Synthetic studies of belt-like hydrocarbons using the reactive platforms
Project/Area Number |
16K17873
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Organic chemistry
|
Research Institution | Kwansei Gakuin University |
Principal Investigator |
Kitamura Kei 関西学院大学, 理工学部, 助教 (00756695)
|
Project Period (FY) |
2016-04-01 – 2018-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | ベルト状分子 / 環化付加反応 / イソベンゾフラン / アライン / ポリアセン / ドナー・アクセプター分子 / 高反応性分子 / シクラセン / シクロイプチセン |
Outline of Final Research Achievements |
The curved aromatic compounds have been expected to show the unique physical properties derived from their π-conjugated systems. In this study, the synthesis of belt-like polycyclic aromatic system was studied by performing a thermal self-cycloaddition of the isobenzofuran containing an electron-acceptor moiety. Two approaches for the donor-acceptor molecules were developed by utilizing either bisaryne or bisisobenzofuran as the reactive platforms, which enabled the construction of belt-like polycyclic molecules.
|
Report
(3 results)
Research Products
(10 results)