| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Outline of Final Research Achievements |
We aimed to apply the rotaxane's intramolecular mobility and cooperative effect on asymmetric catalytic reactions. Rotaxane consists of a ring molecule and a penetrating axle component potentially having dynamic behavior depend on the mechanical linkage. In order to apply such a cooperative effect of rotaxane to asymmetric catalytic reaction, we designed chiral rotaxane catalyst for asymmetric reaction. Furthermore, the selective synthesis and kinetic resolution of rotaxane having molecular chirality attribute to the combination of unsymmetrical components were investigated.
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