| Project/Area Number |
16K17913
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 有機―無機ハイブリッド / ナノゲル / 粒子サイズ検出 / 脂肪酸認識 / フッ素NMR / 生理活性アミン / かご型シルセスキオキサン / 有機―無機ハイブリッドナノゲル / 微粒子センサー / 常磁性フッ素化ナノゲル / フッ素ＮＭＲ / アミン化合物センサー / 脂肪酸センサー / 高分子化学 / 機能性高分子 / 無機高分子 / 有機ー無機ハイブリッド |
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| Outline of Final Research Achievements |
To develop novel sensing materials by using hybrid nano-gel, POSS which consists of eight organic substituents and alternate Si-O bonds to form cage structures with Si atoms as vertices, was used. Hybrid nano-gels were formed by cross-linking POSS units with bithiophene or triphenylamine. Nano-gel composed of bithiophene showed different fluorescent peaks depending on size of silica particles. Moreover, different emission behaviors of triphenylamine-bonded nano-gel were observed by comparing trans-fatty acid with cis-fatty acid. On the other hand, mixture of nano-gel induced fluorine derivatives and paramagnetic compounds detected bioactive amino compounds by changing signals of 19 fluorine NMR. From these results, our hybrid nano-gels shows its potential applications in various fields such as detectors by using photo- and magnetic- stimuli.
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