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Eco-friendly polymerization by using ionic liquid

Research Project

Project/Area Number 16K17911
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionJapan Advanced Institute of Science and Technology (2017)
Kanazawa University (2016)

Principal Investigator

Takada Kenji  北陸先端科学技術大学院大学, 先端科学技術研究科, 特任助教 (10772171)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsリビング重合 / 有機分子触媒 / イオン液体 / セルロース / アニオン重合 / グループトランスファー重合
Outline of Final Research Achievements

Ionic liquid catalyzed polymerization was carried out by using methyl methacrylate and 1-ethyl-3-methylimidazolium type ionic liquid as a monomer and catalyst, respectively. Although ionic liquids different in anionic species were used as catalysts, those that showed polymerization ability were only ionic liquids with acetate anions of 1-ethyl-3-methylimidazolium acetate. By using the catalytic activity of 1-ethyl-3-methylimidazolium acetate, the transesterification reaction of cellulose proceeded very highly efficiently. Further, the ionic liquid was separated (recycled) from the solution after the reaction, and the same reaction was carried out once again, and it showed reactivity equivalent to that before recycling. From these results, it can be said that this research is an eco-friendly method and a new reaction system that can synthesize naturally occurring materials.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (15 results)

All 2017 2016

All Journal Article (8 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 8 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results)

  • [Journal Article] Alkylated alkali lignin for compatibilizing agents of carbon fiber-reinforced plastics with polypropylene2017

    • Author(s)
      Sakai Hiroki、Kuroda Kosuke、Muroyama Shiori、Tsukegi Takayuki、Kakuchi Ryohei、Takada Kenji、Hata Ayano、Kojima Ryosuke、Ogoshi Tomoki、Omichi Masaaki、Ninomiya Kazuaki、Takahashi Kenji
    • Journal Title

      Polymer Journal

      Volume: 50 Issue: 3 Pages: 281-284

    • DOI

      10.1038/s41428-017-0009-3

    • NAID

      120006766282

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bio-based mesoporous sponges of chitosan conjugated with amino acid-diketopiperazine through oil-in-water emulsions2017

    • Author(s)
      Kenji Takada, Hongrong Yin, Tomoaki Matsui, Tatsuo Kaneko
    • Journal Title

      Journal of Polymer Research

      Volume: 24 Issue: 12 Pages: 216-216

    • DOI

      10.1007/s10965-017-1372-7

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of thermotropic polybenzoxazole using 3-amino-4-hydroxybenzoic acid2017

    • Author(s)
      4)Mohammad Asif Ali, Hiroshi Shimosegawa, Aniruddha Nag, Kenji Takada, Tatsuo Kaneko
    • Journal Title

      Journal of Polymer Research

      Volume: 24 Issue: 12 Pages: 214-214

    • DOI

      10.1007/s10965-017-1362-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recyclable and scalable organocatalytic transesterification of polysaccharides in a mixed solvent of 1-ethyl-3-methylimidazolium acetate and dimethyl sulfoxide2017

    • Author(s)
      Van Nguyen Quy、Nomura Shuhei、Hoshino Rina、Ninomiya Kazuaki、Takada Kenji、Kakuchi Ryohei、Takahashi Kenji
    • Journal Title

      Polymer Journal

      Volume: 49 Issue: 11 Pages: 783-787

    • DOI

      10.1038/pj.2017.49

    • NAID

      40021359863

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective dissolution of biomass in ionic liquids by irradiation of non-thermal atmospheric pressure plasma2017

    • Author(s)
      Kosuke Kuroda, Kai Shimomura, Tatsuo Ishijima, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      Australian Journal of Chemistry

      Volume: 印刷中 Issue: 6 Pages: 731-734

    • DOI

      10.1071/ch16554

    • NAID

      120005860226

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Efficient hydrolysis of polysaccharides in bagasse by in situ synthesis of an acidic ionic liquid after pretreatment2016

    • Author(s)
      Heri Satria, Kosuke Kuroda (co-first author), Takatsugu Endo, Kenji Takada, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 5 Issue: 1 Pages: 708-713

    • DOI

      10.1021/acssuschemeng.6b02055

    • NAID

      120005860227

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Intramolecular olefin metathesis as a robust tool to synthesize single-chain nanoparticles in a size-controlled manner2016

    • Author(s)
      渡部航大;田中涼斗;高田健司;Myung-Jin Kim;Jae-Suk Lee;田島健次;磯野拓也;佐藤敏文
    • Journal Title

      Polymer Chemistry

      Volume: 7 Issue: 29 Pages: 4782-4792

    • DOI

      10.1039/c6py00795c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Hydrolysis of cellulose using an acidic and hydrophobic ionic liquid, and subsequent separation of glucose aqueous solution from the ionic liquid and 5-(hydroxymethyl)furfural2016

    • Author(s)
      Kosuke Kuroda, Kyohei Miyamura, Heri Satria, Kenji Takada, Kazuaki Ninomiya, Kenji Takahashi
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 4 Issue: 6 Pages: 3352-3356

    • DOI

      10.1021/acssuschemeng.6b00420

    • NAID

      120005860228

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 溶融成型性に優れたセルロース誘導体の合成と複合樹脂への応用2017

    • Author(s)
      高田健司、星野莉奈、川島尚大、前場拓貴、覚知亮平、大道正明、高橋憲司
    • Organizer
      第66回高分子年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Strong Organic Acid-Catalyzed Precise Synthesis of Acrylate Polymers2017

    • Author(s)
      Kenji Takada, Tatsuo Kaneko, Toshifumi Satoh, Toyoji Kakuchi
    • Organizer
      Satellite Symposium in Todai Japan-South-East Asia Collaboration Hub of Bioplastics Study JSPS-Core-to-Core Program
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Eco-friendly organocatalytic precise synthesis of polyacrylates2017

    • Author(s)
      Kenji Takada, Toyoji Kakuchi, Tatsuo Kaneko
    • Organizer
      The 3rd Symposium of the Center for Nature-derived Materials (Excellent Core) and The 3rd International Symposium for Green-Innovation Polymers (GRIP2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transesterification reactions of cellulose in a mixture of ionic liquid and dimethyl sulfoxide2016

    • Author(s)
      Shuhei Nomura, Makoto Yamaguchi, Ryo Ito, Ryohei Kakuchi, Kenji Takada, Tomoyuki Ikai, Kazuaki Ninomiya, Katsuhiro Maeda, Kenji Takahashi
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      福岡コンベンションセンター(福岡)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] イオン液体の有機分子触媒能を活用したセルロースのエステル交換反応の反応最適化2016

    • Author(s)
      野村周平、山口誠、伊藤僚、覚知亮平、高田健司、井改知幸、仁宮一章、前田勝浩、高橋憲司
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市文化ホール(石川)
    • Year and Date
      2016-10-24
    • Related Report
      2016 Research-status Report
  • [Presentation] Optimization of ionic liquid-catalyzed transesterification reactions of cellulose2016

    • Author(s)
      Shuhei Nomura, Makoto Yamaguchi, Ryo Ito, Ryohei Kakuchi, Kenji Takada, Tomoyuki Ikai, Kazuaki Ninomiya, Katsuhiro Maeda, Kenji Takahashi
    • Organizer
      6th International IUPAC Conference on Green Chemistry
    • Place of Presentation
      Centro Culturale Candiani(イタリア)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] イオン液体の有機分子触媒能を利用したセルロースのエステル交換反応に及ぼす共溶媒の効果2016

    • Author(s)
      野村周平、山口誠、伊藤僚、覚知亮平、高田健司、井改知幸、仁宮一章、前田勝浩、高橋憲司
    • Organizer
      セルロース学会 第23回年次大会
    • Place of Presentation
      つくばカピオ(茨城)
    • Year and Date
      2016-07-13
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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