| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
This research was aimed at the development of new organocatalytic reactions through the formation of halogen-bonding as the key driving force in the recognition and activation of substrates, based on theoretical and experimental methods. A new halogen bonding donor with the polyfluorinated core, which is expected to exhibit stronger Lewis acidity than previously known imidazolium sails-based halogen bonding donors, was successfully developed. Furthermore, the evaluation of the structural factors on the properties as halogen donors by DFT was conducted. The utilization of the halogen donors as a soft Lewis acid in organocatalytic reactions was attempted.
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