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Ultra-grain refinement as prevention against hydrogen-assisted crack propagation

Research Project

Project/Area Number 16K17981
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Materials/Mechanics of materials
Research InstitutionKyushu University

Principal Investigator

MACADRE ARNAUD  九州大学, カーボンニュートラル・エネルギー国際研究所, 学術研究員 (20635891)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordshydrogen embrittlement / austenite / grain refinement / steel / 環境材料 / 水素
Outline of Final Research Achievements

Grain size refinement led to a large increase of yield stress. Hydrogen charging at different hydrogen pressures (10, 40 and 100 MPa) led to a hydrogen-induced decrease of ductility in the alloy. The ultra-fine grain material (1 micron grains) still retained an elongation of 30% under the highest hydrogen content. There is a solid solution strengthening effect of hydrogen. Hydrogen embrittlement requires larger hydrogen contents in smaller grained material. There was no evidence of cracking of martensite-austenite boundaries, i.e. martensite transformation did not appear as a factor for susceptibility to hydrogen. Large solute hydrogen contents delay the formation of strain-induced martensite and completely cancel it at low strains. There was no effect of grain size on strain-induced martensite, with or without hydrogen. Finally, cracking in small grains seems to be dominated by ductile tensile overload while cracking in large grains is dominated by hydrogen-induced crack propagation.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (10 results)

All 2017 2016

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Hydrogen-induced increase in phase stability in metastable austenite of various grain sizes under strain2017

    • Author(s)
      Macadre Arnaud、Tsuchiyama Toshihiro、Takaki Setsuo
    • Journal Title

      Journal of Materials Science

      Volume: 52 Pages: 3419-3428

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hydrogen-induced increase in phase stability in metastable austenite of various grain sizes under strain2017

    • Author(s)
      Arnaud MACADRE, Toshihiro TSUCHIYAMA, Setsuo TAKAKI
    • Journal Title

      Journal of Materials Science

      Volume: 52 Issue: 6 Pages: 3419-3428

    • DOI

      10.1007/s10853-016-0630-0

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Determination of hydrogen compatibility for solution-treated austenitic stainless steels based on a newly proposed nickel-equivalent equation2016

    • Author(s)
      Takaki, S., Nanba, S., Imakawa, K., Macadre, A., Yamabe, J., Matsunaga, H. and Matsuoka, S.
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 41 Issue: 33 Pages: 15095-15100

    • DOI

      10.1016/j.ijhydene.2016.06.193

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] In-situ SEM/EBSD observation of hydrogen-assisted cracking of ultra-fine grained austenite2017

    • Author(s)
      A. Macadre, T. Tsuchiyama, S. Takaki
    • Organizer
      5th International Symposium on Steel Science (ISSS2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] SEM/EBSD tensile testing of hydrogen-charged austenitic steel with ultra-fine grains2017

    • Author(s)
      A. Macadre, T. Tsuchiyama, S. Takaki
    • Organizer
      EUROMAT 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Comparison of fatigue crack tips with ultra-fine grains in metastable austenite and stable austenite2017

    • Author(s)
      A. Macadre, T. Tsuchiyama, S. Takaki
    • Organizer
      International Workshop on Giant Straining Process for Advanced Materials (GSAM2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] nvestigating grain size as a means to reduce hydrogen embrittlement2016

    • Author(s)
      A. Macadre, T. Tsuchiyama, S. Takaki
    • Organizer
      2016 International Hydrogen Conference
    • Place of Presentation
      JACKSON LAKE LODGE
    • Year and Date
      2016-09-11
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of various hydrogen contents and grain sizes on tensile behaviour of metastable austenite2016

    • Author(s)
      A. Macadre, T. Tsuchiyama, S. Takaki
    • Organizer
      PRICM 9
    • Place of Presentation
      Kyoto International Conference Center
    • Year and Date
      2016-08-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Cracking in austenite: effect of ultra-fine grained metastable austenite2016

    • Author(s)
      A. Macadre, K. Mori, M. Kubota, T. Tsuchiyama, S. Takaki
    • Organizer
      THERMEC 2016
    • Place of Presentation
      Messe Congrez Graz
    • Year and Date
      2016-05-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Using ultra-grain refinement in austenite: evolution of properties with and without hydrogen2016

    • Author(s)
      A. Macadre, T. Tsuchiyama, S. Takaki, K. Mori, R. Mori, M. Kubota
    • Organizer
      328th Committee on Fatigue Materials of JSMS
    • Place of Presentation
      Kyushu University
    • Related Report
      2016 Research-status Report
    • Invited

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Published: 2016-04-21   Modified: 2019-03-29  

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