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Sustainabele synthesis of useful chemicals from glycerol

Research Project

Project/Area Number 16K18291
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionTottori University

Principal Investigator

Suganuma Satoshi  鳥取大学, 工学(系)研究科(研究院), 助教 (90731753)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsバイオマス変換 / グリセロール / アクロレイン / アクリル酸 / MFIゼオライト / W-V複合酸化物 / 脱水酸化反応 / 二機能性触媒 / ZSM-5 / 酸性質測定 / 二元機能触媒 / 触媒・化学プロセス / バイオマス / 資源・エネルギー有効利用技術
Outline of Final Research Achievements

A bifunctional catalyst consisting of small MFI zeolite crystallites covering crystals of W-V binary oxide with hexagonal tungsten bronze structure. One-pass oxidehydration of glycerol into acrylic acid was tested to show the high selectivity of MFI/W-V-O. Glycerol was dehydrated into acrolein by Bronsted acid sites on MFI, and acrolein was oxidized into acrylic acid by redox sites on W-V-O.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (24 results)

All 2018 2017 2016

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (16 results) (of which Int'l Joint Research: 8 results)

  • [Journal Article] Keggin-type Molybdovanadophosphoric Acids Loaded on ZSM-5 Zeolite as a Bifunctional Catalyst for Oxidehydration of Glycerol2018

    • Author(s)
      Suganuma, S., Hisazumi, T., Taruya, K., Tsuji, E., Katada, N.
    • Journal Title

      Mol. Catal.

      Volume: 449 Pages: 85-92

    • DOI

      10.1016/j.mcat.2018.02.015

    • NAID

      120006873126

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dealkylation of Alkyl Polycyclic Aromatic Hydrocarbon over Silica Monolayer Solid Acid Catalyst2017

    • Author(s)
      Katada, Naonobu; Kawaguchi, Yusuke; Takeda, Kazuki; Matsuoka, Taku; Uozumi, Naoki; Kanai, Kazuki; Fujiwara, Shohei; Kinugasa, Keisuke; Nakamura, Koshiro ; Suganuma, Satoshi ; Nanjo, Masato
    • Journal Title

      Appl. Catal., A: Gen.

      Volume: 530 Pages: 93-101

    • DOI

      10.1016/j.apcata.2016.11.018

    • NAID

      120006873123

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Shape Selectivity in Toluene Disproportionation into para-Xylene Generated by Chemical Vapor Deposition of Tetramethoxysilane on MFI Zeolite Catalyst2017

    • Author(s)
      Mitsuyoshi, Daisuke; Kuroiwa, Koji; Kataoka, Yuta; Nakagawa, Takuya; Kosaka, Misaki; Nakamura, Koshiro; Suganuma, Satoshi; Araki, Yasuhiro; Katada, Naonobu
    • Journal Title

      Micropor. Mesopor. Mater.

      Volume: 242 Pages: 118-126

    • DOI

      10.1016/j.micromeso.2017.01.022

    • NAID

      120006873124

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Catalytic Activity for Toluene Disproportionation by Loading Lewis Acidic Nickel Species on ZSM-5 Zeolite2017

    • Author(s)
      Satoshi Suganuma, Koshiro Nakamura, Akihito Okuda, Naonobu Katada
    • Journal Title

      Mol. Catal.

      Volume: 435 Pages: 110-117

    • DOI

      10.1016/j.mcat.2017.03.029

    • NAID

      120006543706

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Acidic Property on Catalytic Activity and Selectivity in Dehydration of Glycerol2017

    • Author(s)
      Suganuma, S., Hisazumi, T., Taruya, K., Tsuji, E., Katada, N.
    • Journal Title

      ChemistrySelect

      Volume: 2 Issue: 20 Pages: 5524-5531

    • DOI

      10.1002/slct.201700941

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids2017

    • Author(s)
      Koshiro Nakamura, Ryo Mizuta, Satoshi Suganuma, Etsushi Tsuji and Naonobu Katada
    • Journal Title

      Catal. Commun.

      Volume: 102 Pages: 103-107

    • DOI

      10.1016/j.catcom.2017.08.033

    • NAID

      120006873125

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of aldehydes from 1,2-alkanediols over silica-supported WO3 catalyst2016

    • Author(s)
      Sun, Daolai; Yamada, Yasuhiro; Sato, Satoshi; Suganuma, Satoshi; Katada, Naonobu
    • Journal Title

      Appl. Catal., A: Gen.

      Volume: 526 Pages: 164-171

    • DOI

      10.1016/j.apcata.2016.08.029

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] 固体酸触媒によるグリーンプロセスの開発2016

    • Author(s)
      菅沼学史
    • Journal Title

      化学工業

      Volume: 67 Pages: 32-37

    • Related Report
      2016 Research-status Report
  • [Presentation] 酸化チタン表面上での逆ミセル法によるブラウンミラーライト型酸化物超微粒子の合成2017

    • Author(s)
      平尾啓, 南部良輔, 出上慶貴, 辻悦司, 菅沼学史, 片田直伸
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      八王子
    • Year and Date
      2017-03-27
    • Related Report
      2016 Research-status Report
  • [Presentation] MFIゼオライト/W-V-O複合酸化物二機能性触媒上でのグリセロールからアクリル酸への脱水酸化反応2017

    • Author(s)
      樽谷孝太朗, 久住拓也, 菅沼学史, 辻悦司, 片田直伸
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] MFIゼオライト微粒子を担持したW-V-O複合酸化物の構造解析とグリセロール脱水酸化反応に対する触媒作用2017

    • Author(s)
      樽谷孝太朗, 久住拓也, 森脇休, 菅沼学史, 辻悦司, 片田直伸
    • Organizer
      第33回ゼオライト研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 減圧軽油中のアルキル多環芳香族の脱アルキル化反応―シリカモノレイヤー触媒の再生―2016

    • Author(s)
      竹田一貴, 衣笠圭祐, 佐藤大地, 菅沼学史, 片田直伸
    • Organizer
      第46回石油・石油化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2016-11-18
    • Related Report
      2016 Research-status Report
  • [Presentation] シリカモノレイヤー触媒の高温焼成によるアルキルナフタレンの脱アルキル化活性の変化2016

    • Author(s)
      衣笠圭祐, 川口侑亮, 竹田一貴, 菅沼学史, 片田直伸
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      盛岡
    • Year and Date
      2016-09-23
    • Related Report
      2016 Research-status Report
  • [Presentation] Co/ZSM-5ゼオライト上でのメタンによるベンゼンのメチル化反応2016

    • Author(s)
      中村浩史郎, 奥田章仁, 太田清貴, 菅沼学史, 辻悦司, 片田直伸
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      盛岡
    • Year and Date
      2016-09-22
    • Related Report
      2016 Research-status Report
  • [Presentation] モリブドバナドリン酸からなるKeggin型ヘテロポリ酸を部分酸化触媒に用いたグリセロール脱水酸化反応2016

    • Author(s)
      久住拓也, 樽谷孝太朗, 菅沼学史, 辻悦司, 片田直伸
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      盛岡
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] Benzene methylation by methane over Co supported on ZSM-5 zeolite catalysts: Influence of Co and Al contents2016

    • Author(s)
      Akihito Okuda, Kiyotaka Ohta, Satoshi Suganuma and Naonobu Katada
    • Organizer
      16th International Catalysis Congress
    • Place of Presentation
      Beijing
    • Year and Date
      2016-07-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of nitrogen-containing compounds on dealkylation of alkylnaphthalene catalyzed by silica monolayer2016

    • Author(s)
      Kazuki Takeda, Taku Matsuoka, Yusuke Kawaguchi, Shohii Fujiwara, Keisuke Kinugasa, Satoshi Suganuma and Naonobu Katada
    • Organizer
      16th International Catalysis Congress
    • Place of Presentation
      Beijing
    • Year and Date
      2016-07-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Bi-functional catalysts for single pass oxidehydration of glycerol into acrylic acid2016

    • Author(s)
      Takuya Hisazumi, Kazuki Morimoto, Satoshi Suganuma, Etsushi Tsuji and Naonobu Katada
    • Organizer
      16th International Catalysis Congress
    • Place of Presentation
      Beijing
    • Year and Date
      2016-07-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Compensation effect between activation entropy and enthalpy in reactions of benzene derivatives over various aluminosilicates2016

    • Author(s)
      Koshiro Nakamura, Ryo Mizuta, Satoshi Suganuma and Naonobu Katada
    • Organizer
      16th International Catalysis Congress
    • Place of Presentation
      Beijing
    • Year and Date
      2016-07-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Methane as methylating agent on Co/MFI zeolite catalyst2016

    • Author(s)
      Akihito Okuda, Kiyotaka Ohta, Satoshi Suganuma, Etsushi Tsuji and Naonobu Katada
    • Organizer
      Novel Catalysts for Energy and Environmental Issues
    • Place of Presentation
      Sapporo
    • Year and Date
      2016-07-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Influence of acidic properties of solid catalysts on dehydration of glycerol2016

    • Author(s)
      Satoshi Suganuma, Takuya Hisazumi and Naonobu Katada
    • Organizer
      Novel Catalysts for Energy and Environmental Issues
    • Place of Presentation
      Sappori
    • Year and Date
      2016-06-30
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Factors controlling Bronsted acid strength of zeolite2016

    • Author(s)
      Naonobu Katada and Satoshi Suganuma
    • Organizer
      18th International Zeolite Conference
    • Place of Presentation
      Rio de Janeiro
    • Year and Date
      2016-06-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Methylation of benzene by methane on ZSM-5 zeolite-supported cobalt catalyst2016

    • Author(s)
      Akihito Okuda, Kiyotaka Ohta, Satoshi Suganuma and Naonobu Katada
    • Organizer
      18th International Zeolite Conference
    • Place of Presentation
      Rio de Janeiro
    • Year and Date
      2016-06-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] シリカモノレイヤー触媒によるアルキル多環芳香族の脱アルキル化2016

    • Author(s)
      片田直伸, 松岡卓, 川口侑亮, 竹田一貴, 藤原翔平, 衣笠圭祐, 菅沼学史
    • Organizer
      石油学会第65回研究発表会
    • Place of Presentation
      船堀
    • Year and Date
      2016-05-24
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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