• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Orienetd growth of crystalline organic-inorganic hybrid materials on metal hydroxides

Research Project

Project/Area Number 16K17967
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionOsaka Prefecture University (2017)
Osaka University (2016)

Principal Investigator

OKADA Kenji  大阪府立大学, 工学(系)研究科(研究院), 助教 (30750301)

Co-Investigator(Renkei-kenkyūsha) TAKAHASHI Masahide  大阪府立大学, 大学院工学研究科, 教授 (20288559)
TOKUDOME Yasuaki  大阪府立大学, 大学院工学研究科, 准教授 (50613296)
Research Collaborator Paolo Falcaro  Graz University of Technology, Institute of Physical and Theoretical Chemistry, 教授
Doonan Christian  The University of Adelaide, Centre for Advanced Nanomaterials, 教授
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
KeywordsMetal organic frameworks / 金属水酸化物 / 多孔質材料 / 配向 / エピタキシャル成長 / Metal Organic Frameworks / 配向薄膜 / 多孔質 / 金属有機構造体 / 無機工業材料 / エピタキシャル / セラミックス / ナノ材料 / 表面・界面物性
Outline of Final Research Achievements

Thin films of porous materials are of great interest for various applications such as separation, storage, electronics and photonics. It has long been expected a pore alignment in a large scales exceeding cm-scale. However, the formation of thin films with alignment of pores remains a significant challenge especially for microporous crystalline materials including zeolite and metal-organic frameworks (MOFs). In the present study, we succeeded to achieve perfectly oriented MOF films on the cm-scale using metal hydroxides as a substrate. Optical devises with anisotropic properties could be fabricated by impregnating functional molecules into the aligned micropores of the oriented MOF film. The details are described in [Nature Mater., 2017, 16, 342.]

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (13 results)

All 2017 2016 Other

All Int'l Joint Research (4 results) Journal Article (2 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (5 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Remarks (2 results)

  • [Int'l Joint Research] グラーツ工科大学(オーストリア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] アデレード大学(オーストラリア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] CSIRO/アデレード大学/モナシュ大学(オーストラリア)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] グラーツ工科大学(オーストリア)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Electrochemical sensor and catalyst on Cu3(BTC)2 coating electrode from Cu(OH)2 films2017

    • Author(s)
      Kenji Okada , Shota Sawai , Ken Ikigaki , Yasuaki Tokudome , Paolo Falcaro and Masahide Takahashi
    • Journal Title

      CrystEngComm

      Volume: 印刷中 Issue: 29 Pages: 4194-4200

    • DOI

      10.1039/c7ce00416h

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Centimetre scale micropore alignment in oriented polycrystalline Metal-Organic Framework films via heteroepitaxial growth2017

    • Author(s)
      Falcaro P., Okada K., Hara T., Ikigaki K., Tokudome Y., Thornton A.W., Hill A.J., Williams T., Doonan C., Takahashi M.,
    • Journal Title

      Nature Mater.

      Volume: 16 Issue: 3 Pages: 342-348

    • DOI

      10.1038/nmat4815

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] シングルナノの細孔が一方向を向いた金属有機構造体(MOF)薄膜 ~金属水酸化物薄膜上でのエピタキシャル成長~2017

    • Author(s)
      岡田健司
    • Organizer
      日本セラミックス協会 2017年 年会
    • Place of Presentation
      日本大学(東京都・千代田区)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Micropore aligned films based on Metal Organic Frameworks heteroepitaxially-grown on metal hydroxide scaffold2017

    • Author(s)
      K. Okada, K. Ikigaki, M. Takahashi, P. Falcaro, C. Doonan, Y. Tokudome, K. Machida
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 機金属水酸化物が導く金属有機構造体(MOF)のエピタキシャル成長2017

    • Author(s)
      岡田健司
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 1-Dimensional Metal Hydroxide Nanomaterials:Alignment and surface functionalization2016

    • Author(s)
      Kenji Okada
    • Organizer
      The 2nd International Conference on NanoMaterials
    • Place of Presentation
      Mauritius
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属水酸化物ナノ構造体の形成による機能性表面の創出2016

    • Author(s)
      岡田健司、町田憲一
    • Organizer
      日本セラミックス協会関西支部
    • Place of Presentation
      大阪大学中之島センター(大阪府・大阪市)
    • Related Report
      2016 Research-status Report
  • [Remarks] 大面積でナノサイズの穴が全て同じ方向を向いた多孔質MOF薄膜の合成に、世界で初めて成功

    • URL

      http://resou.osaka-u.ac.jp/ja/research/2016/20161206_1

    • Related Report
      2016 Research-status Report
  • [Remarks] Lining up metal–organic frameworks

    • URL

      http://www.nature.com/nmat/journal/v16/n3/index.html#af

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi