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Creation of ZnO nano-bulk thermoelectric conversion materials incorporating metal nanoparticles by using soft-chemical precursors

Research Project

Project/Area Number 16K18248
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Research InstitutionKyushu University

Principal Investigator

Watanabe Kosuke  九州大学, エネルギー基盤技術国際教育研究センター, 助教 (40617007)

Research Collaborator OHTAKI Michitaka  九州大
SUEKUNI Koichiro  九州大
SUGAHARA Tohru  大阪大
SUEMATSU Koichi  九州大
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsナノコンポジット / 液相前駆体法 / 酸化物 / ナノ構造制御 / フォノン散乱 / 機能性複合材料 / 酸化物熱電変換材料 / 金属ナノ粒子 / 酸化亜鉛 / 複合材料 / 無機工業材料 / ナノ構造形成・制御
Outline of Final Research Achievements

Nanopowders consisting of ZnO and the Au nanoparticles with diameters of ca. 50 nm and 3 nm were prepared from soft-chemical precursors. Mixtures of this nanopowders and Al2O3 powders were molded, and sintered by using the spark plasma sintering method. The nanocomposites embedding Au nanoparticles (d < 40 nm) in the Al doped ZnO matrix were obtained the addition 0.15 mol% amount of Au. The nanocomposites were achieved not only a decrease in the thermal conductivity due to selective phonon scattering but also an increase in the electrical conductivity at the same time. Consequently, it was shown that nanocomposites incorporating such metal nanoparticles were a guideline for material design of new thermoelectric materials.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (17 results)

All 2018 2017 2016

All Journal Article (4 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (13 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] 金属ナノ粒子を導入した酸化物系ナノ複合体の形成と熱・電気輸送特性2018

    • Author(s)
      渡邊厚介
    • Journal Title

      セラミックス

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultraselective Toluene Gas Sensor: Nanosized Gold Loaded on Zinc Oxide Nanoparticles2018

    • Author(s)
      Koichi Suematsu, Kosuke Watanabe, Akihiro Tou, Yonjiao Sun, Kengo Shimanoe
    • Journal Title

      Analytical Chemistry

      Volume: 90 Issue: 3 Pages: 1959-1966

    • DOI

      10.1021/acs.analchem.7b04048

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] ZnO上へのAuナノ粒子担持による選択的トルエン感知2018

    • Author(s)
      末松昂一、渡邊厚介、島ノ江憲剛
    • Journal Title

      Proceedings of the 63rd Chemical Sensor Symposium Supplement A

      Volume: 34 Pages: 85-87

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Mechanically Stable Mixed Metal Oxide of Cu and Mn as Oxygen Carrier for Chemical Looping Syngas Combustion2016

    • Author(s)
      Sandra Sajen, Sunit Kumar Singh, Pallavi Mungse, Sadhana Rayalu, Kosuke Watanabe, Govindachetty Saravanan, Nitin Labhasetwar
    • Journal Title

      Energy Fuels

      Volume: 30 Issue: 9 Pages: 7596-7603

    • DOI

      10.1021/acs.energyfuels.6b01433

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] ZnO上へのAuナノ粒子担持による選択的トルエン検知2018

    • Author(s)
      末松昂一、渡邊厚介、島ノ江憲剛
    • Organizer
      第63回化学センサ研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 極細Auナノワイヤの生成反応における条件依存性2017

    • Author(s)
      石橋史啓、渡邊厚介、大瀧倫卓
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶應技術大学日吉キャンパス(横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Thermoelectric Properties of ZnO with Au Nanoparticles Dispersed therein2017

    • Author(s)
      Kosuke Watanabe, Kazuki Mine, Koichiro Suekuni, Michitaka Ohtaki
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design (ISEPD2017)
    • Place of Presentation
      沖縄県市町村自治会館(那覇)
    • Year and Date
      2017-02-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Controlling factors for Formation Reaction of Ultrathin Au Nanowires2017

    • Author(s)
      Fumihiro Ishibashi, Kosuke Watanabe, Michitaka Ohtaki
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design (ISEPD2017)
    • Place of Presentation
      沖縄県市町村自治会館(那覇)
    • Year and Date
      2017-02-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属ナノ粒子を導入したZnO系ナノコンポジットの形成と熱電特性2017

    • Author(s)
      渡邊厚介、峯一貴、末國晃一郎、大瀧倫卓
    • Organizer
      日本セラミックス協会平成29年度九州支部秋季合同研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] SrTiO3/TiNコアシェル構造ナノ粒子の合成と熱電ナノコンポジット化2017

    • Author(s)
      松﨑彰剛、渡邊厚介、末國晃一郎、大瀧倫卓
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Auナノ粒子を導入したAl:ZnOナノコンポジットの構造と熱電特性2017

    • Author(s)
      峯一貴、渡邊厚介、末國晃一郎、大瀧倫卓
    • Organizer
      第14回日本熱電学会学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ZnO焼結体への金属ナノ粒子分散プロセスと熱電特性2016

    • Author(s)
      渡邊厚介、小川敏史、大瀧倫卓
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス(東広島市)
    • Year and Date
      2016-09-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Ag/ZnOナノコンポジットの形成と熱電特性2016

    • Author(s)
      渡邊厚介、峯一貴、大瀧倫卓
    • Organizer
      第13回日本熱電学会学術講演会(TSJ2016)
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] 極細Auナノワイヤの液相合成2016

    • Author(s)
      石橋史啓、渡邊厚介、大瀧倫卓
    • Organizer
      第6回九州若手セラミックフォーラム(KYCF-6)&第46回窯業基礎九州懇話会
    • Place of Presentation
      ルートイングランティア太宰府(太宰府市)
    • Year and Date
      2016-08-26
    • Related Report
      2016 Research-status Report
  • [Presentation] ゾルゲル法を用いたZnOナノ粒子のTiO2被覆2016

    • Author(s)
      松崎彰剛、渡邊厚介、大瀧倫卓
    • Organizer
      第6回九州若手セラミックフォーラム(KYCF-6)&第46回窯業基礎九州懇話会
    • Place of Presentation
      ルートイングランティア太宰府(太宰府市)
    • Year and Date
      2016-08-26
    • Related Report
      2016 Research-status Report
  • [Presentation] AgをドープしたZnOナノ粒子の構造と光学特性2016

    • Author(s)
      峯一貴、渡邊厚介、大瀧倫卓
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2016-07-02
    • Related Report
      2016 Research-status Report
  • [Presentation] ゾルゲル法を用いたZnO/TiO2コアシェルナノ構造の形成2016

    • Author(s)
      松崎彰剛、渡邊厚介、大瀧倫卓
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2016-07-02
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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