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Synthesis of contracted helices as template for formation of pi-stack structure with substrate face-on orientation

Research Project

Project/Area Number 16K20885
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Device related chemistry
Functional solid state chemistry
Research InstitutionMuroran Institute of Technology

Principal Investigator

Mawatari Yasuteru  室蘭工業大学, 工学研究科, 助教 (40422000)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsπ共役系高分子 / ポリアセチレン / 置換ポリアセチレン / らせん / πスタック / 積層 / らせん伸縮 / 色彩可変 / 高分子合成 / 高分子構造・物性 / 有機導体 / 表面・界面物性
Outline of Final Research Achievements

Organic thin-film solar cells that are flexible, light, and able to be fabricated by coating process are promising candidates for next-generation solar cells because they can be fabricated by a coating process. Because the energy conversion efficiency is about half that of the silicon type, dramatic improvements are strongly desired. Aiming at the substrate face-on orientation of π-conjugated molecules contributing to the improvement of conversion efficiency, we tried to form stacked π-conjugated molecule utilizing helical polyaetylenes as a template. As the results, we succeeded to clarify molecular design for acquiring a contracted helical structure with solubility.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (9 results)

All 2017 2016

All Presentation (8 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results) Book (1 results)

  • [Presentation] Color gradation originated with stretch and contract of aromatic substituted helical polyacetylenes2017

    • Author(s)
      Yasuteru Mawatari, Masatoshi Tabata
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 伸縮するらせん状置換ポリアセチレンの段階的色彩制御2017

    • Author(s)
      馬渡康輝、田畑昌祥
    • Organizer
      第25回ポリイミド・芳香族系高分子会議,第25回ポリイミド・芳香族系高分子会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 芳香族置換ポリアセチレンの側鎖間πスタックに起因するらせん伸縮2017

    • Author(s)
      馬渡康輝、田畑昌祥
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Molecular design, synthesis, and characterization of substituted helical polyacetylenes toward color-tunable material2017

    • Author(s)
      Y. Mawatari, A. Kamegawa, M. Tabata
    • Organizer
      FiMPART'17
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] らせん伸縮に着目した置換ポリアセチレンの構造解析2017

    • Author(s)
      馬渡康輝
    • Organizer
      第13回電子移動化学若手の会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 側鎖間πスタックに起因するらせん状芳香族置換ポリアセチレンの溶液中での伸縮2017

    • Author(s)
      馬渡康輝、田畑昌祥
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ヘリカルポリフェニルアセチレンの溶液中の可逆的相転移2017

    • Author(s)
      馬渡康輝、田畑昌祥
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 嵩高い置換基を有するポリアセチレンの構造転移2016

    • Author(s)
      佐々木隆浩・馬渡康輝・田畑昌祥
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス(神奈川県横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Book] Carbon-related Materials in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE2017

    • Author(s)
      Y. Mawatari, M. Tabata
    • Total Pages
      22
    • Publisher
      Springer
    • ISBN
      9783319616513
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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