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The application of steelmaking slag as agricultural material through the control of composition and structure

Research Project

Project/Area Number 16K18270
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Metal making/Resorce production engineering
Research InstitutionTohoku University

Principal Investigator

GAO XU  東北大学, 多元物質科学研究所, 助教 (80707670)

Co-Investigator(Renkei-kenkyūsha) KITAMURA SHIN-YA  東北大学, 多元物質科学研究所, 教授 (80400422)
ITO TOYOAKI  東北大学, 大学院農学研究科, 准教授 (10176349)
Research Collaborator SHIBATA HIROYUKI  東北大学, 多元物質科学研究所, 教授 (50250824)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords製鋼スラグ系肥料 / 水田 / 遊離酸化鉄 / 非結晶相 / 非結晶相構造 / 水溶性
Outline of Final Research Achievements

Nowadays, the decrease in soil pH, lack of silicate and free iron ion in soil solution are occurring in the paddy fields of Japan. Therefore, the steelmaking slag, a by-product from steelmaking process, has been expected as a costless solution. Both Ca and Si can be easily dissolved from steelmaking slag, however, the water-soluble amount of Fe is not enough even though the content of iron oxides in slag are high. To improve the water solubility of Fe, the use of a glassy phase majorly consists of CaO-SiO2-FeOx has been proposed in this study. The relation among the water solubility of glassy phase, chemical composition, and structure has been studied. In addition, through the control of chemical composition and cooling method, a slag which can simultaneously supply Ca, Si, and Fe with large amounts has been successfully synthesized, and this indicate it is possible to achieve a new type of fertilizer made of steelmaking slag which can easily supply Ca, Si, and Fe into paddy fields.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (5 results)

All 2018 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Effect of the mineralogical phases in steelmaking slag fertilizer on the dissolution behavior of nutritious elements and rice growth2017

    • Author(s)
      Xu Gao, Sun-joong Kim, Hideomi Minoshima, Toyoaki Ito, Shin-ya Kitamura
    • Journal Title

      Journal of Sustainable Metallurgy

      Volume: 3 Issue: 2 Pages: 207-218

    • DOI

      10.1007/s40831-016-0064-6

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] CaO-SiO2-FeOx系ガラス相の溶出挙動に及ぼす構造の影響2018

    • Author(s)
      小泉匠平・高旭・植田滋・北村信也・金橋康二・髙橋貴文
    • Organizer
      CAMP-ISIJ, 鉄鋼協会第175回春季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] CaO-SiO2-FeOx系非結晶相からのFe溶出に対するpH、ORP、及び酸の種類の影響2017

    • Author(s)
      小泉匠平、高旭、植田滋、北村信也
    • Organizer
      日本鉄鋼協会春季講演大会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Dissolution Behavior of Fe from Glassy Oxide Phase in Steelmaking Slag2017

    • Author(s)
      Shohei Koizumi, Xu Gao, Shigeru Ueda and Shin-ya Kitamura
    • Organizer
      Proceedings of the 8th International Symposium on High Temperature Metallurgical Processing, TMS2017: Annual Meeting & Exhibition
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2017-02-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] CaO-SiO2-FeOx系非結晶相からのFeの溶出に対する組成の影響2016

    • Author(s)
      小泉匠平、高旭、植田滋、北村信也
    • Organizer
      日本鉄鋼協会秋季講演大会
    • Place of Presentation
      大阪大学 (大阪府吹田市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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