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Development and application of 3D-imaging-XAFS technique that can visualize the catalytic active domain in practical materials

Research Project

Project/Area Number 16K18288
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionNagoya University

Principal Investigator

Matsui Hirosuke  名古屋大学, 理学研究科, 助教 (90754309)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
KeywordsPEFC / 酸素吸蔵材料 / イメージングXAFS / ナノXAFS / CT-XAFS / XAFS / CT / 可視化 / 固体高分子形燃料電池 / 酸化鉄 / 固体触媒 / 顕微分光 / X線イメージング / 走査型顕微XAFS / 鉄酸化物触媒 / 構造異方性
Outline of Final Research Achievements

In this study, we newly developed two kinds of imaging-XAFS techniques; two-dimensional scanning XAFS technique (Nano-XAFS) and CT-XAFS technique combined with 3D-computed tomography (CT) method. The developed XAFS imaging techniques were applied for the operando characterization while the practical catalyst materials were reacted or operated. Through the investigation for the reaction and degradation processes in a polymer electrolyte fuel cell (PEFC) catalyst membrane and practical catalyst particles, we clarified the details of interaction among the structure, chemical state, and their properties in the view of two/three-dimensional visualizations.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (38 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (27 results) (of which Int'l Joint Research: 8 results,  Invited: 5 results) Book (2 results)

  • [Int'l Joint Research] Universitat Innsbruck(Austria)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Visualization of Heterogeneous Oxygen Storage Behavior in Platinum-Supported Cerium-Zirconium Oxide Three-Way Catalyst particles by Hard X-ray Spectro-Ptychography2018

    • Author(s)
      Makoto Hirose, Nozomu Ishiguro, Kei Shimomura, Nicolas Burdet, Hirosuke Matsui, Mizuki Tada, Yukio Takahashi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 130 Issue: 6 Pages: 1490-1495

    • DOI

      10.1002/ange.201710798

    • NAID

      120006473548

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structural investigations of La0.6Sr0.4FeO3-δ under reducing conditions: kinetic and thermodynamic limitations for phase transformations and iron exsolution phenomena2018

    • Author(s)
      Gotsch Thomas、Schlicker Lukas、Bekheet Maged F.、Doran Andrew、Grunbacher Matthias、Praty Corsin、Tada Mizuki、Matsui Hirosuke、Ishiguro Nozomu、Gurlo Aleksander、Klotzer Bernhard、Penner Simon
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 6 Pages: 3120-3131

    • DOI

      10.1039/c7ra12309d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Operando 3D Visualization of Migration and Degradation of a Platinum Cathode Catalyst in a Polymer Electrolyte Fuel Cell2017

    • Author(s)
      Matsui Hirosuke、Ishiguro Nozomu、Uruga Tomoya、Sekizawa Oki、Higashi Kotaro、Maejima Naoyuki、Tada Mizuki
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 32 Pages: 9371-9375

    • DOI

      10.1002/anie.201703940

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron Exsolution Phenomena in Lanthanum Strontium Ferrite SOFC Anodes2017

    • Author(s)
      Gotsch Thomas、Praty Corsin、Grunbacher Matthias、Schlicker Lukas、Bekheet Maged F.、Doran Andrew、Gurlo Aleksander、Tada Mizuki、Matsui Hirosuke、Ishiguro Nozomu、Kloetzer Bernhard、Penner Simon
    • Journal Title

      ECS Transactions

      Volume: 78 Issue: 1 Pages: 1327-1341

    • DOI

      10.1149/07801.1327ecst

    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] In-situ X-ray nano-CT System for Polymer Electrolyte Fuel Cells under Operating Conditions2017

    • Author(s)
      Sekizawa O、Uruga T、Ishiguro N、Matsui H、Higashi K、Sakata T、Iwasawa Y、Tada M
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 849 Pages: 012022-012022

    • DOI

      10.1088/1742-6596/849/1/012022

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Imaging of Oxygen Diffusion in Individual Platinum/Ce2Zr2Ox Catalyst Particles During Oxygen Storage and Release2016

    • Author(s)
      H. Matsui, N. Ishiguro, K. Enomoto, O. Sekizawa, T. Uruga, and M. Tada
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 39 Pages: 12022-12025

    • DOI

      10.1002/anie.201606046

    • NAID

      120005946580

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Kinetics and Mechanism of Redox Processes of Pt/C and Pt3Co/C Cathode Electrocatalysts in a Polymer Electrolyte Fuel Cell During an Accelerated Durability Test2016

    • Author(s)
      N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, H. Matsui, M. Taguchi, K. Nagasawa, T. Yokoyama, M. Tada
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 35 Pages: 19642-19651

    • DOI

      10.1021/acs.jpcc.6b04437

    • NAID

      120005946814

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Imaging Analysis of Heterogeneous Solid Catalyst by Spatially-Resolved XAFS2016

    • Author(s)
      松井公佑, 唯美津木
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 59 Issue: 11 Pages: 307-314

    • DOI

      10.3131/jvsj2.59.307

    • NAID

      130005282118

    • ISSN
      1882-2398, 1882-4749
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 3D-multiple elemental visualization of PEFC Pt3Co/C cathode catalyst during accelerated degradation test2018

    • Author(s)
      Y. Tan, H. Matsui, N. Ishiguro, T. Uruga, O. Sekizawa, N. Maejima, Mizuki Tada
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] EXAFS-CT法による燃料電池触媒のその場局所構造観察2018

    • Author(s)
      前島尚行、松井公佑、石黒志、Tan YuanYuan、小澤沙記、坂田智裕、東晃太朗、関澤央輝、宇留賀朋哉、唯 美津木
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 結像型顕微XAFSによる樹状型FeOx粒子の酸化還元サイクルにおける酸化鉄相分布の可視化2018

    • Author(s)
      石黒志、松井公佑、鈴木陽也、関澤央輝、新田清文、寺田靖子、宇留賀朋哉、唯美津木
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 硬X線スペクトロタイコグラフィによる酸素吸蔵・放出材料の三次元価数識別イメージング2018

    • Author(s)
      広瀬真、石黒志、下村啓、松井公佑、唯美津木、高橋幸生
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Visualization of anisotropic crystalline phase variations inside Cr-supported FeOx dendrite crystals for oxygen storage process2018

    • Author(s)
      H. Matsui, Y. Suzuki, N. Ishiguro, M. Tada
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Rh, Crを担持したミクロンサイズのセリア結晶粒子の合成とレドックス特性2018

    • Author(s)
      "若松昂平、松井公佑、石黒志、邨次智、唯美津木 "
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カソードのガス交換と電位操作によるPEFC Pt/C, Pt3Co/Cカソード触媒の酸化過程の構造速度論解析2018

    • Author(s)
      小澤沙記、松井公佑、田口将寛、石黒志、宇留賀朋哉、関澤央輝、坂田智裕、東晃太朗、唯美津木
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 3D-visualization of distribution and redox property of a PEFC Pt/C cathode catalyst during degradation process by imaging XAFS2018

    • Author(s)
      N. Maejima, H. Matsui, N. Ishiguro, Y. Tan, T. Uruga, T. Sakata, K. Higashi, O. Sekizawa, M. Tada
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Operando 3D-visualization of local chemical composition in PEFC Pt3Co/C cathode catalyst during accelerated degradation test2018

    • Author(s)
      Y. Tan, H. Matsui, N. Ishiguro, N. Maejima, T. Uruga, O. Sekizawa, M. Tada
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Visualization of Oxygen Diffusion in Ce2Zr2Ox Particles by Ptychographic-XAFS2018

    • Author(s)
      N. Ishiguro, M. Hirose, K. Shimomura, N. Burdet, H. Matsui, M. Tada, Y. Takahashi
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 走査型顕微XAFS法によるCe2Zr2Ox触媒粒子内の酸素拡散様式イメージング2017

    • Author(s)
      松井公佑,石黒志,関澤央輝,宇留賀朋哉,唯美津木
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] カソードガス交換・セル電圧の同期変化による固体高分子形燃料電池Pt/Cカソード電極触媒の構造速度論解明2017

    • Author(s)
      田口将寛,松井公佑,石黒志,関澤央輝,坂田智裕,宇留賀朋哉,唯美津木
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 空間分解XAFS法による触媒材料の化学状態イメージング2017

    • Author(s)
      松井公佑
    • Organizer
      X線スペクトロスコピー利用研究会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] "走査型顕微XAFS法によるCe2Zr2Ox粒子内の酸素拡散様式の可視化 "2017

    • Author(s)
      松井公佑,石黒志,関澤央輝,宇留賀朋哉,唯美津木
    • Organizer
      "第30回日本放射光学会年会放射光科学合同シンポジウム "
    • Place of Presentation
      神戸芸術センター
    • Year and Date
      2017-01-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Oxidation of Pt and Pt3Co electrocatalysts at PEFC cathode studied by operando time-resolved QXAFS2017

    • Author(s)
      H. Matsui, S. Ozawa, N. Ishiguro, O. Sekizawa, T. Uruga, M. Tada
    • Organizer
      The 8th International Symposium on Surface Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 3D-visualization of PEFC Pt cathode catalyst in MEA during ADT cycles by operando CT-XANES technique2017

    • Author(s)
      H. Matsui, N. Ishiguro, T. Uruga, O. Sekizawa, M. Tada
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visualization of Heterogeneity of Solid Catalysts2017

    • Author(s)
      M. Tada, H. Matsui, N. Ishiguro
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ADT Processes of Pt/C and Pt3Co/C PEFC Cathode Electrocatalysts Studied by Operando Time-resolved Quick-XAFS2017

    • Author(s)
      N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, H. Matsui, K. Nagasawa, M. Tada
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoscale Chemical Imaging of Oxygen Storage and Release Particles by Hard X-ray Spectro-Ptychography2017

    • Author(s)
      M. Hirose, N. Ishiguro, K. Shimomura, N. Burdet, H. Matsui, M. Tada, Y. Takahashi
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics and reaction mechanism of oxidation processes on Pt/C and Pt3Co/C cathode catalysts studied by operando time-resolved QXAFS2017

    • Author(s)
      S. Ozawa, H. Matsui, N. Ishiguro, T. Uruga, O. Sekizawa, T. Sakata, K. Higashi, Mizuki Tada
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 3D-Visualization of Pt and Co Segregations in Pt3Co Cathode Catalyst Layer by Operando XAFS-CT Imaging2017

    • Author(s)
      Y. Tan, H. Matsui, N. Ishiguro, N. Maejima, T. Uruga, O. Sekizawa, M. Tada
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 実固体触媒中の反応・劣化現象の 画像化計測技術の開発2017

    • Author(s)
      松井公佑
    • Organizer
      第6回(2017年度) 研究開発奨励賞 研究発表会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] OperandoイメージングXAFS法の開発と実固体触媒材料の可視化2017

    • Author(s)
      松井公佑
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] オペランドCT-XAFS法による固体高分子形燃料電池の触媒劣化・溶出様式の3次元可視化2017

    • Author(s)
      小澤沙記、松井公佑、石黒志、宇留賀朋哉、関澤央輝、坂田智裕、東晃太朗、唯美津木
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Visualization of Oxidation Diffusion Mode in Individual Pt/Ce2Zr2Ox Catalyst Particles under Redox Reactions by Scanning Nano-XAFS2016

    • Author(s)
      H. Matsui, M. Tada
    • Organizer
      9th Singapore International Chemistry Conference
    • Place of Presentation
      National University of Singapore
    • Year and Date
      2016-12-11
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] In situ CT-XAFSによる 燃料電池Pt電極触媒の劣化過程観察2016

    • Author(s)
      松井公佑
    • Organizer
      第8回 岩澤コンファレンス「サスイナブル社会のための最先端触媒化学・表面科学」
    • Place of Presentation
      名古屋大学
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] "Pt/Ce2Zr2Ox触媒粒子の酸素貯蔵・放出サイクルにおける酸素拡散様式のイメージング解析 "2016

    • Author(s)
      松井公佑,石黒志,榎本香里,関澤央輝,宇留賀朋哉,唯美津木
    • Organizer
      第19回XAFS討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2016-09-03
    • Related Report
      2016 Research-status Report
  • [Book] Catalysts and Catalysis2017

    • Author(s)
      石黒志・松井公佑・唯美津木
    • Total Pages
      6
    • Publisher
      触媒学会
    • Related Report
      2017 Annual Research Report
  • [Book] XAFS Techniques for Catalysts, Nanomaterials, and Surfaces2017

    • Author(s)
      M. Tada, H. Matsui
    • Total Pages
      6
    • Publisher
      Springer
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2019-03-29  

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