Orienetd growth of crystalline organic-inorganic hybrid materials on metal hydroxides
| Project/Area Number |
16K17967
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Osaka Prefecture University (2017)
Osaka University (2016) |
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Principal Investigator |
OKADA Kenji 大阪府立大学, 工学(系)研究科(研究院), 助教 (30750301)
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| Co-Investigator(Renkei-kenkyūsha) |
TAKAHASHI Masahide 大阪府立大学, 大学院工学研究科, 教授 (20288559)
TOKUDOME Yasuaki 大阪府立大学, 大学院工学研究科, 准教授 (50613296)
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| Research Collaborator |
Paolo Falcaro Graz University of Technology, Institute of Physical and Theoretical Chemistry, 教授
Doonan Christian The University of Adelaide, Centre for Advanced Nanomaterials, 教授
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | Metal organic frameworks / 金属水酸化物 / 多孔質材料 / 配向 / エピタキシャル成長 / Metal Organic Frameworks / 配向薄膜 / 多孔質 / 金属有機構造体 / 無機工業材料 / エピタキシャル / セラミックス / ナノ材料 / 表面・界面物性 |
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| Outline of Final Research Achievements |
Thin films of porous materials are of great interest for various applications such as separation, storage, electronics and photonics. It has long been expected a pore alignment in a large scales exceeding cm-scale. However, the formation of thin films with alignment of pores remains a significant challenge especially for microporous crystalline materials including zeolite and metal-organic frameworks (MOFs). In the present study, we succeeded to achieve perfectly oriented MOF films on the cm-scale using metal hydroxides as a substrate. Optical devises with anisotropic properties could be fabricated by impregnating functional molecules into the aligned micropores of the oriented MOF film. The details are described in [Nature Mater., 2017, 16, 342.]
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Report
(3 results)
Research Products
(13 results)
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[Journal Article] Centimetre scale micropore alignment in oriented polycrystalline Metal-Organic Framework films via heteroepitaxial growth2017
Author(s)
Falcaro P., Okada K., Hara T., Ikigaki K., Tokudome Y., Thornton A.W., Hill A.J., Williams T., Doonan C., Takahashi M.,
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Journal Title
Nature Mater.
Volume: 16
Issue: 3
Pages: 342-348
DOI
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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