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Reversible Gelation of Electrolyte in Dye-Sensitized Solar Cell

Research Project

Project/Area Number 16K20960
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Composite materials/Surface and interface engineering
Research InstitutionChiba University

Principal Investigator

Hirose Yuji  千葉大学, 大学院工学研究院, 助教 (60400991)

Research Collaborator JOGASAKI Takumi  千葉大学, 大学院工学研究科, 大学院生
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords色素増感太陽電池 / 可逆ゲル / 電解液 / ダイラタント流体 / 発電効率 / ヨウ素 / ゲル化剤 / 粘度上昇 / ヨウ化リチウム / エタノール / 有機溶媒 / 太陽光発電 / 太陽電池 / 物性実験 / 流体 / ゲル
Outline of Final Research Achievements

To prevent the leakage of electrolyte solution and improve the power generation efficiency of a dye-sensitized solar cell (DSSC), electrolyte was added to “reversible gel” which turns into gel by shaking and regains the fluidity after a certain time. When the electrolyte was added in the reversible gel sample, precipitation was observed. However, the homogeneous sample can be prepared by adding some organic solvents. In addition, the sample was kept the behavior of reversible gel.
This sample was injected in DSSC and the voltage was measured by irradiating the light. The voltage increased gradually as time was elapsed. It is supposed that this unique phenomenon was occurred by lowering of viscosity of sample which turned into gel when it was injected to DSSC.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (13 results)

All 2018 2017 2016 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 3 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Rheological Behavior of Nanosilica Suspensions in Poly(Ethylene Oxide) Solutions with Sodium Chloride2017

    • Author(s)
      Hirose Yuji
    • Journal Title

      Materials Sciences and Applications

      Volume: 08 Issue: 05 Pages: 333-341

    • DOI

      10.4236/msa.2017.85022

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Rheological Behavior of Nanosilica Suspensions in Poly(Ethylene Oxide) Solutions with Sodium Chloride2017

    • Author(s)
      Yuji Hirose
    • Journal Title

      Materials Sciences and Applications

      Volume: 8

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] DYE-SENSITIZED SOLAR CELLS BASED ON ELECTROLYTE SOLUTION2018

    • Author(s)
      Yuji Hirose, Takumi Jogasaki and Hironao Ogura
    • Organizer
      Grand Renewable Energy 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリエチレングリコールオリゴマーを添加したナノシリカ分散系のダイラタント流動2018

    • Author(s)
      廣瀬裕二
    • Organizer
      日本レオロジー学会第45年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ヨウ化リチウムを加えたナノシリカ系振盪ゲルの粘度2017

    • Author(s)
      廣瀬 裕二
    • Organizer
      第66回高分子学会年次大会
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2017-05-29
    • Related Report
      2016 Research-status Report
  • [Presentation] Rheological Properties of Nanosilica Shaking Gels with Poly(Ethylene Glycol) and Lithium Iodide2017

    • Author(s)
      Yuji Hirose
    • Organizer
      10th World Congress of Chemical Engineering
    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ポリエチレングリコール/ナノシリカ系可逆ゲルのゲル化機構2017

    • Author(s)
      廣瀬裕二
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化スズを用いた色素増感太陽電池の性能評価2017

    • Author(s)
      城ヶ崎匠、廣瀬裕二
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ヨウ化リチウムを加えたナノシリカ系振盪ゲルの粘度2017

    • Author(s)
      廣瀬裕二
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] マイクロ粒子によるナノシリカ系可逆ゲルの粘度上昇2016

    • Author(s)
      廣瀬 裕二
    • Organizer
      第 64 回レオロジー討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-10-28
    • Related Report
      2016 Research-status Report
  • [Presentation] Effect of Particle Size Distribution on Rheological Behavior of Nanosilica Reversible Gel2016

    • Author(s)
      Yuji Hirose
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      京都テルサ
    • Year and Date
      2016-08-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] ゲル化・増粘剤の使い方、選び方 事例集2018

    • Author(s)
      酒井武彦、龍崎美智子、廣瀬裕二他
    • Total Pages
      691
    • Publisher
      技術情報協会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 千葉大学大学院工学研究科 廣瀬研究室HP

    • URL

      http://hirose-lab.tu.chiba-u.ac.jp/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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