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Engineering of crystallization of glasses using control of glass structure and induction of large stress

Research Project

Project/Area Number 16K18233
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Shinozaki Kenji  国立研究開発法人産業技術総合研究所, 無機機能材料研究部門, 研究員 (10723489)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsガラス / 結晶化 / ガラスセラミックス / 応力誘起 / 格子欠陥 / ナノ結晶 / 蛍光 / 長残光 / 酸フッ化物 / アップコンバージョン / 結晶化ガラス / 無機工業化学 / 結晶成長 / 結晶工学 / 光物性
Outline of Final Research Achievements

This study was carried out to control precipitated crystalline phase, morphology and function by utilizing stress and defect induced by crystallization of glass or glass structure. For example, by synthesizing typical fluorescent crystals and afterglow crystals via the glass state, we succeeded in fluorescence shift and high temperature phase precipitation. In addition, based on the design of the glass structure, a novel borate-based BaF2 nanocrystallized glass was developed. By reducing the particle size of the nanocrystal to 8 nm, high transparency comparable to glass was obtained. In addition, excellent up-conversion characteristics were obtained due to low phonon energy of BaF2 by heat treatment crystallization.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (48 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (11 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 1 results) Presentation (30 results) (of which Int'l Joint Research: 8 results,  Invited: 4 results) Remarks (2 results) Patent(Industrial Property Rights) (4 results)

  • [Int'l Joint Research] Coe College(米国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Control of self-powdering phenomenon in ferroelastiic beta'-Gd2(MoO4)3 crystallization in boro-tellurite glasses2018

    • Author(s)
      M. Kotaka, T. Honma, T. Komatsu, K. Shinozaki, M. Affatigato, R. Müller
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 印刷中 Pages: 85-92

    • DOI

      10.1016/j.jnoncrysol.2017.12.006

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Tb 3+ -doped BaF 2 -Al 2 O 3 -B 2 O 3 glass and glass-ceramic for radiation measurements2018

    • Author(s)
      Okada Go、Shinozaki Kenji、Komatsu Takayuki、Kawano Naoki、Kawaguchi Noriaki、Yanagida Takayuki
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: - Pages: 101-105

    • DOI

      10.1016/j.jnoncrysol.2018.02.013

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Luminescence of Ce 3+ in aluminophosphate glasses prepared in air2018

    • Author(s)
      Masai Hirokazu、Shinozaki Kenji、Okada Go、Kawaguchi Noriaki、Ina Toshiaki、Yanagida Takayuki
    • Journal Title

      Journal of Luminescence

      Volume: 195 Pages: 413-419

    • DOI

      10.1016/j.jlumin.2017.11.063

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterizations of Pr-doped Yb 3 Al 5 O 12 single crystals for scintillator applications2018

    • Author(s)
      Yoshida Yasuki、Shinozaki Kenji、Igashira Takuya、Kawano Naoki、Okada Go、Kawaguchi Noriaki、Yanagida Takayuki
    • Journal Title

      Solid State Sciences

      Volume: 78 Pages: 1-6

    • DOI

      10.1016/j.solidstatesciences.2018.02.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Scintillation and VUV-excited photoluminescence of europium-doped BaF2?Al2O3?B2O3 glasses2018

    • Author(s)
      Shinozaki Kenji、Fujimoto Yutaka、Okada Go、Kawaguchi Noriaki、Yanagida Takayuki、Akai Tomoko、Koshimizu Masanori、Asai Keisuke
    • Journal Title

      Journal of Materials Science: Materials in Electronics

      Volume: 印刷中 Issue: 14 Pages: 11824-11829

    • DOI

      10.1007/s10854-018-9282-y

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of photoluminescence of glass phosphor by nanoimprint of moth-eye structure2017

    • Author(s)
      Kenji SHINOZAKI, Ryosuke KAMAKURA, Shunsuke MURAI, Toshiyuki MIHARA, Naoyuki KITAMURA, Yuki KAWACHIYA, Katsuhisa TANAKA, Tomoko AKAI
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 10 Pages: 766-769

    • DOI

      10.2109/jcersj2.17069

    • NAID

      130006110742

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient red-emitting BaMgBO3F:Eu3+,R+ (R: Li, Na, K, Rb) phosphor for near-UV excitation synthesized via glass precursor solid-state reaction2017

    • Author(s)
      Shinozaki Kenji、Akai Tomoko
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 9 Pages: 092601-092601

    • DOI

      10.7567/jjap.56.092601

    • NAID

      210000148264

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Radiophotoluminescence in Sm-doped BaF2-Al2O3-B2O3 glass-ceramics2017

    • Author(s)
      Go Okada, Kenji Shinozaki, Takayuki Komatsu, Safa Kasap, Takayuki
    • Journal Title

      RADIATION MEASUREMENTS

      Volume: inpress Pages: 73-78

    • DOI

      10.1016/j.radmeas.2016.12.006

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nano-crystallization and highly oriented crystal line patterning of Bi2GeO5 and Bi4Ge3O12 in Sm2O3-Bi2O3-GeO2 glasses2017

    • Author(s)
      Yang Cunlei, Kenji Shinozaki, Tsuyoshi Honma, Takayuki Komatsu
    • Journal Title

      JOURNAL OF NON-CRYSTALLINE SOLIDS

      Volume: 459 Pages: 116-122

    • DOI

      10.1016/j.jnoncrysol.2017.01.001

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Long Afterglow in Hexagonal SrAl2O4:Eu2+, Dy3+ Synthesized by Crystallization of Glass and Solidification of Supercooled Melts2016

    • Author(s)
      Kenji Shinozaki, Tsuyoshi Honma, Mario Affatigato, Takayuki Komatsu
    • Journal Title

      JOURNAL OF LUMINESCENCE

      Volume: 177 Pages: 286-289

    • DOI

      10.1016/j.jlumin.2016.05.013

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Dielectric properties of glass-ceramics with Ba1-xY2x/3Nb2O6 nanocrystals and laser patterning of highly oriented crystal lines2016

    • Author(s)
      S. Hasegawa, K. Shinozaki, T. Honma, V. Dimitrov, H.G. Kim, T. Komatsu
    • Journal Title

      JOURNAL OF NON-CRYSTALLINE SOLIDS

      Volume: 452 Pages: 74-81

    • DOI

      10.1016/j.jnoncrysol.2016.08.024

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] フツホウ酸系BaF2透明ナノ結晶化ガラスの創製と蛍光特性2018

    • Author(s)
      篠崎 健二、小仲 凌太、赤井 智子
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Ce3+ドープ50BaF2-25Al2O3-25B2O3ガラスの構造と蛍光およびシンチレーション特性2018

    • Author(s)
      篠崎 健二、岡田 豪、河口 範明、柳田 健之、赤井 智子
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ce添加CaF2-Al2O3-B2O3ガラスのドシメータ特性2018

    • Author(s)
      加藤 匠、平野 翔太郎、佐溝 隼大、岡田 豪、河口 範明、柳田 健之、篠崎 健二、正井 博和
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] (2018年度進歩賞受賞講演)ガラス構造と結合性に基づき設計された新規光機能ガラス及び結晶化ガラスの創成2018

    • Author(s)
      篠崎 健二
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高ケイ酸ガラス中の希土類のシンチレーション発光2018

    • Author(s)
      赤井 智子、篠崎 健二、山下 勝、岡田 豪、河口 範明、柳田 健之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Tb-Rbドープシリカの真空紫外光及びX線励起による発光特性2018

    • Author(s)
      赤井 智子、篠崎 健二、正井 博和、山下 勝、岡田 豪、河口 範明、柳田 健之
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 新規フツホウ酸ガラスの光学特性と放射光X線による構造解析2018

    • Author(s)
      篠崎 健二、尾原 幸治、赤井 智子
    • Organizer
      The 28th Meeting on Glasses for Photonics
    • Related Report
      2017 Annual Research Report
  • [Presentation] CsPO3-CsCl-CeX 3(X=Cl, Br)-Al(PO3)3系ガラスシンチレータの研究2018

    • Author(s)
      藤本 裕、柳田 健之、中内 大介、加賀美 佳、篠崎 健二、越水 正典、赤井 智子、浅井 圭介
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Eu添加BaF2-Al2O3-B2O3結晶化ガラスのRPL特性2018

    • Author(s)
      岡田 豪、篠崎 健二、河口 範明、柳田 健之
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Mg2+およびZn2+を添加したフツホウ酸ガラスの構造および結晶化と発光特性2018

    • Author(s)
      篠崎 健二、赤井 智子
    • Organizer
      第58回ガラスおよびフォトニクス材料討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フツホウ酸ガラス中のFの局所構造とAlおよびMgが及ぼすガラス構造への効果2018

    • Author(s)
      篠崎 健二、助永 壮平、柴田 浩幸、赤井 智子
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フッ化物導入によるガラスの構造制御と高効率蛍光2018

    • Author(s)
      篠崎 健二
    • Organizer
      第12回日本セラミックス協会関西支部学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 蛍光ガラスへのナノインプリンティングによる蛍光強度への効果2017

    • Author(s)
      篠崎健二、三原敏行、北村直之、赤井智子
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山市
    • Year and Date
      2017-01-12
    • Related Report
      2016 Research-status Report
  • [Presentation] Impact of stress formation on crystal structure and luminescence in glass-ceramics synthesized by crystallization of glass and supercooled melt2017

    • Author(s)
      Kenji Shinozaki, Tomoko Akai, Mario Affatigato, Takayuki Komatsu
    • Organizer
      2th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12), including Glass & Optical Materials Division Meeting (GOMD 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Tin-phosphate glass with crystal-like open structure2017

    • Author(s)
      Akihiko Sakamoto, Kenji Shinozaki, Tsuyoshi Honma, Takayuki Komatsu
    • Organizer
      2th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12), including Glass & Optical Materials Division Meeting (GOMD 2017)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ZnO添加が及ぼすBaF2-B2O3ガラスのガラス構造および結晶化挙動への効果とアップコンバージョン特性2017

    • Author(s)
      篠崎 健二、小仲 凌太、赤井 智子
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Long-Persistent Luminescence of High Temperature Phase of SrAl2O4 Synthesized by Crystallization of Glass2017

    • Author(s)
      Kenji Shinozaki, Mario Affatigato, Takayuki Komatsu
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Highly Efficient Photoluminescence of Eu3+, Deep UV Transmission Window, and Glass Structure in Fluoroborate Glasses with Highly Fluoride Content2017

    • Author(s)
      Kenji Shinozaki, Sohei Sukenaga, Hiroyuki Shibata, Tomoko Akai
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ガラス蛍光体へのサブ波長周期パターンのナノインプリントによる反射損失の低減と発光方位の制御2017

    • Author(s)
      篠崎健二、鎌倉涼介、村井俊介、三原敏行、北村直之、田中勝久、赤井智子
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      横浜市
    • Related Report
      2016 Research-status Report
  • [Presentation] 過冷却融液の結晶化によるY3Al5O12:Ceの合成と蛍光波長シフト2017

    • Author(s)
      篠崎健二、赤井智子、Mario Affatigato、小松高行
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      横浜市
    • Related Report
      2016 Research-status Report
  • [Presentation] Surface deformation and indentation-induced stress in various nanocrystallized glasses2016

    • Author(s)
      Kenji Shinozaki, Tsuyoshi Honma, Takayuki Komatsu
    • Organizer
      Glass & Optical Materials Division Meeting 2016
    • Place of Presentation
      Madison (USA)
    • Year and Date
      2016-05-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of afterglow glass-ceramics with SrAl2O4 from SrO-Al2O3 supercooled melt2016

    • Author(s)
      Kenji Shinozaki, Mikiya Kotaka, Tsuyoshi Honma, Mario Affatigato, Takayuki Komatsu
    • Organizer
      Glass & Optical Materials Division Meeting 2016
    • Place of Presentation
      Madison (USA)
    • Year and Date
      2016-05-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ガラス及び過冷却融液からの高温相SrAl2O4:Eu2+,Dy3+合成と長残光特性2016

    • Author(s)
      篠崎健二、赤井智子、小松高行
    • Organizer
      日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      大阪市
    • Related Report
      2016 Research-status Report
  • [Presentation] 希土類添加フツホウ酸ガラスおよびナノ結晶化ガラスの蛍光特性2016

    • Author(s)
      篠崎健二、赤井智子、本間剛、小松高行
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟市
    • Related Report
      2016 Research-status Report
  • [Presentation] フツホウ酸ガラスの構造と光学的特性2016

    • Author(s)
      篠崎健二、赤井智子、小松高行
    • Organizer
      応用物理学会関西支部平成28年度第1回講演会
    • Place of Presentation
      池田市
    • Related Report
      2016 Research-status Report
  • [Presentation] MgF2-BaO-B2O3系フツホウ酸ガラスの構造と結晶化挙動及び光学的特性2016

    • Author(s)
      篠崎健二、山下勝、北村直之、赤井智子、本間剛、小松高行
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      東大阪市
    • Related Report
      2016 Research-status Report
  • [Presentation] RPL in Sm-doped BaF2-Al2O3-B2O3 glass ceramics2016

    • Author(s)
      Go Okada, Kenji Shinozaki, Takayuki Komatsu, Safa Kasap, Takayuki
    • Organizer
      18th International Conference on Solid State Dosimetry
    • Place of Presentation
      ミュンヘン
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Long Afterglow in Hexagonal SrAl2O4:Eu2+, Dy3+ Glass-ceramics Synthesized Using Levitation Melting Technique2016

    • Author(s)
      Kenji Shinozaki, Mikiya Kotaka, Tsuyoshi Honma, Mario Affatigato, Takayuki Komatsu
    • Organizer
      International Symposium on the Science of Engineering Ceramics
    • Place of Presentation
      新潟市
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly Efficient Photoluminescence of Eu3+ in Fluoroborate Glass with Related Composition of BaMgBO3F2016

    • Author(s)
      Kenji Shinozaki, Tomoko Akai, Takayuki Komatsu
    • Organizer
      CerSJ-GOMD Joint Symposium on Glass Science and Technologies
    • Place of Presentation
      京都
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] High quantum yield and low concentration quenching of Eu3+ emission in fluoroborate glasses and nanocrystallized glasses2016

    • Author(s)
      Kenji Shinozaki, Tomoko Akai, Takayuki Komatsu
    • Organizer
      2016 MRS Fall Meeting
    • Place of Presentation
      Boston (USA)
    • Related Report
      2016 Research-status Report
  • [Remarks] 産総研-篠崎 健二

    • URL

      https://staff.aist.go.jp/k-shinozaki/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 産総研-篠崎健二

    • URL

      https://staff.aist.go.jp/k-shinozaki/

    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] ガラス蛍光体および照明装置2017

    • Inventor(s)
      篠崎 健二、三原 敏行、北村 直之、赤井 智子
    • Industrial Property Rights Holder
      篠崎 健二、三原 敏行、北村 直之、赤井 智子
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-250732
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] ガラス蛍光体および照明装置2017

    • Inventor(s)
      篠崎 健二、三原 敏行、村井 俊介、田中 勝久、他
    • Industrial Property Rights Holder
      篠崎 健二、三原 敏行、村井 俊介、田中 勝久、他
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-250731
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] ガラス組成物、その製造方法、ガラス組成物を用いた蛍光体およびガラス組成物を用いた蛍光体およびガラス組成物を用いた紫外透過光学部材2017

    • Inventor(s)
      篠崎 健二、赤井 智子
    • Industrial Property Rights Holder
      篠崎 健二、赤井 智子
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-116527
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 化合物、それを用いた蛍光体、および化合物の製造方法2017

    • Inventor(s)
      篠崎 健二、赤井 智子
    • Industrial Property Rights Holder
      篠崎 健二、赤井 智子
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-090952
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2022-06-07  

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