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Development of Structural Control Guidelines for Control of Mechanical, Electrical and Thermal Properties of Carbon Nanotubes

Research Project

Project/Area Number 16K20904
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Materials/Mechanics of materials
Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Shirasu Keiichi  東北大学, 工学研究科, 助教 (20757679)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsカーボンナノチューブ / 合成 / 熱処理 / 力学特性 / 線膨張係数 / 構造制御 / 公称強度 / 直径 / 結晶性 / 引張試験 / アニール処理 / 超高温アニール処理 / 電気伝導性
Outline of Final Research Achievements

To enable the development of multiwalled carbon nanotubes (MWCNTs) with superior mechanical properties, the structural-mechanical property relationships of MWCNTs were investigated. We showed that the nominal (engineering) tensile strength was written as a product of the fracture strength (effective strength) and fracture cross-section ratio that were calculated by the fracture cross-sectional area divided by the full cross-sectional area including the hollow core.
The axial coefficient of thermal expansion (CTE) of the MWCNTs was computed by using the Young’s modulus of the MWCNTs and CTE of the aligned MWCNT reinforced epoxy composites in rule of mixture, and the effects of the diameter and crystallinity of MWCNTs on the axial CTE were investigated. We demonstrated by thermal expansion testing that the MWCNTs were shown to possess negative CTEs, and the CTEs tended to become less negative with increasing diameter and crystallinity.

Academic Significance and Societal Importance of the Research Achievements

本研究は,CNTの構造と強度特性および線膨張係数との関係性を明らかにし,今後のCNT構造設計(合成条件や後処理条件)指針を提示できた点に大きな学術的意義がある.配向MWCNTシート・紡績糸ならびにそれを用いた複合材料は,材料・デバイスの軽量化や省エネルギー化によるCO2削減の有力な手段となる先端材料である.その構成要素であるCNT単体の構造と特性との関係性を明らかにできたことで,既存材料である炭素繊維やCFRPを超える軽量かつ高強度なCNT繊維の実現可能性が高まることが期待される.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (25 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Peer Reviewed: 8 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results) Presentation (12 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Book (2 results) Remarks (1 results)

  • [Int'l Joint Research] INSA-Lyon(フランス)

    • Related Report
      2017 Research-status Report
  • [Journal Article] How do the mechanical properties of carbon nanotubes increase? An experimental evaluation and modeling of the engineering tensile strength of individual carbon nanotubes2019

    • Author(s)
      Shirasu Keiichi、Yamamoto Go、Hashida Toshiyuki
    • Journal Title

      Materials Research Express

      Volume: 6 Issue: 5 Pages: 055047-055047

    • DOI

      10.1088/2053-1591/ab069f

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical and thermal expansion properties of aligned carbon nanotube reinforced epoxy composites2019

    • Author(s)
      SHIRASU Keiichi、TAMAKI Itaru、YAMAMOTO Go、HASHIDA Toshiyuki
    • Journal Title

      Mechanical Engineering Journal

      Volume: 6 Issue: 3 Pages: 19-00012-19-00012

    • DOI

      10.1299/mej.19-00012

    • NAID

      130007663718

    • ISSN
      2187-9745
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of graphitization on mechanical properties of untwisted carbon nanotube yarn and its strength development mechanism2018

    • Author(s)
      金 太成、林 晏理、二川 秀史、白須 圭一、山本 剛、橋田 俊之、細井 厚志、川田 宏之
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 84 Issue: 860 Pages: 17-00585-17-00585

    • DOI

      10.1299/transjsme.17-00585

    • NAID

      130006726276

    • ISSN
      2187-9761
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of large-movements and high-force electrothermal bimorph actuators based on aligned carbon nanotube reinforced epoxy composites2017

    • Author(s)
      Shirasu Keiichi、Yamamoto Go、Inoue Yoku、Ogasawara Toshio、Shimamura Yoshinobu、Hashida Toshiyuki
    • Journal Title

      Sensors and Actuators A: Physical

      Volume: 267 Pages: 455-463

    • DOI

      10.1016/j.sna.2017.10.051

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Key factors limiting carbon nanotube strength: Structural characterization and mechanical properties of multi-walled carbon nanotubes2017

    • Author(s)
      SHIRASU Keiichi、TAMAKI Itaru、MIYAZAKI Takamichi、YAMAMOTO Go、BEKAREVICH Raman、HIRAHARA Kaori、SHIMAMURA Yoshinobu、INOUE Yoku、HASHIDA Toshiyuki
    • Journal Title

      Mechanical Engineering Journal

      Volume: 4 Issue: 5 Pages: 17-00029-17-00029

    • DOI

      10.1299/mej.17-00029

    • NAID

      130006943406

    • ISSN
      2187-9745
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Evaluation of carbon nanotube strength for application to composite materials2017

    • Author(s)
      Keiichi Shirasu
    • Journal Title

      Proceedings of 13th International Conference on Advanced Materials and Nanotechnology

      Volume: 5 Pages: 69-69

    • Related Report
      2017 Research-status Report
  • [Journal Article] Potential use of CNTs for production of zero thermal expansion coefficient composite materials: An experimental evaluation of axial thermal expansion coefficient of CNTs using a combination of thermal expansion and uniaxial tensile tests2017

    • Author(s)
      Keiichi Shirasu, Akihiro Nakamura, Go Yamamoto, Toshio Ogasawara, Yoshinobu Shimamura, Yoku Inoue, Toshiyuki Hashida
    • Journal Title

      Composites Part A: Applied Science and Manufacturing

      Volume: 95 Pages: 152-160

    • DOI

      10.1016/j.compositesa.2016.12.027

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of structural defects on strength and fracture properties of multi-walled carbon nanotubes2017

    • Author(s)
      玉木格,白須圭一, 宮崎孝道, 山本剛, Raman Bekarevich, 平原佳織, 島村佳伸, 井上翼, 橋田俊之
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 83 Issue: 847 Pages: 16-00283-16-00283

    • DOI

      10.1299/transjsme.16-00283

    • NAID

      130006943707

    • ISSN
      2187-9761
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Temperature dependence of axial thermal expansion coefficient of multi-walled carbon nanotubes (A procedure based on measurements of coefficient of thermal expansion for aligned carbon nanotube/epoxy composites)2016

    • Author(s)
      白須圭一, 中村彰宏,山本剛, 小笠原俊夫, 島村佳伸, 井上翼, 橋田俊之
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 82 Issue: 844 Pages: 16-00228-16-00228

    • DOI

      10.1299/transjsme.16-00228

    • NAID

      130006943363

    • ISSN
      2187-9761
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 多層カーボンナノチューブのエチレンガス雰囲気下における加熱処理とその機械的特性に関する研究2019

    • Author(s)
      浅岡美穂,白須圭一,山本剛,橋田俊之
    • Organizer
      日本機械学会東北学生会 第49回学生員卒業研究発表講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Effect of crystallinity on axial thermal expansion coefficient of carbon nanotubes: Experimental and simulation studies2018

    • Author(s)
      Keiichi Shirasu, Go Yamamoto, Toshiyuki Hashida
    • Organizer
      The 5th Asian Symposium on Materials and Processing (ASMP2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CNT複合材料開発のためのCNT単体の力学特性評価2018

    • Author(s)
      白須圭一,山本剛,橋田俊之
    • Organizer
      日本機械学会M&M2018材料力学カンファレンス
    • Related Report
      2018 Annual Research Report
  • [Presentation] Evaluation of fracture and mechanical properties of carbon nanotubes by means of uniaxial tensile testing method2018

    • Author(s)
      Keiichi Shirasu, Luqman Hakim Bin Mat Yusoff , Go Yamamoto, Toshiyuki Hashida
    • Organizer
      1st CUHK-TU Joint Workshop on Advanced Materials and Manufacture
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 一軸引張り試験によるカーボンナノチューブの変形・破壊特性の評価に関する研究2018

    • Author(s)
      Luqman Hakim Bin Mat Yusoff,白須圭一,山本剛,橋田俊之
    • Organizer
      日本機械学会東北学生会第48回学生員卒業研究発表講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 多層カーボンナノチューブの熱処理による構造制御とその材料特性評価に関する研究2017

    • Author(s)
      玉木格,白須圭一,山本剛,橋田俊之
    • Organizer
      日本機械学会東北支部 第52期総会・講演会
    • Place of Presentation
      東北大学工学部青葉記念会館,仙台市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 水潤滑下におけるカーボンナノチューブ/アルミナ複合材料の摩擦・摩耗特性評価に関する研究2017

    • Author(s)
      宮浦拓人,中村陽文,白須圭一,山本剛,橋田俊之
    • Organizer
      日本機械学会東北学生会第47回学生員卒業研究発表講演会
    • Place of Presentation
      東北学院大学,多賀城市
    • Year and Date
      2017-03-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Preparation of Multi-Walled Carbon Nanotubes and Evaluation of their Mechanical Properties2017

    • Author(s)
      Keiichi Shirasu, Itaru Tamaki, Go Yamamoto and Toshiyuki Hashida
    • Organizer
      2nd USTB-TU Joint Workshop on Advanced Materials and Manufacture
    • Place of Presentation
      University of Science and Technology Beijing, Beijin, China
    • Year and Date
      2017-02-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of carbon nanotube strength for application to composite materials2017

    • Author(s)
      Keiichi Shirasu, Go Yamamoto, Toshiyuki Hashida
    • Organizer
      13th International Conference and Exhibition on Advanced Materials and Nanotechnology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 配向カーボンナノチューブ/エポキシ複合材料の線膨張係数に及ぼすカーボンナノチューブの結晶性の影響2017

    • Author(s)
      白須圭一,玉木格,山本剛,橋田俊之
    • Organizer
      第42回複合材料シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] Evaluation of Tensile properties of Multi-Walled Carbon Nanotubes Synthesized by Chemical Vapor Deposition2016

    • Author(s)
      Itaru Tamaki, Keiichi Shirasu, Takamichi Miyazaki, Go Yamamoto, Raman Bekarevich, Kaori Hirahara, Yoshinobu Shimamura, Yoku Inoue and Toshiyuki Hashida
    • Organizer
      Asia-Pacific Conference on Fracture and Strength 2016 (APCFS2016)
    • Place of Presentation
      Toyama International Conference Center, Toyama, Japan
    • Year and Date
      2016-09-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 配向カーボンナノチューブ複合材料の熱膨張測定に基づくカーボンナノチューブの軸方向線膨張係数の実験的評価とその温度依存性に関する研究2016

    • Author(s)
      白須圭一,中村彰宏,山本剛,小笠原俊夫,島村佳伸,井上翼,橋田俊之
    • Organizer
      日本機械学会東北支部 第52期秋季講演会
    • Place of Presentation
      秋田県民会館ジョイナス,秋田市
    • Year and Date
      2016-09-17
    • Related Report
      2016 Research-status Report
  • [Book] Carbon Nanotubes - Recent Progress (Chapter 6: Mechanical and Fracture Properties of Carbon Nanotubes)2018

    • Author(s)
      Keiichi Shirasu, Go Yamamoto, Daniel Nelias, Toshiyuki Hashida
    • Total Pages
      20
    • Publisher
      InTech open access publisher
    • ISBN
      9781789230536
    • Related Report
      2017 Research-status Report
  • [Book] 実用化に向けたソフトアクチュエータの開発と応用・制御技術2017

    • Author(s)
      白須圭一,山本剛,橋田俊之
    • Total Pages
      238
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Research-status Report
  • [Remarks] 東北大学橋田研究室ホームページ

    • URL

      http://www.hashidalab.rift.mech.tohoku.ac.jp/

    • Related Report
      2018 Annual Research Report 2017 Research-status Report 2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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