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Development of efficient techniques to produce TiO2/C nanocomposites by controlling vapor phase reactions

Research Project

Project/Area Number 16K18283
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

Iwamura Shinichiroh  北海道大学, 工学研究院, 助教 (10706873)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords反応プロセス / ナノ材料 / エネルギーデバイス / 炭素材料 / 化学気相成長法 / 多孔質材料 / ナノ粒子担持
Outline of Final Research Achievements

In this study, efficient production processes to prepare TiO2/C nanoparticles with a high TiO2 content and porous-carbon/TiO2 nanocomposites with a very small diameter of TiO2 nanoparticles were developed. The process to prepare the TiO2/C nanoparticles was performed by injecting a mixture of a Ti source and carbon source as liquid pulses into a heated reactor (ca. 800C) under a N2 flow. The obtained TiO2/C nanoparticles showed a high charge/discharge capacity as a TiO2 anode for high safe lithium-ion batteries. The process to prepare the porous-carbon/TiO2 nanocomposites were performed by injecting a Ti source as liquid pulses into a vacuuming heated reactor (200C) in which a porous-carbon was placed. The obtained porous-carbon/TiO2 nanocomposites showed a high rate-performance and cyclability, which are suitable for anodes in lithium-ion capacitors.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (14 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Cost-effective synthesis of activated carbons with high surface areas for electrodes of nonaqueous electric double layer capacitors2018

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Journal Title

      Separation and Purification Technology

      Volume: 印刷中 Pages: 174-180

    • DOI

      10.1016/j.seppur.2018.04.022

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient preparation of TiO 2 /C nanocomposite for electrode material through the liquid pulse injection technique2018

    • Author(s)
      Iwamura Shinichiroh、Fujita Kazuki、Iwashiro Ryo、Mukai Shin R.
    • Journal Title

      Materials Today Communications

      Volume: 14 Pages: 15-21

    • DOI

      10.1016/j.mtcomm.2017.12.002

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of the Porous Structure of the Cathode on the Discharge Capacity of Lithium-Air Batteries2017

    • Author(s)
      Sakai Kazuki、Iwamura Shinichiroh、Mukai Shin R.
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 164 Issue: 13 Pages: A3075-A3080

    • DOI

      10.1149/2.0791713jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of Practical Activation Depth for Effective CO2 Activation Using PMMA-templated Carbons with a Tailorable Pore System of Meso- and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      Journal of Porous Materials

      Volume: 24 Issue: 6 Pages: 1497-1506

    • DOI

      10.1007/s10934-017-0389-y

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PMMA-Templated Carbon Gel Monoliths with Independently Tunable Micro-, Meso-, and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 4 Pages: 315-323

    • DOI

      10.1252/jcej.16we313

    • NAID

      130006837170

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 多孔質炭素内部へのTiO2ナノ粒子の均一担持に向けた新規CVD手法の開発2018

    • Author(s)
      岩村 振一郎、本橋 翔太、向井 紳
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 炭素ナノ複合材料の効率的製造プロセスの開発2018

    • Author(s)
      岩村 振一郎
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 液パルスインジェクション法によるTiO2/Cナノ粒子の高効率製造と電極材料への応用2017

    • Author(s)
      藤田 和樹、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第 25 回化学工学・粉体研究発表会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2017-01-27
    • Related Report
      2016 Research-status Report
  • [Presentation] Activated Carbons with Ultra-High Surface Areas from Phenolic Resins Using Conventional Physical Activation2017

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino and Shin R Mukai
    • Organizer
      APCChE2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 減圧液パルスCVD法による多孔質炭素内部へのTiO2ナノ粒子の均一担持2017

    • Author(s)
      岩村 振一郎、本橋 翔太、向井 紳
    • Organizer
      化学工学会 第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Efficient Production of TiO2/C Nanoparticles through the Liquid Pulse Injection Technique2017

    • Author(s)
      Shinichiroh Iwamura, Kazuki Fujita, Isao Ogino, Shin R. Mukai
    • Organizer
      13th National Meeting on New Carbon Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 減圧液パルスCVD法による炭素細孔内へのTiO2ナノ粒子の均一担持とリチウムイオンキャパタへの応用2017

    • Author(s)
      岩村 振一郎、本橋 翔太、向井 紳
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液パルスインジェクション法により製造したカーボンナノファイバーのリチウム空気電池空気極への利用2016

    • Author(s)
      住田 稜、坂井 一樹、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学(千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 賦活カーボンゲルへのホウ素ドープとEDLCへの応用2016

    • Author(s)
      大西 健太、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学(千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 細孔構造制御により作製したMnO2/Cナノ複合体のキャパシタ電極への応用2016

    • Author(s)
      岩村 振一郎、梅津 遼太郎、大西 健太、荻野 勲、向井 紳
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学(千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Introduction of additional micropores and tunable macropores into carbon gels2016

    • Author(s)
      Kazuki Sakai, Takeshi Mori, Takanori Tsuchiya, Shinichiro Iwamura, Isao Ogino, and Shin R. Mukai
    • Organizer
      The 10th International Conference on Multi-functional Materials and Applications
    • Place of Presentation
      Khon Kaen, Thailand
    • Year and Date
      2016-12-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 液パルスインジェクション法により製造したカーボンナノファイバーのリチウム空気電池空気極への利用2016

    • Author(s)
      岩村 振一郎、住田 稜、坂井 一樹、荻野 勲、向井 紳
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ 国際会議場(千葉市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Research-status Report
  • [Presentation] 液パルスインジェクション法による電極材料用TiO2/Cナノ複合体の高効率製造2016

    • Author(s)
      岩村 振一郎、藤田 和樹、岩城凌、荻野 勲、向井 紳
    • Organizer
      化学工学会 第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] CVD法による炭素複合材料の製造2016

    • Author(s)
      岩村 振一郎
    • Organizer
      第54回炭素材料夏季セミナー
    • Place of Presentation
      富士通労働組合総合センター(上水内郡飯綱町)
    • Year and Date
      2016-08-29
    • Related Report
      2016 Research-status Report
    • Invited
  • [Remarks] CVD法による炭素・無機ナノ複合材料の合成

    • URL

      http://mde-cp.eng.hokudai.ac.jp/aboutus/cvd/cvd.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属酸化物ー多孔体複合体の製造方法及び多孔質炭素材料とチタン酸化物との複合体2017

    • Inventor(s)
      向井紳、岩村振一郎、本橋翔大
    • Industrial Property Rights Holder
      向井紳、岩村振一郎、本橋翔大
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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