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Production of metal ion separation membrane using graphene oxide

Research Project

Project/Area Number 16K21237
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Functional solid state chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology (2017)
Kumamoto University (2016)

Principal Investigator

Hatakeyama Kazuto  国立研究開発法人産業技術総合研究所, 材料・化学領域, 研究員 (30773965)

Research Collaborator Hirose Kyosuke  熊本大学, 学生
Matsumoto Yasumichi  熊本大学, 理事
Koinuma Michio  熊本大学, 准教授
Taniguchi Takaaki  物質材料研究機構, 主任研究員
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords酸化グラフェン / イオン分離膜 / 層間制御 / イオン透過速度 / イオン選択膜
Outline of Final Research Achievements

Graphene oxide (GO) produced from natural graphite shows excellent mechanical, gas barrier, proton conducting properties. Because of these properties, GO is expected to be introduced into wild field. In this study, we try to produce a metal ion separation membrane using a GO freestanding membrane. As a result, we have successfully tuned the copper ion permeation rate through GO freestanding membrane and found that the layer distance is the key factor that determines ion permeation. Moreover, we achieved to separate lead ion from lead and copper ion mixed solution. The separation mechanism was also explained by layer distance. These results are an important step in the study of the ion permeation properties of GO membranes.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (19 results)

All 2018 2017 2016

All Journal Article (11 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 11 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] The Effect of Layer Distance and Oxygen Content for Tuning Ion Permeation through Graphene Oxide Membrane2018

    • Author(s)
      Kazuto Hatakeyama、Kyosuke Hirose、Keisuke Awaya、Michio Koinuma、Narumi Kameda、Tetsuya Kida、Shinya Hayami、Yasumichi Matsumoto
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 3 Pages: 292-295

    • DOI

      10.1246/cl.171070

    • NAID

      130006434026

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermally conductive tough flexible elastomers as composite of slide-ring materials and surface modified boron nitride particles via plasma in solution2018

    • Author(s)
      Taku Goto, Masaki Iida, Helen Tan, Chang Liu, Koichi Mayumi, Rina Maeda, Koichi Kitahara, Kazuto Hatakeyama, Tsuyohito Ito, Yoshiki Shimizu, Hideaki Yokoyama, Kaoru Kimura, Kohzo Ito, Yukiya Hakuta, and Kazuo Terashima
    • Journal Title

      Appl. Phys. Lett. 112

      Volume: 112 Issue: 10 Pages: 101901-101901

    • DOI

      10.1063/1.5020325

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solid Electrolyte Gas Sensor Based on a Proton-Conducting Graphene Oxide Membrane2017

    • Author(s)
      Miyamoto Azumi、Kuwaki Yuta、Sano Toshifumi、Hatakeyama Kazuto、Quitain Armand、Sasaki Mitsuru、Kida Tetsuya
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 6 Pages: 2994-3001

    • DOI

      10.1021/acsomega.7b00239

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Role of hydrophilic groups in acid intercalated graphene oxide as a superionic conductor2017

    • Author(s)
      Wakata Kosuke、Islam Md. Saidul、Karim Mohammad Razaul、Hatakeyama Kazuto、Rabin Nurun Nahar、Ohtani Ryo、Nakamura Masaaki、Koinuma Michio、Hayami Shinya
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 35 Pages: 21901-21905

    • DOI

      10.1039/c7ra01634d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] All-Graphene Oxide Flexible Solid-State Supercapacitors with Enhanced Electrochemical Performance2017

    • Author(s)
      Chikamo Ogata, Ruriko Kurogi, Keisuke Awaya, Kazuto Hatakeyama, Takaaki Taniguchi, Michio Koinuma, Michio; Yasumichi Matsumoto
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 9 Issue: 31 Pages: 26151-26160

    • DOI

      10.1021/acsami.7b04180

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface state change effects of electrochemically oxidized/reduced glassy carbon on electrochemical capacitance2017

    • Author(s)
      Keisuke Awaya, Kazuto Hatakeyama, Michio Koinuma, Yasumichi Matsumoto
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 7 Pages: 1030-1032

    • DOI

      10.1246/cl.170253

    • NAID

      130005709478

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Production of water-dispersible reduced graphene oxide without stabilizers using liquid-phase photoreduction2017

    • Author(s)
      Hatakeyama Kazuto、Awaya Keisuke、Koinuma Michio、Shimizu Yoshiki、Hakuta Yukiya、Matsumoto Yasumichi
    • Journal Title

      Soft Matter

      Volume: 13 Issue: 45 Pages: 8353-8356

    • DOI

      10.1039/c7sm01386h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Proton conductors produced by chemical modifications of carbon allotropes, perovskites and metal organic frameworks2016

    • Author(s)
      Mohammad Razaul Karim, Kazuto Hatakeyama, Michio Koinuma, Shinya Hayami
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 16 Pages: 7243-7256

    • DOI

      10.1039/c6ta10923c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Interlayer Distance and Oxygen Content on Proton Conductivity of Graphite Oxide2016

    • Author(s)
      M. R. karim, M. S. Islam, K. Hatakeyama, M. Nakamura, R. Ohtani, M. Koinuma, S. Hayami
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 38 Pages: 21976-21982

    • DOI

      10.1021/acs.jpcc.6b06301

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Thermally Stable Super Ionic Conductor from Carbon Sphere Oxide2016

    • Author(s)
      M. S. Islam, M. R. Karim, K. Hatakeyama, H. Takehira, R. Ohtani, M. Nakamura, M. Koinuma, S. Hayami
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 16 Pages: 2322-2327

    • DOI

      10.1002/asia.201600835

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electrochemical detection of hydrogen using two-dimensional carbon nanosheets2016

    • Author(s)
      Azumi Miyamoto, Yuta Kuwaki, Kazuto Hatakeyama, Quitain Armando, Mitsura Sasaki, Yasumichi Matsumoto, Tetsuya Kida
    • Journal Title

      ECS Trans.

      Volume: 75 Issue: 16 Pages: 39-45

    • DOI

      10.1149/07516.0039ecst

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 酸化グラフェン膜のイオン透過特性2017

    • Author(s)
      畠山一翔
    • Organizer
      第8回酸化グラフェンシンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] The Factor of Ion Permeation through Graphene Oxide Membrane2017

    • Author(s)
      Kazuto Hatakeyama、Michio Koinuma、Shinya Hayami、Yasumichi Matsumoto
    • Organizer
      RPGR2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] pH調整光還元による水への高分散還元酸化グラフェンの作製2017

    • Author(s)
      畠山一翔、粟屋恵介、鯉沼陸央、清水禎樹、伯田幸也、松本泰道
    • Organizer
      グラフェン・酸化グラフェン合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Proton/Electron Mixed Conducting Property of Graphene Oxide2016

    • Author(s)
      Kazuto Hatakeyama, Michio Koinuma, Tetsuya Kida, Shinya Hayami, Yasumichi Matsumoto
    • Organizer
      The 8th annual Recent Progress in Graphene and Two-dimensional Materials Research (RPGR2016)
    • Place of Presentation
      Sungkyunkwan University, Korea
    • Year and Date
      2016-09-25
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Proton and Proton/Electron Mixed Conducting Properties of Graphene Oxide2016

    • Author(s)
      Kazuto Hatakeyama
    • Organizer
      UNISTでの特別講演
    • Place of Presentation
      UNIST, Koria
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高いプロトン伝導性と熱安定性を有した石炭酸化物2016

    • Author(s)
      畠山一翔、谷口貴章、鯉沼陸央、速水真也、松本泰道
    • Organizer
      第6回酸化グラフェンシンポジウム
    • Place of Presentation
      九州大学筑紫地区キャンパス、福岡
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸化グラフェン膜を通した銅イオン透過速度制御2016

    • Author(s)
      畠山一翔、廣瀬恭典、鯉沼陸央、速水真也、松本泰道
    • Organizer
      第6回酸化グラフェンシンポジウム
    • Place of Presentation
      九州大学筑紫地区キャンパス、福岡
    • Related Report
      2016 Research-status Report
  • [Presentation] 塩基性条件を用いた水への高分散性を有する 還元酸化グラフェンの作製2016

    • Author(s)
      畠山一翔、鯉沼陸央、松本泰道
    • Organizer
      第7回酸化グラフェンシンポジウム
    • Place of Presentation
      姫路商工会議所、兵庫
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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