| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
Graphene nanoribbons (GNRs) are expected to show excellent properties, which depends on their molecular width and edge-structures. Bottom-up syntheses of GNRs are indispensable method for fabrication with atomically-precise controlled manner. We established effective GNR synthesis as 2-zone chemical vapor deposition method. In this project, I proposed synthesis of asymmetrically edge-functionalized GNRs. We found molecular torsion on surface plays a critical role on surface reaction. We reported biomimetic surface polymerization and strain-induced skeletal rearrangement. These findings pave the way to create new bottom-up nanocarbon materials.
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