Synthesis of asymmetrically edge-functionalized graphene nanoribbons
Project/Area Number |
16K17893
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Functional solid state chemistry
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Research Institution | Kyoto University |
Principal Investigator |
NAKAE Takahiro 京都大学, エネルギー理工学研究所, 助教 (20505995)
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Project Period (FY) |
2016-04-01 – 2018-03-31
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Project Status |
Completed (Fiscal Year 2017)
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Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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Keywords | グラフェンナノリボン / 多環式芳香族炭化水素 / 表面重合 / キラリティー / 分子ひずみ |
Outline of Final Research Achievements |
Graphene nanoribbons (GNRs) are expected to show excellent properties, which depends on their molecular width and edge-structures. Bottom-up syntheses of GNRs are indispensable method for fabrication with atomically-precise controlled manner. We established effective GNR synthesis as 2-zone chemical vapor deposition method. In this project, I proposed synthesis of asymmetrically edge-functionalized GNRs. We found molecular torsion on surface plays a critical role on surface reaction. We reported biomimetic surface polymerization and strain-induced skeletal rearrangement. These findings pave the way to create new bottom-up nanocarbon materials.
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Report
(3 results)
Research Products
(43 results)
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[Journal Article] Template Synthesis of Decaphyrin without Meso-Bridges: Cyclo[10]pyrrole2016
Author(s)
T. Okujima, C. Ando, S. Agrawal, H. Matsumoto, S. Mori, K. Ohara, I. Hisaki, T. Nakae, M. Takase, H. Uno, and N. Kobayashi
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Journal Title
journal of the American Chemical Society
Volume: 138
Issue: 24
Pages: 7540-7543
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Presentation] Observation of azulene-to-fulvalene rearrangement by AFM2016
Author(s)
A. Shiotari, K. Iwata, T. Nakae, Y. Shinagawa, S. Mori, T. Okujima, H. Uno, H. Sakaguchi, Y. Sugimoto
Organizer
24th International Colloquium on Scanning Probe Microscopy
Place of Presentation
Honolulu, Hawaii, USA
Year and Date
2016-12-14
Related Report
Int'l Joint Research
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