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Synthetic studies of belt-like hydrocarbons using the reactive platforms

Research Project

Project/Area Number 16K17873
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionKwansei Gakuin University

Principal Investigator

Kitamura Kei  関西学院大学, 理工学部, 助教 (00756695)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsベルト状分子 / 環化付加反応 / イソベンゾフラン / アライン / ポリアセン / ドナー・アクセプター分子 / 高反応性分子 / シクラセン / シクロイプチセン
Outline of Final Research Achievements

The curved aromatic compounds have been expected to show the unique physical properties derived from their π-conjugated systems. In this study, the synthesis of belt-like polycyclic aromatic system was studied by performing a thermal self-cycloaddition of the isobenzofuran containing an electron-acceptor moiety. Two approaches for the donor-acceptor molecules were developed by utilizing either bisaryne or bisisobenzofuran as the reactive platforms, which enabled the construction of belt-like polycyclic molecules.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (10 results)

All 2018 2017 2016

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] 1,3-Dialkyny- and 1,3-dialkenyl-isobenzofurans: new π-extended congeners prepared by double nucleophilic addition of alkynyllithiums to o-phthalaldehyde2017

    • Author(s)
      工藤涼司、北村圭、羽村季之
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 1 Pages: 25-28

    • DOI

      10.1246/cl.160884

    • NAID

      130005308325

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Water-soluble 1,3-Diarylisobenzoheterols: Syntheses and Characterization2017

    • Author(s)
      戸澤仁志、北村圭、羽村季之
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 5 Pages: 703-706

    • DOI

      10.1246/cl.170137

    • NAID

      130005655717

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] キノイド型合成ブロックを活用する置換ポリアセンの合成2018

    • Author(s)
      北村 圭,工藤涼司,羽村季之
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 拡張型アセン分子の系統的合成と機能開発2018

    • Author(s)
      北村圭
    • Organizer
      日本化学会新領域研究グループ 有機合成化学を起点とするものづくり戦略 中間研究報告会
    • Related Report
      2017 Annual Research Report
  • [Presentation] π拡張型ルブレンを活用する高次縮環芳香族化合物の合成研究2017

    • Author(s)
      北村 圭,長井由作,張 可樹,羽村季之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] イソナフトフランを合成ブロックとする置換ペンタセンおよび置換ヘキサセンの合成研究2017

    • Author(s)
      工藤涼司,北村 圭,羽村季之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 水溶性イソベンゾヘテロールの合成2017

    • Author(s)
      戸沢仁志,北村 圭,羽村季之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Synthesis, Properties, and Reactivity of π-Extended Rubrene Derivatives2017

    • Author(s)
      Kei Kitamura, Kenta Asahina, Yusaku Nagai, Keshu Zhang, Toshiyuki Hamura
    • Organizer
      The 11th International Symposium on Integrated Synthesis (ISONIS-11) and The 3rd International Symposium on Middle Molecular Strategy (ISMMS-3)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] π拡張ルブレンを基盤とする高次縮環芳香族化合物の合成2016

    • Author(s)
      北村 圭
    • Organizer
      機能性ナノ単一サイズ有機分子創製研究 パイスター分子制御による未来型物質変換研究拠点 2016年度合同シンポジウム
    • Place of Presentation
      関西学院大学 神戸三田キャンパス(兵庫県三田市)
    • Year and Date
      2016-12-16
    • Related Report
      2016 Research-status Report
  • [Presentation] π拡張型ルブレン類の合成と物性2016

    • Author(s)
      北村 圭,朝比奈健太,長井由作,張 可樹,羽村季之
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場(広島県広島市)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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