| Project/Area Number |
16K18278
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | Osaka University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | オルガノシリカ膜 / イオン液体 / メタノール分離 / ガス蒸気分離 / 透過分離メカニズム / イオン液体膜 / メタノール合成 / ガス・蒸気透過 / 膜分離 / 膜反応器 |
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| Outline of Final Research Achievements |
A silylated ionic liquid-derived organosilica membrane was prepared on the outer surface of a porous alumina substrate. Its separation properties for binary methanol/H2 and H2O/H2 mixtures, and a methanol/H2O/H2/CO2 quaternary mixture were studied. The separation factors for methanol/H2 in the binary system were 12-71. The membrane also showed high H2O/H2 separation performances in the quaternary system, and the presence of H2O and CO2 in the feed stream did not affect the methanol permeation performance. The silylated ionic liquid-derived organosilica membrane showed an excellent potential for the simultaneous separation of methanol and H2O from methanol synthesis gas.
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