Sustainabele synthesis of useful chemicals from glycerol

• Project/Area Number: 16K18291
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Catalyst/Resource chemical process
• Research Institution: Tottori University
• Principal Investigator: Suganuma Satoshi 鳥取大学, 工学(系)研究科(研究院), 助教 (90731753)
• Project Period (FY): 2016-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: バイオマス変換 / グリセロール / アクロレイン / アクリル酸 / MFIゼオライト / W-V複合酸化物 / 脱水酸化反応 / 二機能性触媒 / ZSM-5 / 酸性質測定 / 二元機能触媒 / 触媒・化学プロセス / バイオマス / 資源・エネルギー有効利用技術

Outline of Final Research Achievements

A bifunctional catalyst consisting of small MFI zeolite crystallites covering crystals of W-V binary oxide with hexagonal tungsten bronze structure. One-pass oxidehydration of glycerol into acrylic acid was tested to show the high selectivity of MFI/W-V-O. Glycerol was dehydrated into acrolein by Bronsted acid sites on MFI, and acrolein was oxidized into acrylic acid by redox sites on W-V-O.

Research Products

• [Journal Article] Keggin-type Molybdovanadophosphoric Acids Loaded on ZSM-5 Zeolite as a Bifunctional Catalyst for Oxidehydration of Glycerol (2018)
  • Author(s): Suganuma, S., Hisazumi, T., Taruya, K., Tsuji, E., Katada, N.
  • Journal Title: Mol. Catal. Volume: 449 Pages: 85-92
  • DOI: 10.1016/j.mcat.2018.02.015
  • NAID: 120006873126
  • Peer Reviewed
• [Journal Article] Dealkylation of Alkyl Polycyclic Aromatic Hydrocarbon over Silica Monolayer Solid Acid Catalyst (2017)
  • Author(s): Katada, Naonobu; Kawaguchi, Yusuke; Takeda, Kazuki; Matsuoka, Taku; Uozumi, Naoki; Kanai, Kazuki; Fujiwara, Shohei; Kinugasa, Keisuke; Nakamura, Koshiro ; Suganuma, Satoshi ; Nanjo, Masato
  • Journal Title: Appl. Catal., A: Gen. Volume: 530 Pages: 93-101
  • DOI: 10.1016/j.apcata.2016.11.018
  • NAID: 120006873123
  • Peer Reviewed
• [Journal Article] Shape Selectivity in Toluene Disproportionation into para-Xylene Generated by Chemical Vapor Deposition of Tetramethoxysilane on MFI Zeolite Catalyst (2017)
  • Author(s): Mitsuyoshi, Daisuke; Kuroiwa, Koji; Kataoka, Yuta; Nakagawa, Takuya; Kosaka, Misaki; Nakamura, Koshiro; Suganuma, Satoshi; Araki, Yasuhiro; Katada, Naonobu
  • Journal Title: Micropor. Mesopor. Mater. Volume: 242 Pages: 118-126
  • DOI: 10.1016/j.micromeso.2017.01.022
  • NAID: 120006873124
  • Peer Reviewed
• [Journal Article] Enhancement of Catalytic Activity for Toluene Disproportionation by Loading Lewis Acidic Nickel Species on ZSM-5 Zeolite (2017)
  • Author(s): Satoshi Suganuma, Koshiro Nakamura, Akihito Okuda, Naonobu Katada
  • Journal Title: Mol. Catal. Volume: 435 Pages: 110-117
  • DOI: 10.1016/j.mcat.2017.03.029
  • NAID: 120006543706
  • Peer Reviewed
• [Journal Article] Influence of Acidic Property on Catalytic Activity and Selectivity in Dehydration of Glycerol (2017)
  • Author(s): Suganuma, S., Hisazumi, T., Taruya, K., Tsuji, E., Katada, N.
  • Journal Title: ChemistrySelect Volume: 2 Issue: 20 Pages: 5524-5531
  • DOI: 10.1002/slct.201700941
  • Peer Reviewed
• [Journal Article] Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids (2017)
  • Author(s): Koshiro Nakamura, Ryo Mizuta, Satoshi Suganuma, Etsushi Tsuji and Naonobu Katada
  • Journal Title: Catal. Commun. Volume: 102 Pages: 103-107
  • DOI: 10.1016/j.catcom.2017.08.033
  • NAID: 120006873125
  • Peer Reviewed
• [Journal Article] Production of aldehydes from 1,2-alkanediols over silica-supported WO3 catalyst (2016)
  • Author(s): Sun, Daolai; Yamada, Yasuhiro; Sato, Satoshi; Suganuma, Satoshi; Katada, Naonobu
  • Journal Title: Appl. Catal., A: Gen. Volume: 526 Pages: 164-171
  • DOI: 10.1016/j.apcata.2016.08.029
  • Peer Reviewed
• [Journal Article] 固体酸触媒によるグリーンプロセスの開発 (2016)
  • Author(s): 菅沼学史
  • Journal Title: 化学工業 Volume: 67 Pages: 32-37
• [Presentation] 酸化チタン表面上での逆ミセル法によるブラウンミラーライト型酸化物超微粒子の合成 (2017)
  • Author(s): 平尾啓, 南部良輔, 出上慶貴, 辻悦司, 菅沼学史, 片田直伸
  • Organizer: 電気化学会第84回大会
  • Place of Presentation: 八王子
  • Year and Date: 2017-03-27
• [Presentation] MFIゼオライト/W-V-O複合酸化物二機能性触媒上でのグリセロールからアクリル酸への脱水酸化反応 (2017)
  • Author(s): 樽谷孝太朗, 久住拓也, 菅沼学史, 辻悦司, 片田直伸
  • Organizer: 第120回触媒討論会
• [Presentation] MFIゼオライト微粒子を担持したW-V-O複合酸化物の構造解析とグリセロール脱水酸化反応に対する触媒作用 (2017)
  • Author(s): 樽谷孝太朗, 久住拓也, 森脇休, 菅沼学史, 辻悦司, 片田直伸
  • Organizer: 第33回ゼオライト研究発表会
• [Presentation] 減圧軽油中のアルキル多環芳香族の脱アルキル化反応―シリカモノレイヤー触媒の再生― (2016)
  • Author(s): 竹田一貴, 衣笠圭祐, 佐藤大地, 菅沼学史, 片田直伸
  • Organizer: 第46回石油・石油化学討論会
  • Place of Presentation: 京都
  • Year and Date: 2016-11-18
• [Presentation] シリカモノレイヤー触媒の高温焼成によるアルキルナフタレンの脱アルキル化活性の変化 (2016)
  • Author(s): 衣笠圭祐, 川口侑亮, 竹田一貴, 菅沼学史, 片田直伸
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 盛岡
  • Year and Date: 2016-09-23
• [Presentation] Co/ZSM-5ゼオライト上でのメタンによるベンゼンのメチル化反応 (2016)
  • Author(s): 中村浩史郎, 奥田章仁, 太田清貴, 菅沼学史, 辻悦司, 片田直伸
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 盛岡
  • Year and Date: 2016-09-22
• [Presentation] モリブドバナドリン酸からなるKeggin型ヘテロポリ酸を部分酸化触媒に用いたグリセロール脱水酸化反応 (2016)
  • Author(s): 久住拓也, 樽谷孝太朗, 菅沼学史, 辻悦司, 片田直伸
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 盛岡
  • Year and Date: 2016-09-21
• [Presentation] Benzene methylation by methane over Co supported on ZSM-5 zeolite catalysts: Influence of Co and Al contents (2016)
  • Author(s): Akihito Okuda, Kiyotaka Ohta, Satoshi Suganuma and Naonobu Katada
  • Organizer: 16th International Catalysis Congress
  • Place of Presentation: Beijing
  • Year and Date: 2016-07-07
  • Int'l Joint Research
• [Presentation] Effect of nitrogen-containing compounds on dealkylation of alkylnaphthalene catalyzed by silica monolayer (2016)
  • Author(s): Kazuki Takeda, Taku Matsuoka, Yusuke Kawaguchi, Shohii Fujiwara, Keisuke Kinugasa, Satoshi Suganuma and Naonobu Katada
  • Organizer: 16th International Catalysis Congress
  • Place of Presentation: Beijing
  • Year and Date: 2016-07-07
  • Int'l Joint Research
• [Presentation] Bi-functional catalysts for single pass oxidehydration of glycerol into acrylic acid (2016)
  • Author(s): Takuya Hisazumi, Kazuki Morimoto, Satoshi Suganuma, Etsushi Tsuji and Naonobu Katada
  • Organizer: 16th International Catalysis Congress
  • Place of Presentation: Beijing
  • Year and Date: 2016-07-07
  • Int'l Joint Research
• [Presentation] Compensation effect between activation entropy and enthalpy in reactions of benzene derivatives over various aluminosilicates (2016)
  • Author(s): Koshiro Nakamura, Ryo Mizuta, Satoshi Suganuma and Naonobu Katada
  • Organizer: 16th International Catalysis Congress
  • Place of Presentation: Beijing
  • Year and Date: 2016-07-05
  • Int'l Joint Research
• [Presentation] Methane as methylating agent on Co/MFI zeolite catalyst (2016)
  • Author(s): Akihito Okuda, Kiyotaka Ohta, Satoshi Suganuma, Etsushi Tsuji and Naonobu Katada
  • Organizer: Novel Catalysts for Energy and Environmental Issues
  • Place of Presentation: Sapporo
  • Year and Date: 2016-07-01
  • Int'l Joint Research
• [Presentation] Influence of acidic properties of solid catalysts on dehydration of glycerol (2016)
  • Author(s): Satoshi Suganuma, Takuya Hisazumi and Naonobu Katada
  • Organizer: Novel Catalysts for Energy and Environmental Issues
  • Place of Presentation: Sappori
  • Year and Date: 2016-06-30
  • Int'l Joint Research
• [Presentation] Factors controlling Bronsted acid strength of zeolite (2016)
  • Author(s): Naonobu Katada and Satoshi Suganuma
  • Organizer: 18th International Zeolite Conference
  • Place of Presentation: Rio de Janeiro
  • Year and Date: 2016-06-21
  • Int'l Joint Research
• [Presentation] Methylation of benzene by methane on ZSM-5 zeolite-supported cobalt catalyst (2016)
  • Author(s): Akihito Okuda, Kiyotaka Ohta, Satoshi Suganuma and Naonobu Katada
  • Organizer: 18th International Zeolite Conference
  • Place of Presentation: Rio de Janeiro
  • Year and Date: 2016-06-21
  • Int'l Joint Research
• [Presentation] シリカモノレイヤー触媒によるアルキル多環芳香族の脱アルキル化 (2016)
  • Author(s): 片田直伸, 松岡卓, 川口侑亮, 竹田一貴, 藤原翔平, 衣笠圭祐, 菅沼学史
  • Organizer: 石油学会第65回研究発表会
  • Place of Presentation: 船堀
  • Year and Date: 2016-05-24