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Development of highly Na storage material with highly amorphous structure by soft chemical synthesis

Research Project

Project/Area Number 16K18252
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

Kajita Tetsuya  東北大学, 学際科学フロンティア研究所, 助教 (50729233)

Co-Investigator(Renkei-kenkyūsha) ITOH Takashi  東北大学, 学際科学フロンティア研究所, 准教授 (40302187)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords二次電池 / 負極 / アモルファス / ナトリウム / Naイオン / ナトリウム二次電池 / ゲルマニウム / 電池材料 / Naイオン二次電池
Outline of Final Research Achievements

The aim of this research project is to create a highly amorphized material using soft chemistry method and develop new electrode material group for Na-ion battery. We synthesized highly amorphous Si and Ge oxide powders by soft chemistry method. However, only the amorphous Ge oxide powder showed the electrochemical performance for the Na-ion battery. In the soft chemical synthesis, fine particles of several microns was observed by using 2-propanol, a secondary alcohol, as the alcohol species for oxidizing Zintle phase NaM. Using an ether solvent for the Na-ion battery electrolyte solution, the electrochemical performances of the amorphous Ge oxide material were greatly improved.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 2016

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results)

  • [Journal Article] Mixed ether-based solvents provide a long cycle life with high rate capability to graphite anodes for Na-ion batteries2018

    • Author(s)
      Kajita Tetsuya、Itoh Takashi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 4 Pages: 2188-2195

    • DOI

      10.1039/c7cp06998g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Vanillin to Prevent the Dendrite Growth of Zn in Zinc-Based Secondary Batteries2017

    • Author(s)
      Azhagurajan Mukkannan、Nakata Akiyoshi、Arai Hajime、Ogumi Zempachi、Kajita Tetsuya、Itoh Takashi、Itaya Kingo
    • Journal Title

      J. Electrochem. Soc.

      Volume: 164 Issue: 12 Pages: A2407-A2417

    • DOI

      10.1149/2.0221712jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ether-based solvents significantly improved electrochemical performance for Na-ion batteries with amorphous GeOx anodes2017

    • Author(s)
      T. Kajita*, T. Itoh
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19(2) Issue: 2 Pages: 1003-1009

    • DOI

      10.1039/c6cp06354c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical performance of highly amorphous GeOx powders synthesized in different alcohols for use in Na- and Li-ion batteries2016

    • Author(s)
      T. Kajita*, T. Itoh
    • Journal Title

      RSC Adv.

      Volume: 6(104) Issue: 104 Pages: 102109-102115

    • DOI

      10.1039/c6ra20794d

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In Situ Visualization of Lithium Ion Intercalation into MoS2 Single Crystals using Differential Optical Microscopy with Atomic Layer Resolution2016

    • Author(s)
      Mukkannan Azhagurajan, Tetsuya Kajita, Takashi Itoh, Youn-Geun Kim, and Kingo Itaya
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 10 Pages: 3355-3361

    • DOI

      10.1021/jacs.5b11849

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] エーテル溶媒を用いたアモルファスGe酸化物におけるナトリウムイオン二次電池特性の向上2017

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-24
    • Related Report
      2016 Research-status Report
  • [Presentation] 高アモルファス型Ge酸化物の合成と負極特性2017

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] アモルファスGe酸化物負極のエーテル溶媒を用いた電解液での電池特性と表面状態2017

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Na二次電池用アモルファスGe酸化物負極のエーテル溶媒中での電極特性と表面状態2017

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] エーテル溶媒を用いたアモルファスGe酸化物における ナトリウムイオン二次電池特性の向上2017

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      電気化学会第84回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] アモルファスGe酸化物負極のNaイオン電池特性2016

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ(千葉県幕張市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Research-status Report
  • [Presentation] Na二次電池用Ge酸化物負極2016

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      電気化学会東北支部第29回東北若手の会
    • Place of Presentation
      南部屋海扇閣(青森県青森市)
    • Year and Date
      2016-11-25
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Electrochemical Sodium storage in amorphous Ge oxide2016

    • Author(s)
      T. Kajita、 T. Itoh
    • Organizer
      IUPAC 12th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      長沙(中国)
    • Year and Date
      2016-10-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] アモルファスGe酸化物におけるNaイオン二次電池負極特性2016

    • Author(s)
      梶田 徹也、伊藤 隆
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] FeSeへの電気化学的アルカリ金属インターカレーション効果2016

    • Author(s)
      梶田 徹也、川股 隆行、野地 尚、畑田 武宏、加藤 雅恒、小池 洋二、伊藤 隆
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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