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Molecular design of chemically-stable proton-conducting aromatic polymers for fuel cell membranes

Research Project

Project/Area Number 16K18258
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionUniversity of Yamanashi

Principal Investigator

MIYAKE Junpei  山梨大学, 大学院総合研究部, 助教 (30581409)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords高分子合成 / 機能性高分子 / プロトン伝導 / 高分子電解質 / 膜 / 燃料電池
Outline of Final Research Achievements

Based on the molecular design principle (i.e., no heteroatom linkages in the polymer main chain), a novel fluorine-free aromatic ionomer membrane has been designed and synthesized. Compared with the existing perfluorinated or aromatic (i.e., containing heteroatom linkages in the polymer main chain) ionomer membrane, the novel membrane exhibited higher proton conductivity and chemical stability. In addition, the membrane also exhibited high fuel cell performance, with excellent durability under practical conditions.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (27 results)

All 2018 2017 2016 Other

All Journal Article (13 results) (of which Peer Reviewed: 12 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (11 results) (of which Int'l Joint Research: 2 results) Remarks (3 results)

  • [Journal Article] Mechanism of H2O2 Decomposition by Triphenylphosphine Oxide2018

    • Author(s)
      Takao Tsuneda, Junpei Miyake, Kenji Miyatake
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 1 Pages: 259-265

    • DOI

      10.1021/acsomega.7b01416

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Sulfonated Phenylene/Quinquephenylene/Perfluoroalkylene Terpolymers as Proton Exchange Membranes for Fuel Cells2018

    • Author(s)
      Yaojian Zhang, Junpei Miyake, Ryo Akiyama, Ryo Shimizu, Kenji Miyatake
    • Journal Title

      ACS Appl. Energy Mater.

      Volume: 1 Issue: 3 Pages: 1008-1015

    • DOI

      10.1021/acsaem.7b00162

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable Reinforcement Effect in Sulfonated Aromatic Polymers as Fuel Cell Membrane2018

    • Author(s)
      Junpei Miyake, Masato Kusakabe, Akihiro Tsutsumida, Kenji Miyatake
    • Journal Title

      ACS Appl. Energy Mater.

      Volume: 1 Issue: 3 Pages: 1233-1238

    • DOI

      10.1021/acsaem.7b00349

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 4.次世代燃料電池用の電解質膜の課題と可能性2018

    • Author(s)
      三宅純平, 宮武健治
    • Journal Title

      Denki Kagaku

      Volume: 86 Issue: Spring Pages: 20-24

    • DOI

      10.5796/denkikagaku.18-FE0004

    • NAID

      130006728120

    • ISSN
      2433-3255, 2433-3263
    • Related Report
      2017 Annual Research Report
  • [Journal Article] Copolymers Composed of Perfluoroalkyl and Ammonium-Functionalized Fluorenyl Groups as Chemically Stable Anion Exchange Membranes2017

    • Author(s)
      Mizuki Ozawa, Taro Kimura, Ryo Akiyama, Junpei Miyake, Junji Inukai, Kenji Miyatake
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 90 Issue: 10 Pages: 1088-1094

    • DOI

      10.1246/bcsj.20170185

    • NAID

      130006770676

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Durability of Sulfonated Phenylene Poly(Arylene Ether Ketone) Semiblock Copolymer Membrane in Wet-Dry Cycling for PEFCs2017

    • Author(s)
      Hiroshi Ishikawa, Yusuke Fujita, Junichi Tsuji, Masato Kusakabe, Junpei Miyake, Yasushi Sugawara, Kenji Miyatake, Makoto Uchida
    • Journal Title

      J. Electrochem. Soc.

      Volume: 164 Issue: 12 Pages: F1204-F1210

    • DOI

      10.1149/2.1471712jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Design of Flexible Polyphenylene Proton-conducting Membrane for Next-generation Fuel Cells2017

    • Author(s)
      Junpei Miyake, Ryunosuke Taki, Takashi Mochizuki, Ryo Shimizu, Ryo Akiyama, Makoto Uchida, Kenji Miyatake
    • Journal Title

      Sci. Adv.

      Volume: 3 Issue: 10

    • DOI

      10.1126/sciadv.aao0476

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Robust Anion Conductive Polymers Containing Perfluoroalkylene and Pendant Ammonium Groups for High Performance Fuel Cells2017

    • Author(s)
      Hideaki Ono, Taro Kimura, Aoi Takano, Koichiro Asazawa, Junpei Miyake, Junji Inukai, Kenji Miyatake
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 47 Pages: 24804-24812

    • DOI

      10.1039/c7ta09409d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Partially Fluorinated and Ammonium-Functionalized Terpolymers: Effect of Aliphatic Groups on the Properties of Anion Conductive Membranes2017

    • Author(s)
      Hideaki Ono, Junpei Miyake, Kenji Miyatake
    • Journal Title

      J. Polym. Sci. A: Polym. Chem.

      Volume: 55 Issue: 8 Pages: 1442-1450

    • DOI

      10.1002/pola.28513

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Anion Conductive Polymers Containing Aliphatic and Ammonium-functionalized Fluorene Groups2017

    • Author(s)
      Manai Shimada, Ryo Akiyama, Hideaki Ono, Junpei Miyake, Kenji Miyatake
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 3 Pages: 374-377

    • DOI

      10.1246/cl.161073

    • NAID

      130005436550

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fluorine-free Sulfonated Aromatic Polymers as Proton Exchange Membranes2017

    • Author(s)
      Junpei Miyake, Kenji Miyatake
    • Journal Title

      Polym. J.

      Volume: 49 Issue: 6 Pages: 487-495

    • DOI

      10.1038/pj.2017.11

    • NAID

      40021203903

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Anion Conductive Aromatic Polymers Containing Fluorenyl Groups: Effect of the Position and Number of Ammonium Groups2016

    • Author(s)
      Manai Shimada, Shigefumi Shimada, Junpei Miyake, Makoto Uchida, Kenji Miyatake
    • Journal Title

      J. Polym. Sci. A: Polym. Chem.

      Volume: 54 Issue: 7 Pages: 935-944

    • DOI

      10.1002/pola.27928

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Anion-exchange Membranes Containing Fluorinated Poly(arylene ether)s: Properties and Application in Pt-free Hydrazine Fuel Cell2016

    • Author(s)
      Eriko Nishino, Junko Yamada, Koichiro Asazawa, Susumu Yamaguchi, Manai Shimada, Junpei Miyake, Kenji Miyatake
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 6 Pages: 664-666

    • DOI

      10.1246/cl.160161

    • NAID

      130005155032

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 高耐久性芳香族系高分子電解質膜2017

    • Author(s)
      三宅純平、滝隆之介、望月崇史、清水瞭、秋山良、内田誠、宮武健治
    • Organizer
      第24回燃料電池シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] High Performance Ion Conductive Membranes for Energy Applications2017

    • Author(s)
      Kenji Miyatake, Junpei Miyake
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis and Properties of Sulfonated Terpolymers Containing Quinquephenylene Groups as Proton Exchange Membranes2017

    • Author(s)
      Yaojian Zhang, Junpei Miyake, Ryo Akiyama, Ryo Shimizu, Kenji Miyatake
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ionomer Layer Design of the Electrode Using PGM-free Electrocatalysts for Anion Exchange Membrane Fuel Cells2016

    • Author(s)
      Koichiro Asazawa, Aoi Takano, Eriko Nishino, Susumu Yamaguchi, Junpei Miyake, Makoto Uchida, Kenji Miyatake
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science 2016 (PRiME 2016)
    • Place of Presentation
      ハワイコンベンションセンター(アメリカ)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of Partially Fluorinated Anion Exchange Membranes Containing Ammonium-Functionalized Fluorenyl Groups2016

    • Author(s)
      Mizuki Ozawa, Junpei Miyake, Kenji Miyatake
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science 2016 (PRiME 2016)
    • Place of Presentation
      ハワイコンベンションセンター(アメリカ)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 新規スルホン酸化ポリフェニレンの合成と物性評価2016

    • Author(s)
      三宅純平、滝隆之介、秋山良、清水瞭、宮武健治
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] フッ化アルキルとオリゴフェニレン骨格からなる新規アニオン交換膜の合成と物性2016

    • Author(s)
      小野英明、三宅純平、島田盛史、内田誠、宮武健治
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2016-06-08
    • Related Report
      2016 Research-status Report
  • [Presentation] キンケフェニレン構造を有する芳香族系プロトン導電性高分子の合成と物性評価2016

    • Author(s)
      三宅純平、滝隆之介、秋山良、望月崇史、宮武健治
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場(兵庫県)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 親水部にオリゴフェニレン構造を有するアニオン導電性高分子の合成と物性評価2016

    • Author(s)
      横田尚樹、秋山良、三宅純平、宮武健治
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場(兵庫県)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 新規アニオン交換膜を用いたダイレクトヒドラジン燃料電池2016

    • Author(s)
      西野英里子、山田純子、朝澤浩一郎、横田尚樹、秋山良、三宅純平、宮武健治
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場(兵庫県)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 芳香族高分子電解質膜の合成と物性評価2016

    • Author(s)
      三宅純平、宮武健治
    • Organizer
      日本膜学会第38年会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2016-05-10
    • Related Report
      2016 Research-status Report
  • [Remarks] 山梨大学研究者総覧

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_Index.Main

    • Related Report
      2016 Research-status Report
  • [Remarks] 山梨大学クリーンエネルギー研究センター燃料電池研究部門

    • URL

      http://www.fcgroup.yamanashi.ac.jp/

    • Related Report
      2016 Research-status Report
  • [Remarks] 山梨大学燃料電池ナノ材料研究センター

    • URL

      http://fc-nano.yamanashi.ac.jp/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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