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Developments of a new time resolved XAFS measurement scheme and its application for chemical reactions in microseconds on electrodes

Research Project

Project/Area Number 16K17925
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

UEMURA Yohei  分子科学研究所, 物質分子科学研究領域, 助教 (30723647)

Research Collaborator YOKOYAMA Toshihiko  分子科学研究所, 教授
ASAKURA Kiyotaka  北海道大学, 触媒科学研究所, 教授
WADA Takahiro  東京医科歯科大学, 助教
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
KeywordsX線吸収分光 / 時間分解 / X線吸収 / 放射光 / XAFS / 光励起 / 電気化学
Outline of Final Research Achievements

In this project, a new time resolved x-ray absorption fine structure (XAFS) method was tried to be established. XAFS is an important method to understand chemical states on electrodes of batteries or fuel cells. However, chemical reactions of the electrodes cannot be observed with XAFS since the time resolution of XAFS is much slower than the reaction time scales of the electrode chemical reaction. In this new system, a time stamp is decided at the same time each fluorescence x-ray photon from a sample is detected. It was confirmed that the principle of this measurement was plausible.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (4 results)

All 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results) Book (2 results)

  • [Journal Article] Ultra-Fast XAFS Studies on Photocatalyst Using SACLA2017

    • Author(s)
      上村 洋平, 脇坂 祐輝, 城戸 大貴, 高草木 達, 朝倉 清高, 丹羽 尉博
    • Journal Title

      Nihon Kessho Gakkaishi

      Volume: 59 Issue: 1 Pages: 24-28

    • DOI

      10.5940/jcrsj.59.24

    • NAID

      130005437784

    • ISSN
      0369-4585, 1884-5576
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Survey of the structural changes of photoexcited WO3 using “larch”2017

    • Author(s)
      Y. Uemura, A. Koide, T. Yokoyama, D. Kido, Y. Wakisaka, S. Takakusagi, K. Asakura
    • Organizer
      Q2XAFS2017 (Diamond Light Source, United Kingdom)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] XAFS Techniques for Catalysis, Nanomaterials and Surfaces2017

    • Author(s)
      上村洋平他
    • Total Pages
      556
    • Publisher
      Springer
    • Related Report
      2016 Research-status Report
  • [Book] X-ray and Neutron Techniques for Nanomaterials Characterization2017

    • Author(s)
      上村洋平他
    • Total Pages
      830
    • Publisher
      Springer
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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