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Cellulose derivatization for analysis of interactions between cellulose and ionic liquids

Research Project

Project/Area Number 16K18731
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Wood science
Research InstitutionKyoto University

Principal Investigator

ABE Mitsuru  京都大学, 農学研究科, 特別研究員(PD) (50734951)

Research Collaborator NISHIO Yoshiyuki  京都大学, 大学院農学研究科, 教授 (00156043)
SUGIMURA Kazuki  京都大学, 大学院農学研究科, 助教 (30711783)
NISHIYAMA Yoshiharu  Cermav-CNRS, 上級研究員
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsセルロース / イオン液体 / アルカリ水溶液 / 誘導体化反応 / 相互作用 / 水酸化物 / アセチル化 / ベンジル化 / アセチル化反応 / 置換基分布 / 相互作用解析 / 化学工学 / バイオマス / 有機化学
Outline of Final Research Achievements

Some ionic liquids have an excellent ability to dissolve an attractive polysaccharide, cellulose. However, the interactions between these ionic liquids and cellulose have not been sufficiently clarified yet. In this study, cellulose esterification and etherifications were conducted in several cellulose solvents including ionic liquids to analyze the cellulose-solvent interactions. It was found that cellulose acetylation followed by the distribution analysis of the acetyl substituents are promising method to understand the interactions.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (10 results)

All 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Int'l Joint Research] CERMAV-CNRS(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] 高等植物高分子研究所(Cermav)(フランス)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Rapid Benzylation of Cellulose in Tetra-n-butylphosphonium Hydroxide Aqueous Solution at Room Temperature2017

    • Author(s)
      M. Abe, K. Sugimura, Y. Nishiyama, Y. Nishio
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 5 Issue: 6 Pages: 4505-4510

    • DOI

      10.1021/acssuschemeng.7b00492

    • NAID

      120006313612

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Regioselectivity in Acetylation of Cellulose in Ionic Liquids2016

    • Author(s)
      M. Abe, K. Sugimura, and Y. Nishio
    • Journal Title

      Chemistry Select

      Volume: 1 Issue: 10 Pages: 2474-2478

    • DOI

      10.1002/slct.201600520

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] テトラアルキルホスホニウム水酸化物水溶液中でのセルロースの迅速エーテル化2018

    • Author(s)
      阿部充、杉村和紀、西山義春、西尾嘉之
    • Organizer
      第68回日本木材学会大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Rapid Benzylation of Cellulose in Tetra-n-butylphosphonium Hydroxide Aqueous Solution at Room Temperature2017

    • Author(s)
      Abe Mitsuru、Sugimura Kazuki、Nishiyama Yoshiharu、Nishio Yoshiyuki
    • Organizer
      66th SPSJ Annual Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] テトラブチルホスホニウム水酸化物水溶液中でのセルロースの迅速ベンジル化反応2017

    • Author(s)
      阿部充、杉村和紀、西山義春、西尾嘉之
    • Organizer
      セルロース学会第24回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ester and ether derivatization of cellulose using ionic liquids and related solvent systems2017

    • Author(s)
      Abe Mitsuru、Sugimura Kazuki、Nishiyama Yoshiharu、Nishio Yoshiyuki
    • Organizer
      The 4th International Cellulose Conference (ICC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] テトラアルキルホスホニウム水酸化物水溶液中でのセルロースの迅速エーテル化反応2017

    • Author(s)
      阿部充、杉村和紀、西山義春、西尾嘉之
    • Organizer
      第8回イオン液体討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] イオン液体中でのセルロースアセチル化反応における位置選択性2016

    • Author(s)
      阿部充、杉村和紀、西尾嘉之
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(兵庫県、神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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