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Development of novel membranes with embedded zirconium-based adsorbent for phosphate removal and recovery from wastewater

Research Project

Project/Area Number 16K18175
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Civil and environmental engineering
Research InstitutionChuo University

Principal Investigator

Hafuka Akira  中央大学, 理工学部, 助教 (30735353)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords高分子膜 / ポリスルフォン / 限外ろ過膜 / リン除去回収 / 吸着剤 / ジルコニウム / 脱着 / 下廃水 / 硫酸ジルコニウム-界面活性剤ミセルメソ構造体 / 固液分離 / 消化脱離液 / 放流下水 / 水処理膜 / リン回収 / 硫酸ジルコニウム-界面活性剤ミセルメソ多孔体 / リン吸着 / 資源回収
Outline of Final Research Achievements

We developed novel membranes that could adsorb phosphate from water through membrane filtration for use in a phosphate removal and recovery system. Zirconium sulfate surfactant micelle mesostructure (ZS), which was the phosphate adsorbent, was embedded in a polysulfone matrix and flat sheet ultrafiltration membranes were prepared. Scanning electron microscopy showed that the ZS particles existed on both the top surface and in the internal surface of the membrane. The amount of phosphate adsorbed on the membrane with the 100 um thickness made from the polymer solution containing 10.5 wt% ZS was 0.039 mg P/cm2 during filtration of 50 mg P/L synthetic phosphate solution. The membrane could be repeatedly used for phosphate recovery after regeneration by filtration of 0.1 M NaOH solution to desorb the phosphate. We applied the membrane to treat the effluent from an anaerobic membrane bioreactor as a real sample and successfully adsorbed phosphate.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (9 results)

All 2018 2017 2016 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results) (of which Int'l Joint Research: 4 results) Remarks (1 results)

  • [Journal Article] Development of novel polysulfone membranes with embedded zirconium sulfate-surfactant micelle mesostructure for phosphate recovery from water through membrane filtration2017

    • Author(s)
      Furuya Kenji、Hafuka Akira、Kuroiwa Miho、Satoh Hisashi、Watanabe Yoshimasa、Yamamura Hiroshi
    • Journal Title

      Water Research

      Volume: 124 Pages: 521-526

    • DOI

      10.1016/j.watres.2017.08.005

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 下廃水中からのリン回収に向けたジルコニウム-メソ構造体包含ポリスルフォン膜の開発2018

    • Author(s)
      古屋謙治、羽深昭、黒岩美帆、山村寛、佐藤久、渡辺義公
    • Organizer
      第52回日本水環境学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ジルコニウム-メソ多孔体を包含したリン回収多機能膜の開発2017

    • Author(s)
      古屋謙治,羽深昭,黒岩美帆,山村寛,佐藤久,渡辺義公
    • Organizer
      第51回日本水環境学会年会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
  • [Presentation] Development of a novel polysulfone membrane with embedded zirconium compound for phosphate recovery from water2017

    • Author(s)
      A. Hafuka, K. Furuya, H. Satoh, Y. Watanabe, and H. Yamamura
    • Organizer
      8th International Young Water Professionals Conference (IWA IYWPC 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a novel polysulfone membrane with embedded zirconium compound for phosphate recovery from water2017

    • Author(s)
      A. Hafuka, K. Furuya, H. Yamamura, H. Satoh, and Y. Watanabe
    • Organizer
      7th IWA-ASPIRE Conference 2017 (Aspire2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a functionalized membrane for phosphate recovery from water2017

    • Author(s)
      A. Hafuka, K. Furuya, H. Yamamura, H. Satoh, and Y. Watanabe
    • Organizer
      8th IWA Membrane Technology Conference & Exhibition for Water and Wastewater Treatment and Reuse (IWA-MTC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a novel polysulfone membrane with embedded zirconium compound for phosphate recovery from water2017

    • Author(s)
      K. Furuya, A. Hafuka, H. Yamamura, H. Satoh, and Y. Watanabe
    • Organizer
      The 2nd International Resource Recovery Conference (IRRC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] リン吸着能を有するジルコニウム担持分離膜の開発2016

    • Author(s)
      古屋謙治,羽深昭,黒岩美帆,佐藤久,渡辺義公,山村寛
    • Organizer
      第53回環境工学研究フォーラム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2016-12-06
    • Related Report
      2016 Research-status Report
  • [Remarks] 中央大学理工学部水代謝システム工学研究室

    • URL

      http://yamamura.waterblue.ws/

    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2019-03-29  

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