| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Outline of Final Research Achievements |
The curved aromatic compounds have been expected to show the unique physical properties derived from their π-conjugated systems. In this study, the synthesis of belt-like polycyclic aromatic system was studied by performing a thermal self-cycloaddition of the isobenzofuran containing an electron-acceptor moiety. Two approaches for the donor-acceptor molecules were developed by utilizing either bisaryne or bisisobenzofuran as the reactive platforms, which enabled the construction of belt-like polycyclic molecules.
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