロセスの解明2017

    • Author(s)
      南本大穂, 及川隼平, 村越 敬
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Au二量体ナノ構造間隙の電気化学制御2017

    • Author(s)
      及川隼平, 南本大穂, 村越 敬
    • Organizer
      第33 回ライラックセミナー・第23 回若手研究者交流会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電気化学Auナノ構造制御と顕微散乱分光評価2017

    • Author(s)
      及川隼平, 南本大穂, 村越 敬
    • Organizer
      ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ラマン分光法によるプラズモニック光電変換系における電荷移動過程評価2017

    • Author(s)
      安田健介, 南本大穂, 周 睿風, 保田 諭, 村越 敬
    • Organizer
      ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electrochemical Tuning of Gap Distance of Au Nanodimer in a Single nm Scale2017

    • Author(s)
      S. Oikawa, H. Minamimoto, K. Murakoshi
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] In-situ Surface-Enhanced Raman Scattering Observation of Water Molecules at Hydrogen Evolution Electrodes2016

    • Author(s)
      H. Minamimoto, S. Yasuda, K. Murakoshi
    • Organizer
      9th Asian Photochemistry Conference
    • Place of Presentation
      Singapole
    • Year and Date
      2016-12-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photocurrent Generation of PbS Nanopartciles with Narrower Bandgap coupled with Localized Surface Plasmon Resonance2016

    • Author(s)
      X. Li, H. Minamimoto, K. Murakoshi
    • Organizer
      PRiME 2016
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] プラズモニック光電変換極における電子移動過程の解明2016

    • Author(s)
      南本大穂, 戸田貴大, 保田 諭, 村越 敬
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Fabrication of Graphene Composite Plasmon-Active Photoelectrode2016

    • Author(s)
      K. Yasuda, H. Minamimoto, R. Zhou, S. Yasuda, K. Murakoshi
    • Organizer
      第51回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      かでる2.7(北海道札幌市)
    • Year and Date
      2016-09-09
    • Related Report
      2016 Research-status Report
  • [Presentation] Electrochemical Tuning of Gap Distance of Au Nanodimer in a Single nm Scale2016

    • Author(s)
      S. Oikawa, N. Kimura, H. Minamimoto, K. Murakoshi
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Optical Properties of Dye Molecules in Strongly Coupled with Localized Surface Plasmons by Electrochemical in-situ Surface-Enhanced Raman Scattering Measurements2016

    • Author(s)
      F. Kato, Y. Wakisaka, H. Minamimoto, K. Murakoshi
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Precise Control of Plasmon-Active Au Nano-Structures using Electrochemical Method2016

    • Author(s)
      K. Murakoshi, S. Oikawa, A. Ohnuki, S. Yasuda, H. Minamimoto
    • Organizer
      7th Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Hague, Netherlands
    • Year and Date
      2016-08-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Observation of Water Molecules at Hydrogen Evolution Process using in-situ Electrochemical Surface-Enhanced Raman Scattering2016

    • Author(s)
      H. Minamimoto, S. Yasuda, K. Murakoshi
    • Organizer
      7th Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Hague, Netherlands
    • Year and Date
      2016-08-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhanced Photo-Electrochemical Response of Size-Dependent PbS Quantum Dots Excited by Localized Surface Plasmon Resonance2016

    • Author(s)
      X. Li, T. Toda, H. Minamimoto, K. Murakoshi
    • Organizer
      7th Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Hague, Netherlands
    • Year and Date
      2016-08-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electronic Excitation induced by Confined Electromagnetic Filed at Electrified Interfaces2016

    • Author(s)
      H. Minamimoto, S. Yasuda, K. Murakoshi
    • Organizer
      the XIVth International Conference on Electrified Interfaces
    • Place of Presentation
      Singapole
    • Year and Date
      2016-07-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 局所光電場空間内における電気化学反応の観察2016

    • Author(s)
      南本大穂
    • Organizer
      第32回ライラックセミナー・第22回若手研究者交流会
    • Place of Presentation
      おたる自然の村おこばち山荘(北海道小樽市)
    • Year and Date
      2016-06-26
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 電気化学制御下における強結合分子系のin-situ分光評価2016

    • Author(s)
      加藤郁也, 脇坂優美, 南本大穂, 村越 敬
    • Organizer
      第32回ライラックセミナー・第22回若手研究者交流会
    • Place of Presentation
      おたる自然の村おこばち山荘(北海道小樽市)
    • Year and Date
      2016-06-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 半導体基板上でのAu/グラフェンハイブリッド構造の構築とその光物性評価2016

    • Author(s)
      安田健介, 南本大穂, 保田 諭, 周 睿風, 村越 敬
    • Organizer
      第32回ライラックセミナー・第22回若手研究者交流会
    • Place of Presentation
      おたる自然の村おこばち山荘(北海道小樽市)
    • Year and Date
      2016-06-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気化学的酸化溶解反応によるAuナノ構造制御2016

    • Author(s)
      及川隼平, 大貫温順, 木村夏実, 南本大穂, 村越 敬
    • Organizer
      第32回ライラックセミナー・第22回若手研究者交流会
    • Place of Presentation
      おたる自然の村おこばち山荘(北海道小樽市)
    • Year and Date
      2016-06-25
    • Related Report
      2016 Research-status Report
  • [Presentation] プラズモン誘起化学反応における局所反応活性サイトの可視化2016

    • Author(s)
      南本大穂, 戸田貴大, 二嶋 諒, 保田 諭, 村越 敬
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Year and Date
      2016-06-15
    • Related Report
      2016 Research-status Report
  • [Presentation] Auナノ二量体構造のin-situ電気化学顕微散乱分光評価2016

    • Author(s)
      及川隼平, 大貫温順, 木村夏実, 南本大穂, 村越 敬
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Year and Date
      2016-06-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 強結合分子系の電気化学in-situ表面増強ラマン散乱観測2016

    • Author(s)
      加藤郁也, 脇坂優美, 南本大穂, 村越 敬
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Year and Date
      2016-06-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Plasmon-Induced Deposition of Conductive Polymer on Au Nanostructured TiO2 Electrode2016

    • Author(s)
      K. Murakoshi, H. Minamimoto, T. Toda, X. Li
    • Organizer
      229th ECS Meeting
    • Place of Presentation
      San Diego, America
    • Year and Date
      2016-05-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evolution of Surface-Enhanced Raman Scattering Intensity at Metal Surface under Electrochemical Potential Control2016

    • Author(s)
      K. Murakoshi, Y. Wakisaka, M. Takase, H. Minamimoto, S. Yasuda, S. Ito, H. Miyasaka, T. Shoji, Y. Tsuboi
    • Organizer
      The 3rd Optical Manipulation Conference
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2016-05-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] Frontiers of Plasmon Enhanced Spectroscopy Volume 12016

    • Author(s)
      X. Li, H. Minamimoto, S. Yasuda, K. Murakoshi
    • Total Pages
      17
    • Publisher
      ACS Books
    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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