Highly Controlled New Materials of Heavy Group-14 Elements. Creation and Development of Their Unique Functions

• Project/Area Number: 17002005
• Research Category: Grant-in-Aid for Specially Promoted Research
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering; Chemistry
• Research Institution: Tohoku University
• Principal Investigator: KIRA Mitsuo Tohoku University, 理学研究科, 名誉教授 (40004452)
• Co-Investigator(Kenkyū-buntansha): IWAMOTO Takeaki 東北大学, 大学院理学研究科, 准教授 (70302081) ; SETAKA Wataru 東北大学, 高等教育開発推進センター, 助教 (60321775)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥237,120,000 (Direct Cost: ¥182,400,000、Indirect Cost: ¥54,720,000); Fiscal Year 2008: ¥27,430,000 (Direct Cost: ¥21,100,000、Indirect Cost: ¥6,330,000); Fiscal Year 2007: ¥27,430,000 (Direct Cost: ¥21,100,000、Indirect Cost: ¥6,330,000); Fiscal Year 2006: ¥95,940,000 (Direct Cost: ¥73,800,000、Indirect Cost: ¥22,140,000); Fiscal Year 2005: ¥86,320,000 (Direct Cost: ¥66,400,000、Indirect Cost: ¥19,920,000)
• Keywords: ケイ素 / 高周期14族元素 / ケイ素多重結合化合物 / 分子機械 / 安定シリレン / 安定シライミン / 重いアレン / 摂動論 / 分子ギア / シリカート / オリゴシラン / コロナン / ジシレン / 電荷移動吸収 / π-ジシレン錯体 / ロタキサン / 分子ジャイロスコープ / 水溶性オリゴシラン / テトラシラジエン / シクトテトラシレン / Woodward-Hoffmann則 / チオフェン / パラジウム / シラケテンイミン / トリシラアレン / シリレン / パラジウム錯体 / シクロテトラシレン / シクロデキストリン

Research Abstract

炭素では達成できない特異な構造・電子状態をもつ、ケイ素やゲルマニウムなどの高周期14族元素化合物を創製し、その結合、電子状態や物性を明らかにする。同時に、高周期14族元素を次世代機能材料の中心元素として用いるための新しい方法論を提供する。広く高周期典型元素の基礎化学をより現代的で高度なものとして発展させる。

Research Products

• [Journal Article] Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition (2009)
  • Author(s): Iwamoto, T.; Kobayashi, M.; Uchiyama, K.; Shin Sasaki; Nagendran, S.; Isobe, H.; Kira, M
  • Journal Title: J. Am. Chem. Soc 131 Pages: 3156-3157
  • Peer Reviewed
• [Journal Article] Isomerization of an Isolable Silylene into a Silene via 1,2-Silyl Migration (2009)
  • Author(s): Ishida, S.; Iwamoto, T.; Kira, M
  • Journal Title: Organometallics 28 (3) Pages: 919-921
  • Peer Reviewed
• [Journal Article] Isomerization of an Isolable Silylene into a Silene via 1,2-Sily1 Migration (2009)
  • Author(s): S.Ishida, 他2名
  • Journal Title: Organometallics 28 Pages: 919-921
  • Peer Reviewed
• [Journal Article] Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charae-Transfer Transition (2009)
  • Author(s): T.Iwamoto, 他7名
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 3156-3157
  • Peer Reviewed
• [Journal Article] Introduction of Clutch Function into a Molecular Gear System by Silane-Silicate Interconversion (2008)
  • Author(s): Setaka, W.; Nirengi, T.; Kabuto, C.; Kira, M
  • Journal Title: J. Am. Chem. Soc 130 Pages: 15762-15763
  • Peer Reviewed
• [Journal Article] Silicon-based Synthesis of [2]Rotaxanes without Polar Functional Groups and Their Axle Conformation Controlled by Wheel (2008)
  • Author(s): Phan, S. T.; Setaka, W.; Kira, M
  • Journal Title: Chem. Lett 37 Pages: 976-977
  • Peer Reviewed
• [Journal Article] Fourteen-electron bis(dialkylsilylene)palla-dium and twelve-electron bis(dialkylsilyl)-palladium complexes (2008)
  • Author(s): Watanabe, C.; Iwamoto, T.; Kabuto, C.; Kira, M
  • Journal Title: Angew. Chem. Int. Ed 47 Pages: 5386-5389
  • Peer Reviewed
• [Journal Article] 1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge-Ge σ Bond (2008)
  • Author(s): Iwamoto, T.; Yin, D.; Boomgaarden, S.; Kabuto, C.; Kira, M
  • Journal Title: Chem. Lett 37 Pages: 520-521
  • NAID: 10021080340
  • Peer Reviewed
• [Journal Article] Synthesis, structure, and facile ring flipping of a bicyclo[1.1.0]tetrasilane (2008)
  • Author(s): Ueba-Ohshima, K.; Iwamoto, T.; Kira, M
  • Journal Title: Organometallics 27 Pages: 320-323
  • Peer Reviewed
• [Journal Article] 1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge-Geδa Bond (2008)
  • Author(s): T.Iwamoto, 他4名
  • Journal Title: Chem. Lett. 37 Pages: 520-521
  • Peer Reviewed
• [Journal Article] Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes (2008)
  • Author(s): C.Watamabe, 他3名
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 5386-5389
  • Peer Reviewed
• [Journal Article] Silicon-based Synthesis of [2]Rotaxanes without Polar Functional Groups and Their Axle Conformation Controlled by Wheel (2008)
  • Author(s): S.T. Phan, 他2名
  • Journal Title: Chem. Lett. 37 Pages: 976-977
  • Peer Reviewed
• [Journal Article] Solvent Reorientation Process in the "Twisted" Intramolecular Charge-Transfer Process of Cyanophenyldisilane-(H20)2 Cluster Investigated by Transient Infrared Spectroscopy (2008)
  • Author(s): M.Sugiyama, 他4名
  • Journal Title: J. P.hys. Chem. A. 112 Pages: 1168-1171
  • Peer Reviewed
• [Journal Article] Introduction of Clutch Function into a Molecular Gear System by Silane-Silicate Interconversion (2008)
  • Author(s): W.Setaka, 他3名
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 15762-15763
  • Peer Reviewed
• [Journal Article] Formation of a Stannyistannylene via Intramolecular Carbene Insertion of a Transient Stannaacethvlene(RSn〓CR') (2008)
  • Author(s): W.Setaka, 他4名
  • Journal Title: Chem. Commun. Pages: 6558-6560
  • Peer Reviewed
• [Journal Article] Probing the reactivity of a stable silene using muonium (2008)
  • Author(s): B.M. McCollum, 他7名
  • Journal Title: Angew. Chem., Int. Ed. Engl. 47 Pages: 9772-9774
  • Peer Reviewed
• [Journal Article] Synthesis, Structure, and Facile Ring Flipping of a Bicyclo[1.1.0]-tetrasilane (2008)
  • Author(s): K. Ueba-Ohshima他2名
  • Journal Title: Organometallics 27 Pages: 320-323
  • Peer Reviewed
• [Journal Article] Thermal and photochemical cleavage of Si= Si double bond in tetrasila-1, 3-diene (2007)
  • Author(s): Uchiyama, K.; Nagendran, S.; Ishida, S.; Iwamoto, T.; Kira, M
  • Journal Title: J. Am. Chem. Soc 129 Pages: 10638-10639
  • Peer Reviewed
• [Journal Article] Ring-closing metathesis for the synthesis of phenylene-bridged silamacrocycles (2007)
  • Author(s): Phan, S. T.; Setaka, W.; Kira, M
  • Journal Title: Chem. Lett 36 Pages: 1180-1181
  • NAID: 10019846171
  • Peer Reviewed
• [Journal Article] A molecular gyroscope having phenylene rotator encased in three-spoke silicon-based stator (2007)
  • Author(s): Setaka, W.; Ohmizu, S.; Kabuto, C.; Kira, M
  • Journal Title: Chem. Lett 36 Pages: 1076-1077
  • NAID: 10019744772
  • Peer Reviewed
• [Journal Article] Synthesis of tricyclo[3.1.0.02,4]hexasilane and its photochemical isomerization to tricyclo-[2.2.0.02,5]hexasilane (2007)
  • Author(s): Iwamoto, T.; Uchiyama, K.; Kabuto, C.; Kira, M
  • Journal Title: Chem. Lett 36 Pages: 368-369
  • NAID: 10018829317
  • Peer Reviewed
• [Journal Article] Dinuclear Palladium Complex with a Bridging Dialkylsilylene Ligand (2007)
  • Author(s): Watanabe, C.; Iwamoto, T.; Kabuto, C.; Kira, M
  • Journal Title: Chem. Lett 36 Pages: 284-285
  • NAID: 10018522793
  • Peer Reviewed
• [Journal Article] Reactions of trisilaallene and 2-germadisilaallene with various reagents (2007)
  • Author(s): Iwamoto, T.; Abe, T.; Ishida, S.; Kabuto, C.; Kira, M
  • Journal Title: J. Organomet. Chem 692 Pages: 263-270
  • Peer Reviewed
• [Journal Article] A Helmeted Dialkylsilylene (2007)
  • Author(s): Kira, M.; Iwamoto, T.; Ishida, S
  • Journal Title: Bull. Chem. Soc. Jpn 80 Pages: 258-275
  • NAID: 10018517649
  • Peer Reviewed
• [Journal Article] A molecular gyroscope having phenylene rotator encased in three-spoke silicon-based stator (2007)
  • Author(s): W. Setaka, 他3名
  • Journal Title: Chem. Lett. 36 Pages: 1076-1077
  • NAID: 10019744772
  • Peer Reviewed
• [Journal Article] Ring-closing metathesis for the synthesis of phenylene-bridged silamacrocycles (2007)
  • Author(s): S. T. Phan他2名
  • Journal Title: Chem. Lett. 36 Pages: 1080-1081
  • Peer Reviewed
• [Journal Article] Synthesis and Structure of Ethynylsilyllithiums (2007)
  • Author(s): M. Kira, 他5名
  • Journal Title: Organometallics 26 Pages: 4890-4895
  • Peer Reviewed
• [Journal Article] Direct observation of the solvent reorientation dynamics in the "twisted" intramolecular charge-transfer process of cyanophenyldisilane-water cluster by transient infrared spectrocsopy (2007)
  • Author(s): H. Ishikawa他4名
  • Journal Title: Phys. Chem. Chem. Phys. 9 Pages: 117-126
  • Peer Reviewed
• [Journal Article] Thermal and Photochemical Cleavage of Si=Si Double Bond in Tetrasila-1,3-diene (2007)
  • Author(s): K. Uchiyama 他4名
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 10638-10639
  • Peer Reviewed
• [Journal Article] Reactions of trisilaallene and 2-germadisilaallene with various reagents (2007)
  • Author(s): T.Iwamoto他4名
  • Journal Title: J. Organomet. Chem. 692・1-3 Pages: 263-270
• [Journal Article] Direct observation of the solvent reorientation dynamics in the twisted intramolecular charge-transfer process of cyanophenyldisilane-water cluster by transient infrared spectroscopy (2007)
  • Author(s): H.Ishikawa他4名
  • Journal Title: Phys. Chem. Chem. Phys. 9・1 Pages: 117-126
• [Journal Article] Dinuclear palladium complex with a bridging dialkylsilylene ligand (2007)
  • Author(s): C.Watanabe他3名
  • Journal Title: Chem. Lett. 36・2 Pages: 284-285
• [Journal Article] Synthesis of tricyclo[3.1.0.0^<2,4>]hexasilane and its photochemical isomerization to tricyclo[2.2.0.0^<2,5>]hexasilane (2007)
  • Author(s): T.Iwamoto他3名
  • Journal Title: Chem. Lett. 36・3 Pages: 368-369
  • NAID: 10018829317
• [Journal Article] A Helmeted Dialkylsilylene (Award Accounts). (2007)
  • Author(s): M.Kira他2名
  • Journal Title: Bull. Chem. Soc. Jpn. 80・2 Pages: 258-275
• [Journal Article] Synthesis, properties, and reactions of a series of stable dialkyl-substituted silicon-chalcogen doubly bonded compounds (2006)
  • Author(s): Iwamoto, T.; Sato, K.; Ishida, S.; Kabuto, C.; Kira, M
  • Journal Title: J. Am. Chem. Soc 128 Pages: 16914-16920
  • Peer Reviewed
• [Journal Article] Phenylene bridged polysilaalkane macrocycles as framed molecular rotor (2006)
  • Author(s): Setaka, W.; Sato, K.; Ohkubo, A.; Kabuto, C.; Kira, M
  • Journal Title: Chem. Lett 35 Pages: 596-597
  • NAID: 10019162493
  • Peer Reviewed
• [Journal Article] Progress in the Chemistry of Stable Disilenes (2006)
  • Author(s): Kira, M.; Iwamoto, T
  • Journal Title: Adv. Organomet. Chem 54 Pages: 73-148
  • Peer Reviewed
• [Journal Article] Fused tricyclic disilenes with highly strained Si=Si double bonds : addition of a Si-Si single bond to a Si=Si double bond (2006)
  • Author(s): Tanaka, R.; Iwamoto, T.; Kira, M
  • Journal Title: Angew. Chem. Int. Ed. Engl 45 Pages: 6371-6373
  • Peer Reviewed
• [Journal Article] Synthesis, structure, and bonding of stable dialkylsilaketenimines (2006)
  • Author(s): Abe, T.; Iwamoto, T.; Kabuto, C.; Kira, M
  • Journal Title: J. Am. Chem. Soc 128 Pages: 4228-4229
  • Peer Reviewed
• [Journal Article] Ligand dependence of π-complex character in disilene-palladium complexes (2006)
  • Author(s): Iwamoto, T.; Sekiguchi, Y.; Yoshida, N.; Kabuto, C.; Kira, M
  • Journal Title: Dalton Trans Pages: 177-182
  • Peer Reviewed
• [Journal Article] Phenylene bridged polysilaalkane macrocycles as framed molecular rotor (2006)
  • Author(s): W.Setaka他4名
  • Journal Title: Chem. Lett. 35・6 Pages: 596-597
  • NAID: 10019162493
• [Journal Article] Fused tricyclic disilenes with highly strained Si=Si double bonds : addition of a Si-Si single bond to a Si=Si double bond (2006)
  • Author(s): R.Tanaka他2名
  • Journal Title: Angew. Chem. Int. Ed. Engl. 45・38 Pages: 6371-6373
• [Journal Article] Trimethylsilyl-substituted dibenzodehydro[12]annulene having high thermal and chemical stability (2006)
  • Author(s): W.Setaka他3名
  • Journal Title: Chem. Lett. 35・12 Pages: 1364-1365
  • NAID: 10020134572
• [Journal Article] Synthesis, properties, and reactions of a series of stable dialkyl-substituted silicon-chalcogen doubly bonded compounds (2006)
  • Author(s): T.Iwamoto他4名
  • Journal Title: J. Am. Chem. Soc. 128・51 Pages: 16914-16920
• [Journal Article] Ligand dependence of π-complex character in disilene-palladium complexes (2006)
  • Author(s): T.Iwamoto他4名
  • Journal Title: Dalton Trans. No.1 Pages: 177-182
• [Journal Article] Synthesis, structure, and bonding of stable dialkylsilaketenimines (2006)
  • Author(s): T.Abe他3名
  • Journal Title: J.Am.Chem.Soc. Vol.128(印刷中)
• [Journal Article] A stable fused bicyclic disilene as a model for silicon surface (2005)
  • Author(s): Kobayashi, H.; Iwamoto, T.; Kira, M
  • Journal Title: J. Am. Chem. Soc 127 Pages: 15376-15377
  • Peer Reviewed
• [Journal Article] A missing group-14 element trimetallaallene. 2-Germadisilaallene (2005)
  • Author(s): Iwamoto, T.; Abe, T.; Kabuto, C.; Kira, M
  • Journal Title: Chem. Commun Pages: 5190-5192
  • Peer Reviewed
• [Journal Article] New molecular systems with silicon-silicon multiple bonds (2005)
  • Author(s): Kira, M.; Iwamoto, T.; Ishida, S
  • Journal Title: Organosilicon Chemistry VI-From Molecules to Materials, (Auner, N.; Weis, J., Eds) Pages: 25-32
  • Peer Reviewed
• [Journal Article] Intramolecular charge-transfer fluorescence of 1-phenyltridecamethylbicyclo [2.2.2]octasilane (2005)
  • Author(s): W.Setaka他3名
  • Journal Title: Chem.Commun. No.37 Pages: 4666-4668
• [Journal Article] A missing group-14 element trimetallaallene. 2-Germadisilaallene (2005)
  • Author(s): T.Iwamoto他3名
  • Journal Title: Chem.Commun. No.41 Pages: 5190-5192
• [Journal Article] Determination of the equilibrium structure of the charge-transfer state of (p-cyanophenyl)pentamethyldisilane by means of transient infrared spectroscopy (2005)
  • Author(s): H.Ishikawa他5名
  • Journal Title: J.Phys.Chem.A Vol.109 No.40 Pages: 8959-8961
• [Journal Article] A stable fused bicyclic disilene as a model for silicon surface (2005)
  • Author(s): H.Kobayashi他2名
  • Journal Title: J.Am.Chem.Soc. Vol.127 No.44 Pages: 15376-15377
• [Journal Article] 最近の研究から。ケイ素およびゲルマニウムを骨格に含む安定なアレンの構造と電子状態 (2005)
  • Author(s): 岩本武明他2名
  • Journal Title: 日本結晶学会誌 Vol.47 No.5 Pages: 348-353
• [Presentation] Distinctive chemistry of a stable silicon divalent compound (2009)
  • Author(s): Kira, M
  • Organizer: 1st International Symposium on Modern Organic Chemistry
  • Place of Presentation: Monastir, Tunisia
  • Year and Date: 2009-02-21
• [Presentation] Distinctive Chemistry of a Stable Silicon Divalent Compound (2009)
  • Author(s): M. Kira
  • Organizer: International Symposium on Modern Organic Chemistry
  • Place of Presentation: Monastir, Tunisia
  • Year and Date: 2009-02-21
• [Presentation] ケイ素の特長を利用した分子機械の合成と構造 (2008)
  • Author(s): 瀬高渉
  • Organizer: 第1回有機立体化学研究会
  • Place of Presentation: さぬき
  • Year and Date: 2008-12-20
• [Presentation] かご型ポリシラアルカンフレームをもつ分子コンパスの合成と構造 (2008)
  • Author(s): 瀬高渉, 他4名
  • Organizer: 第19回基礎有機化学討論会((第38回構造有機化学討論会・第58回有機反応化学討論会))
  • Place of Presentation: 吹田
  • Year and Date: 2008-10-04
• [Presentation] Stable Tetrasiladiene and Disilenide Derived from Isolable Dialkylsilylene (2008)
  • Author(s): T. Iwamoto, M. Kobayashi, K. Uchiyama, S. Sasaki, H. Isobe, M. Kira
  • Organizer: 第55回有機金属化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-28
• [Presentation] アミノメチル基を有するフェニルジシランの合成と分子内電荷移動 (2008)
  • Author(s): 瀬高渉, 他2名
  • Organizer: 光化学討論会2008
  • Place of Presentation: 堺
  • Year and Date: 2008-09-12
• [Presentation] STRUCTURE OF SILAHYDROCARBON ROTAXANE (2008)
  • Author(s): Wataru Setaka, 他2名
  • Organizer: Yamada Conference 2008"Topological Molecules"
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2008-09-03
• [Presentation] PHENYLENE-BRIDGED POLYSILAALKANE MACROCAGE AS A MOLECULAR COMPASS (2008)
  • Author(s): Wataru Setaka, 他2名
  • Organizer: The third Joint International Symposium on Macrocyclic & Supramolecular Chemistry (III ISMSC)
  • Place of Presentation: Las Vegas, USA
  • Year and Date: 2008-07-17
• [Presentation] THIOPHENE-BRIDGED SILAMACROCAGE AS A MOLECULAR COMPASS (2008)
  • Author(s): Wataru Setaka他2名
  • Organizer: The 15^<th> International Symposium on Organosilicon Chemistry (ISOS-XV)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2008-06-03
• [Presentation] A study toward silicon-based molecular machines (2008)
  • Author(s): Kira, M
  • Organizer: 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2008-06-02
• [Presentation] Stable Tetrasiladiene and Disilenide Derived from Isolable Dialkylsilylene (2008)
  • Author(s): Iwamoto, T
  • Organizer: 15th International Symposium on Organisilicon Chemistry
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2008-06-02
• [Presentation] A Study Directed toward Silicon-Based Molecular Machines (2008)
  • Author(s): M. Kira
  • Organizer: 第15回有機ケイ素科学国際会議(ISOSXV)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2008-06-02
• [Presentation] Transition metal complexes with disilene, digermene, and silylene ligands (2008)
  • Author(s): Kira, M
  • Organizer: 41th Silicon Symposium
  • Place of Presentation: San Francisco, USA
  • Year and Date: 2008-04-26
• [Presentation] Transition Metal Complexes with Disilene, Digermene, and Silylene Ligands (2008)
  • Author(s): M. Kira
  • Organizer: 第41回シリコンシンポジウム
  • Place of Presentation: San Francisco, USA
  • Year and Date: 2008-04-26
• [Presentation] Stable Bicyclo[1.1.0]tetrasilane Radical Anion (2008)
  • Author(s): T. Iwamoto, K. Ohshima-Ueba, M. Kira
  • Organizer: 第41回シリコンシンポジウム
  • Place of Presentation: San Francisco, USA
  • Year and Date: 2008-04-26
• [Presentation] Ring Expansion Reaction of Silylnenecyclotetrasilane to cyclopentasilene (2008)
  • Author(s): T. Iwamoto, K. Ohshima-Ueba, M. Kira
  • Organizer: 第41回シリコンシンポジウム
  • Place of Presentation: San Francisco, USA
  • Year and Date: 2008-04-26
• [Presentation] SYNTHESIS AND STRUCTURE OF SILAHYDROCARBON ROTAXANE (2008)
  • Author(s): Wataru Setaka, 他2名
  • Organizer: The 41st Silicon Symposium
  • Place of Presentation: San Francisco, USA
  • Year and Date: 2008-04-26
• [Presentation] ジトリプチシルトリフルオロシリカートの置換基回転ダイナミクス (2008)
  • Author(s): 二連木隆佳他 3名
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-27
• [Presentation] アントリル置換ジシレンの合成と構造 (2008)
  • Author(s): 小林麻衣子他3名
  • Organizer: 第88回日本化学会春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-26
• [Presentation] シリレンシクロテトラシレンの合成および反応 (2008)
  • Author(s): 降矢裕一他5名
  • Organizer: 第88回日本化学会春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-26
• [Presentation] 安定ジアルキルシリレンとハロアルカン類の反応の機構 (2008)
  • Author(s): 吉良満夫West 先生
  • Organizer: 日本化学会外国人名誉会員記念有機元素化学ミニシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-03-25
• [Presentation] 安定ジアルキルシリレンとハロアルカン類の反応の機構 (2008)
  • Author(s): 吉良満夫
  • Organizer: West先生日本化学会外国人名誉会員記念有機元素化学巳にシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-03-25
• [Presentation] 分子コンパスとしてのチオフェン架橋かご型ポリシラアルカンの合成と構造 (2007)
  • Author(s): 瀬高渉他 2名
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 吹田
  • Year and Date: 2007-12-13
• [Presentation] シリレンシクロテトラシランの合成およびジオトロピック転位 (2007)
  • Author(s): 降矢裕一他4名
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 大坂
  • Year and Date: 2007-12-13
• [Presentation] ジアルキルシライミンの合成と構造 (2007)
  • Author(s): 桂珍玉他5名
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 大坂
  • Year and Date: 2007-12-13
• [Presentation] Directed Approach to the Synthesis of SIlicon-Based Rotaxanes (2007)
  • Author(s): S. T. Phan 他2名
  • Organizer: 1st Asian Silicon Symposium (ASiS-1)
  • Place of Presentation: Zao, Japan
  • Year and Date: 2007-11-01
• [Presentation] Trifluoro[bis(9-triptycyl)]silicates Showing Unique Molecular Motion in Solution (2007)
  • Author(s): T. Nirengi 他2名
  • Organizer: 1st Asian Silicon Symposium (ASiS-1)
  • Place of Presentation: Zao, Japan
  • Year and Date: 2007-11-01
• [Presentation] Synthesis and Structure of Silicon-Based Molecular Gyroscopes (2007)
  • Author(s): Wataru Setaka 他3名
  • Organizer: 1st Asian Silicon Symposium (ASiS-1)
  • Place of Presentation: Zao, Japan
  • Year and Date: 2007-11-01
• [Presentation] Synthesis and Dyotropic Rearrangement of Silylenecyclotetrasilane (2007)
  • Author(s): Yuichi Furiya 他4名
  • Organizer: The First Asian Silicon Symposium (ASiS-1)
  • Place of Presentation: 蔵王
  • Year and Date: 2007-11-01
• [Presentation] 新規ジアリール置換六員環状ジシレンの合成および反応 (2007)
  • Author(s): 阿部剛 他3名
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2007-10-27
• [Presentation] シリル置換シクロテトラシラン-1,3-ジイルアニオンラジカルの合成、構造および電子状態 (2007)
  • Author(s): 上羽澄美ほか2名
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 広島
  • Year and Date: 2007-10-27
• [Presentation] Novel palladium complexes featuring isolable dialkylsilylenes (2007)
  • Author(s): Iwamoto, T
  • Organizer: 4th European Silicon Days Conference
  • Place of Presentation: Bath, UK
  • Year and Date: 2007-09-10
• [Presentation] Novel palladium complexes featuring isolable dialkylsilylenes (2007)
  • Author(s): T. Iwamoto
  • Organizer: 4th European Silicon Days Conference
  • Place of Presentation: イギリス バース
  • Year and Date: 2007-09-09
• [Presentation] 社会に役立つケイ素 (2007)
  • Author(s): 吉良満夫
  • Organizer: 第30回教師のための化学教育講座
  • Place of Presentation: 郡山
  • Year and Date: 2007-08-10
• [Presentation] Synthesis and structure of phenylene-bridged polysilaalkane macrocage as molecular top (2007)
  • Author(s): W. Setaka 他3名
  • Organizer: 12th International Synposium on Novel Aromatic Compounds (ISNA-12)
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2007-07-22
• [Presentation] 安定シリレンおよびジシレンを配位子とする遷移金属錯体 (2007)
  • Author(s): 吉良満夫
  • Organizer: 有機金属部会平成19年度第1回例会
  • Place of Presentation: 大阪
  • Year and Date: 2007-04-16
• [Presentation] 安定シリレンおよびジシレンを配位子とする遷移金属錯体 (2007)
  • Author(s): 吉良満夫
  • Organizer: 有機金属部会平成19年度第1回例会
  • Place of Presentation: 大坂
  • Year and Date: 2007-04-16
• [Presentation] Silicon-Based Molecular Machines (2007)
  • Author(s): Kira, M
  • Organizer: International Workshop on Advanced Chemical Materials for Medical Application
  • Place of Presentation: Wonju, Korea
  • Year and Date: 2007-01-23
• [Presentation] Recent Advances in the Chemistry of a Helmeted Dialkylsilylene (2006)
  • Author(s): Kira, M
  • Organizer: 1st International Conference on Cutting-Edge Organic Chemistry
  • Place of Presentation: Asia, Naha
  • Year and Date: 2006-10-17
• [Presentation] シリコンがつくる新しい社会 (2006)
  • Author(s): 吉良満夫
  • Organizer: ものづくり化学-化学の不思議と夢 講演会
  • Place of Presentation: 東京
  • Year and Date: 2006-10-14
• [Presentation] 25周年を迎えた安定ケイ素二重結合化合物の化学 (2006)
  • Author(s): 吉良満夫
  • Organizer: 元素相乗系化合物の化学第1回シンポジウム
  • Place of Presentation: 札幌
  • Year and Date: 2006-10-13
• [Presentation] 安定なケイ素二価化合物(シリレン)の化学-新展開 (2006)
  • Author(s): 吉良満夫
  • Organizer: 第18回基礎有機化学連合討論会
  • Place of Presentation: 福岡
  • Year and Date: 2006-10-09
• [Presentation] ケイ素化学は有機化学を超えられるか (2006)
  • Author(s): 吉良満夫
  • Organizer: 有機化学コロキウム
  • Place of Presentation: 秋田
  • Year and Date: 2006-09-22
• [Presentation] Unique Reactions of Transition Metal Complexes of Disilenes and Digermenes (2006)
  • Author(s): Kira, M
  • Organizer: 2nd International Symposium of Core-to-Core Program on Main Group Chemistry
  • Place of Presentation: Tokyo
  • Year and Date: 2006-08-27
• [Presentation] Transition Metal Complexes of Disilene, Digermene, and Silylene (2006)
  • Author(s): Kira, M
  • Organizer: 24th Annual Workshop on Organosilicon Chemistry
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2006-05-26
• [Presentation] Unique Reactions of Stable Trisilaallene and Related Compounds (2006)
  • Author(s): Iwamoto T
  • Organizer: The 39th Silicon Symposium, Frankenmuth
  • Place of Presentation: USA
  • Year and Date: 2006-05-17
• [Presentation] Anti-ApicophilicDitriptyciltrifluorosilicate ; An Application for Clutch Function in Molecular Gear System (2006)
  • Author(s): Setaka, W
  • Organizer: 39th Organosilicon Symposium
  • Place of Presentation: Frankenmuth MI (USA)
  • Year and Date: 2006-05-17
• [Presentation] Novel Disilene- and Digermene-Transition Metal Complexes (2005)
  • Author(s): Kira, M
  • Organizer: International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2005)
  • Place of Presentation: Honolulu, USA
  • Year and Date: 2005-12-18
• [Presentation] Unusual Dynamic Structure of Heavy Group-14 Element Trimetallaallenes (2005)
  • Author(s): Kira, M
  • Organizer: International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2005)
  • Place of Presentation: Honolulu, USA
  • Year and Date: 2005-12-17
• [Presentation] Recent Advances in the Chemistry of Stable Dialkylsilylene (2005)
  • Author(s): Kira, M
  • Organizer: 2nd Tsukuba International Symposium on Organic Main Group Chemistry
  • Place of Presentation: Tsukuba, Japan
  • Year and Date: 2005-12-02
• [Presentation] Silicon-Based Molecular Rotors (2005)
  • Author(s): Kira, M
  • Organizer: 13th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2005-11-24
• [Presentation] Synthesis and Molecular Structure of the First Bis(silaketenimine) (2005)
  • Author(s): Iwamoto, T
  • Organizer: The 14th International Symposium on Organometallic Chemistry
  • Place of Presentation: Wurzburg, Germany
  • Year and Date: 2005-08-03
• [Presentation] A Stable Silylene : A Key Building Block for Novel Unsaturated Silicon Compounds (2005)
  • Author(s): Kira, M
  • Organizer: 14th International Symposium on Organosilicon Chemistry (XIV ISOS)
  • Place of Presentation: Wurzburg, Germany
  • Year and Date: 2005-08-01
• [Presentation] 不飽和ケイ素化合物の遷移金属錯体 (2005)
  • Author(s): 吉良満夫
  • Organizer: 無機・分析化学コロキウム
  • Place of Presentation: 川渡(宮城)
  • Year and Date: 2005-07-02
• [Presentation] Molecular Tops with Silaalkane Chains as a Frame (2005)
  • Author(s): Setaka, W
  • Organizer: 38th Organosilicon Symposium
  • Place of Presentation: Boulder (USA)
  • Year and Date: 2005-06-04
• [Book] Adv. Organometal. Chem. 54巻 "Progress in the Chemistry of Stable Disilenes" (2006)
  • Author(s): M.Kira他1名
  • Total Pages: 79
  • Publisher: Elsevier, Inc.
• [Book] Progress in the Chemistry of Stable Disilenes, Adv.Organometal.Chem. (2006)
  • Author(s): M.Kira他1名
  • Total Pages: 79
  • Publisher: Elsevier, Inc.(印刷中)
• [Book] In Organosilicon Chmeistry VI-From Molecules to Materials(N.Auner and J.Weis, Eds.)Chapter 1 New molecular systems with silicon-silicon multiple bonds (2005)
  • Author(s): M.Kira他2名
  • Total Pages: 8
  • Publisher: Wiley-VCH