Development of atom-economical synthesis of novel semiconducting materials with electron-deficient moiety
| Project/Area Number |
16K17908
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 直接アリール化反応 / ドナー・アクセプター型分子 / チエノイソインディゴ / 有機薄膜太陽電池 / ドナーアクセプター構造 / 有機半導体材料 / 有機薄膜トランジスタ / 高分子合成 / 導電性高分子 |
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| Outline of Final Research Achievements |
The atom-economical synthesis of donor-acceptor semiconducting materials with an electron-deficient thienoisoindigo (TIG) moiety has been investigated. The desired materials were successfully synthesized under the direct arylation condition by utilizing a monomer design based on a catalytic cycle of direct arylation. Furthermore, an organic photovoltaics study using an obtained polymer was also achieved. To the best of my knowledge, this is the first OPV study using a TIG-based polymer synthesized by the direct arylation.
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Report
(3 results)
Research Products
(5 results)
