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Molecular Design and Magnetism of Polyoxometalates-based Nanomagnets Exhibiting Quantum Hysteresis

Research Project

Project/Area Number 17002006
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

YAMASE Toshihiro  Tokyo Institute of Technology, Chem. Resources Lab., Professor (80016576)

Co-Investigator(Kenkyū-buntansha) NARUKE Haruo  Tokyo Institute of Technology, Chem. Resources Lab., Associate Professor (40237623)
OZEKI Tomoji  Tokyo Institute of Technology, Grad. School Sci. & Eng., Associate Professor (60214136)
ISHIKAWA Eri  Chubu Univ., Dept. Appl Chem., Associate Professor (90323831)
ITOH Takeru  Tokai Univ., Dept. Chem., Assistant Professor (50376935)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥181,090,000 (Direct Cost: ¥139,300,000、Indirect Cost: ¥41,790,000)
Fiscal Year 2007: ¥36,400,000 (Direct Cost: ¥28,000,000、Indirect Cost: ¥8,400,000)
Fiscal Year 2006: ¥37,050,000 (Direct Cost: ¥28,500,000、Indirect Cost: ¥8,550,000)
Fiscal Year 2005: ¥107,640,000 (Direct Cost: ¥82,800,000、Indirect Cost: ¥24,840,000)
KeywordsSpin Hexagon / Mo-blue Nano-rings / Photo-induced Self-assembly / Rhombic Spin Tetragon / Spin triangle and Spin Prism / Molecular Magnetism / Near-infrared Light-induced Electroconductivity / Quantum Hysteresis / 菱形スピンポリ酸 / ナノリングポリ酸 / 希土類ポリ類 / 量子トンネル / 六角、菱形スピンポリ酸 / 強磁性ポリ酸 / 六角スピンポリ酸 / スピンボールポリ酸 / ナノチューブポリ酸 / ESR / 分子磁石 / 交換相互作用 / ハイゼンベルグ相互作用
Research Abstract

Since we found the spin-frustrated (VO)_3^<6+>-triangle sandwiched by two diamagnetic α-B-[XW_9O_<33>]^<9-> (X=Sb^<III> and Bi^<III>) ligands in [(VO)_3(SbW_9O_<33>)_2]^<12-> and [(VO)_3(BiW_9O_<33>)_2]^<12-> as a simple model of the magnetization (involving Dzyaloshinsky-Moriya interaction) between pure quantum states S=1/2 and S=3/2 in 2004, we have clarified the magnetochemistry of a variety of the spin rings embedded in polyoxometalates for understanding the quantum hysteresis of spin rings at molecular level, as well as the self-assembly mechanism for establishing a methodology of molecular design of these novel polyoxometalates. The results constitute a basis for establishment of the polyoxometalate-based electronic/magnetic devices:
(1) Details of photochemically controlled self-assembly to superclusters such as nano-rings, -ball, -ellipsoids, -egg, -chains, and -tubes have been clarified together with their structure chemistry, which enable us successfully to design of a variety of nano-sized polyoxometalate super clusters.
(2) Molecular magnetisms (magnitudes of J and Δ, and their origins) of spin hexagon, spin prism, and rhombic spin tetragon have been clarified by designing the model compounds such as [(CuCl)_6(AsW_9O_<33>)_2]^<12->, [Mn_6(H_2O)_2(AsW_9O_<34>)_2(AsW_6O_<26>)]^<17->, and [Cu_4(GeW_9O_<34>)_2]^<12->14H_2O, which provide quantum tunneling, quantum hysteresis, anisotropy at zero field, and point-dipole approximation in magnetization experiments.
(3) The near infra-red light-induced photoconductivity of Mo-blue giant clusters is found, and a significance of the coordination of aqua ligands on the molecular surface in photoconduction is pointed out.

Report

(7 results)
  • 2013 Self-evaluation (Follow-up Assessment) ( PDF )   Comments (Follow-up Assessment) ( PDF )
  • 2012 Abstract(Follow-up Assessment) ( PDF )
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (138 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (89 results) (of which Peer Reviewed: 39 results) Presentation (30 results) Book (11 results) Patent(Industrial Property Rights) (8 results)

  • [Journal Article] Structure and Magnetism of[n-BuNH_3]_<12>[Cu_4(GeW_9O_<34>)_2]14H_2OSandwiching a Rhomb-like Cu_4^<8+>Tetragon through α-Keggin Linkage2009

    • Author(s)
      T. Yamase, H. Abe, E. Ishikawa, H. Nojiri, Y. Ohshima
    • Journal Title

      Inorg. Chem. 48

      Pages: 138-148

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Inorganic-Organic Hybrid Layered Crystal Composed of Polyoxomolybdates and Surfactant with π-Electrons2009

    • Author(s)
      T. Ito, T. Yamase
    • Journal Title

      Chem. Lett. (in press)

    • NAID

      10025121101

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structure and Magnetism of [n-BuNH_3]_<12>[Cu_4(GeW_9O_<34>)_2]・14H_2O Sandwiching a Rhomb-like Cu_4^<8+> Tetragon through α-Keggin Linkage2009

    • Author(s)
      T. Yamase, H. Abe, Eri Ishikawa, H. Nojiri, Y. Ohshima
    • Journal Title

      Inorg. Chem 48

      Pages: 138-148

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Inorganic-Organic Hybrid Layered Crystal Composed of Polyoxomolybdates and Surfactant with p-Electrons2009

    • Author(s)
      T. Ito, T. Yamase
    • Journal Title

      Chem. Lett. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Chapter 243 : Luminescence of Polyoxometallolanthanoates and Photochemical Nano-ring Formation2009

    • Author(s)
      T. Yamase
    • Journal Title

      Handbook of the Physics and Chemistry of Rare Earths., K. A. Gschneidner, Jr., J.-C. G. Bunzli, and V. K. Pecharsky (Eds. ), Elsevier B. V. Vol. 39

      Pages: 297-356

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Structure and Magnetism of [n-BuNH_3]_<12>[Cu_4(GeW_9O_<34>)_2]・14H_2O Sandwiching a Rhomb-like Cu_4^<8+> Tetragon through α-Keggin Linkage2009

    • Author(s)
      T. Yamase, H. Ebe, Eri Ishikawa, H. Nojiri, and Y. Ohshima
    • Journal Title

      Irong. Chem. 48

      Pages: 138-148

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inorganic-Organic Hybrid Layered Crystal Composed of Polyoxomolybdates and Surfactant with π-Electrons2009

    • Author(s)
      T. Ito and T. Yamase
    • Journal Title

      Chem. Lett. 19(in press)

    • NAID

      10025121101

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anti-tumoral effect of polyoxomolybdates : induction of apoptotic cell death and autophagy in in vitro and in vivo models2008

    • Author(s)
      Aya Ogata, Hironobu Yanagie, Eri Ishikawa, Yasuyuki Morishita, Sayaka Mitsui, Atsushi Yamashita, Kenichiro Hasumi, Shinichi, Takamoto, Toshihiro Yamase, Masazumi Eriguchi
    • Journal Title

      Bn. J. Cancer 98

      Pages: 399-409

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 1/3 Magnetization Anormaly in Triangular Spin Prism2008

    • Author(s)
      Y Ohshima, H. Nojiri, K. Fukaya, T. Yamase
    • Journal Title

      J. Phys. Soc. Jpn. 77

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Photoreductive Self-assembly of[Mo^<VI>_7O_<24>]^<6-> to Anti-tumor al, [H_2Mo^V_<12>O_<28>(0H)_<12>(M0^<VI>O_3)_4]^<6-> in Aqueous Media2008

    • Author(s)
      T. Yamase, E. Ishikawa
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 983-991

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Anti-tumoral effect of polyoxomolybdates : induction of apoptotic cell death and autophagy in in vitro and in vivo models2008

    • Author(s)
      Aya Ogata, Hironobu Yanagie, Eri Ishikawa, Yasuyuki Morishita, Sayaka Mitsui, Atsushi Yamashita, Kenichiro Hasumi, Shinichi, Takamoto, Toshihiro Yamase, Masazumi Eriguchi
    • Journal Title

      Bri. J. Cancer 98

      Pages: 399-409

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 1/3 Magnetization Anormaly in Triangular Snin Prism2008

    • Author(s)
      Y. Ohshima, H. Nojiri, K. Fukaya, T. Yamase
    • Journal Title

      J. Phys. Soc. Jpn 77

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Photoreductive self-assembly of [Mo^<VI>_7O_<24>]^<6-> to Anti-tumor al, [H_2Mo^V_<12>O_28(OH)_<12>(Mo^<VI>O_3)_4]^<6-> in Aqueous Media2008

    • Author(s)
      T. Yamase, E. lshikawa
    • Journal Title

      Bull. Chem. Soc. Jpn 81

      Pages: 983-991

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Anti-tumoral effect of polyoxomolybdates : induction of apoptotic cell death and autophagy in in vitro and in vivo models2008

    • Author(s)
      Aya Ogata, Hironobu Yanagie, Eri Ishikawa, Yasuyuki Morishita, Sayaka Mitsui, Atsushi Yamashita, Kenichiro Hasumi, Shinichi, Takamoto, Toshihiro Yamase, and Masazumi Eriguchi
    • Journal Title

      Bri. J. Cancer 98

      Pages: 399-409

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 1/3 Magnetization Anormaly in Triangular Spin Prism2008

    • Author(s)
      Y. Ohshima, H. Nojiri, K. Fukaya, and T. Yamase
    • Journal Title

      J. Phys. Soc. Jpn. 77

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoreductive Self-assembly of [Mo^<VI>_7O_<24>]^<6-> to Anti-tumor al, [H_2MO^V_<12>O_<28>(OH)_<12>(Mo^<VI>O_3)_4]^<6-> in Aqueous Media2008

    • Author(s)
      T. Yamase and E. Ishikawa
    • Journal Title

      Bull. Chem. Soc. Jpn. 81

      Pages: 983-991

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure of double Keggin-TiAV-mixed polyanion, [(A-β-GeTi_3W_9O_<37>)_2O_3]^<14-> and multielectron-transfer-based photocatalytic H_2-generation2007

    • Author(s)
      T. Yamase, X. Cao, S. Yazaki
    • Journal Title

      J. Mol. Catal, A 262

      Pages: 119-127

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] V-shaped Polyoxotungstoarsenates Incorporating a Prism-like Hexa Transition-Metals Center : [M_6(H_2O)_2(AsW_9O_<34>)_2(AsW_6O_<26>)]^<17->(M^<2+>=Mn^<2+>, Co^<2+>, Zn^<2+>)2007

    • Author(s)
      K. Fukaya, T. Yamase
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 178-182

    • NAID

      10018708646

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Enhancement effect of polyoxometalates on NGF-induced neurite-outgrowth for PC-12 cells2007

    • Author(s)
      M. Oda, M. Inoue, K. Hino, Y. Nakamura, T. Yamase
    • Journal Title

      Biol. Pharm. Bull. 30

      Pages: 787-790

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Langmuir-Blodgett Films of a Mo-blue Nanoring [Mo_<142>O_<429>H_<10>(H_2O)_<49>(CH_3CO_2)_5(CH_3CH_2CO_2)]^<30-> (Mo_<142>)by the Semiamphiphilic Method2007

    • Author(s)
      M. Clemente-Leon, T. Itoh, E. Coronado, T. Yamase
    • Journal Title

      Langmuir 23

      Pages: 4042-4047

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Array of Polyoxomolybdate Nanoball Constructed by Langmuir-Blodgett Semiamphiphilic Method2007

    • Author(s)
      M. Clemente-Leon, T. Itoh, H. Yashiro, T. Yamase
    • Journal Title

      Chem. Mater. 19

      Pages: 2589-2594

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structure of double Keggin-Ti/W-mixed polyanion, [ (A-β-GeTi_3W_9O_<37>_2O_3] ^<14->and multielectron-transfer-based photocatalytic H_2-generation2007

    • Author(s)
      T. Yamase, X. Cao, S. Yazaki
    • Journal Title

      J. Mol. Catal., A 262

      Pages: 119-127

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] V-shaped Polyoxotungstoarsenates Incorporating a Prism-like Hexa Transition-Metals Center : [M_6(H_ 2O)_2(AsW_9O_<34>_2(AsW_60_<26>]^<17->(M^<2+> = Mn^<2+>, Co^<2+>,Zn^<2+>)2007

    • Author(s)
      K. Fukaya, T. Yamase
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 178-182

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Langmuir-Blodgett Films of a Mo-blue Nanoring [Mo_<142>O_<429>H_<10>(H_2O)_<49>(CH_3CO_2)_5(CH_3CH_2CO_2)]^<30-> (Mo_<142>) by the Semiamphiphilic Method2007

    • Author(s)
      M. Clemente-Leon, T. Itoh, E. Coronado, T. Yamase
    • Journal Title

      Langmuir 23

      Pages: 4042-4047

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Two-Dimensional Array of Polyoxomolybdate Nanoball Constructed by Langmuir-Blodgett Semiamphiphilic Method2007

    • Author(s)
      M. Clemente-Leon, T. Itoh, H. Yashiro, T. Yamase
    • Journal Title

      Chem. Mater 19

      Pages: 2589-2594

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] ナノリング金属酸化物クラスター(ポリ酸)の分子磁性と分子設計2007

    • Author(s)
      山瀬利博
    • Journal Title

      固体物理、3月

      Pages: 45-54

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] V-shaped Polyoxotungstoarsenates Incorporating a Prism-like Hexa Transition-Metals Center : [M_6(H_2O)_2(AsW_9O_<34>)_2(AsW_6O_<26>)]^<17-> (M^<2+>=Mn^<2+>, Co^<2+>, Zn^<2+>)2007

    • Author(s)
      K. Fukuya and T. Yamase
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 178-182

    • NAID

      10018708646

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement effect of polyxometalates on NGF-induced neurite-outgrowth for PC-12 cells2007

    • Author(s)
      M. Oda, M. Inoue, K. Hino, Y. Nakamura, and T. Yamase
    • Journal Title

      Biol. Pharm. Bull. 30

      Pages: 787-790

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] langmuir-Blodgett Films of a Mo-blue Nanoring [Mo_<142>O_<429>H_<10>(H2O)_<49>(CH_3CO_2)_5(CH_3CH_2CO_2)]^<30-> (Mo_<142>) by the Semiamphiphilic Method2007

    • Author(s)
      M. Clemente-Leon, T. Ito, E. Coronado, and T. Yamase
    • Journal Title

      Langmuir 23

      Pages: 4042-4047

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Array of Polyoxomolybdate Nanoball Constructed by Langmuir-Blodgett Semiamphiphilic Method2007

    • Author(s)
      M. Clemente-Leon, T. Ito, H. Yashiro, and T. Yamase
    • Journal Title

      Chem. Mater 19

      Pages: 2589-2594

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced Self-Assembly to Lanthanide-Containing Molybdenum-Blue Superclusters and Molecular Design2006

    • Author(s)
      Toshihiro Yamase, Eri Ishikawa, Yohko Abe, Yutaka Yano
    • Journal Title

      J. Alloys & Compounds 404

      Pages: 693-700

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Molecular Luminescence spectroscopy of decatungstoeuropate Langumuir-Blodhett monolayers2006

    • Author(s)
      Takeru Itoh, Toshihiro Yamase
    • Journal Title

      J. Alloys & Compounds 404

      Pages: 813-815

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structures and Photoluminescence of Another Crown-typed Polyoxotungstoeuropate[H_2O⊂{Eu(H_2O)_4}_2{Eu(H_2O)_2(AsW_9O_<33>)}_4]^<x->in the Presence of Na^+ or Ca^<2+>2006

    • Author(s)
      Keisuke Fukaya, Toshihiro Yamase
    • Journal Title

      J. Alloys &Compounds 404

      Pages: 915-920

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] ^<31>P-nmr and Isothermal Titration Calorimetry Studies on Polyoxomolybdates-catalyzed Hydrolysis of ATP2006

    • Author(s)
      E. Ishikawa, T. Yamase
    • Journal Title

      J. Inorg. Biochem. 100

      Pages: 344-350

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Enhancement of antibacterial activity of β-lactam antibiotics by[P_2W_<18>O_<62>]^<6->, [SiMo_<12>O<40>]^<4->, and [PTi_2W_<10>O_<40>]^<7-> against mechicillin-resistant and vancomycin-resistant Staphylococcus aureus2006

    • Author(s)
      Miyao Inoue, Tomoko Suzuki, Yutaka Fujita, Mayumi Oda, Nobuhiro Matsumoto, Toshihiro Yamase
    • Journal Title

      J Inorg. Biochem. 100

      Pages: 1225-1233

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Regular Two-Dimensional Molecular Array of Photoluminescent Anderson-type Polyoxometalate Constructed by Langmuir-Blodgett Technique2006

    • Author(s)
      T. Itoh, H. Yashiro, T. Yamase
    • Journal Title

      Langmuir 22

      Pages: 2806-2810

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Photoluminescence Behavior of Langmuir-Blodgett Monolayers and Multilayers Composed of Decatungstoeuropate2006

    • Author(s)
      T. Itoh, H. Yashiro, T∧Yamase
    • Journal Title

      J. Cluster Sci. 17

      Pages: 375-387

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Prevention of the interaction between HVEM, herpes virus entrymediator, and gD, HSV envelope protein. by α-Keggin polyoxotungstate, PM-192006

    • Author(s)
      Katsuaki Dan, Toshihiro Yamase
    • Journal Title

      Biomedicine & Pharmacothrapy 60

      Pages: 169-173

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Anti-RNA virus activity of polyoxometalates2006

    • Author(s)
      Shiroh Shigeta, Shuichi Mori, Toshihiro Yamase ' Norio Yamamoto, Naoki Yamamoto
    • Journal Title

      Biomedicine & Pharmacothrapy 60

      Pages: 211-219

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Synergistic effect of polyoxometalates in combination with oxacillinagainst mechicillin-resistant and vancomycin-resistant Staphylococcusaureus : a high initial inoculum of 1 x 10^8 cfu/ml for in vivo test2006

    • Author(s)
      Miyao Inoue, Tomoko Suzuki, Yutaka Fujita, Jim Iijima, Mayumi Oda, Nobuhiro Matsumoto, Toshihiro Yamase
    • Journal Title

      Biomedicine & Pharmacothrapy 60

      Pages: 220-226

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Antitumor activity of polyoxomolybdate, [NH_3Pr^<1>]_6[Mo_7O_24]3H_2Oagainst human gastric cancer model2006

    • Author(s)
      S. Mitsui, A. Ogata, H. Yanagie, H. Kasano, T. Hisa, T. Yamase, M. Eriguchi
    • Journal Title

      Biomedicine & Pharmacothrapy 60

      Pages: 353-358

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Exchange Interactions for Cu_6^<12+>- and Mn_6^<12+>-Hexagons Sandwiched by Two B-α[XW_9O_<33>]^<9->(X=As^<III> and Sb^<III> ) Ligands in D_<3d>-Symmetric Polyoxotungstates2006

    • Author(s)
      T. Yamase, K. Fukaya, H. Nojiri, Y Ohshima
    • Journal Title

      Inorg. Chem. 45

      Pages: 7698-7704

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Magnetic properties of the ferromagnetic ring-shaped single-molecule magnet Cu_62006

    • Author(s)
      Y Ohshima, H. Nojiri, K. Fukaya, T. Ymnase
    • Journal Title

      J. Phys., Conference Series 51

      Pages: 195-198

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structures and Photolumine scence of Another Crown-typed Polyoxotungstoeuropate [H_2O⊂{Eu(H_2O)_4} _2 {Eu(H_2O)_2 (AsW_9O_<33>)}_4] <x->in the Presence of Na^+or Ca^<2+>2006

    • Author(s)
      Keisuke Fukaya, Toshihiro Yamase
    • Journal Title

      J. Alloys & Compounds 404

      Pages: 915-920

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] ^<31>P-nmr and Isothermal Titratio n Calorimetry Studies on Polyoxomolybdates-catalyzed Hydrolysis of ATP2006

    • Author(s)
      E. Ishikawa, T. Yamase
    • Journal Title

      J. Inorg. Biochem. 100

      Pages: 344-350

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Enhancement of antibacterial activity of β-lactam antibiotics by[P_2W_<18>O_<62>] ^<6->, [SiMo_<12>O_<40>] ^<4->, and [PTi_2W_<10>O_<40>]^<7-> against mechicillin-resistant and vancomycin-resistant Staphylococcus aureus2006

    • Author(s)
      Miyao Inoue, Tomoko Suzuki, Yutaka Fujita, Mayumi Oda, Nobuhiro Matsumoto, Toshihiro Yamase
    • Journal Title

      J. Inorg. Biochem 100

      Pages: 1225-123

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Two-Dimensional Photoluminescence Behavior of Langmuir-Blodgett Monolayers and Multilayers Composed of Decatungstoeuropate2006

    • Author(s)
      T. Itoh, H. Yashiro, T. Yamase
    • Journal Title

      J. Cluster Sci. 17

      Pages: 375-387

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Prevention of the interaction between HVEM, herpes virus entry mediator, and gD, HSV envelope protein, by a Keggin polyoxotungstate, PM-192006

    • Author(s)
      Katsuaki Dan, Toshihiro Yamase
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 169-173

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Anti-RNA virus activity of polyoxometalates2006

    • Author(s)
      Shiroh Shigeta, Shuichi Mori, Toshihiro Yamase, Norio Yamamoto, Naoki Yamamoto
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 211-219

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Synergistic effect of polyoxometalates in combination with oxacillin against mechicillin-resistant and vancomycin-resistant Staphylococcus aureus : a high initial inoculum of 1 x 10^8 cfu/ml for in vivo test2006

    • Author(s)
      Miyao Inoue, Tomoko Suzuki, Yutaka Fujita, Jun Iijima, Mayumi Oda, Nobuhiro Matsumoto, Toshihiro Yamase
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 220-226

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Antitumor activity of polyoxomolybdate, [NH_3Pr^i]_6 [Mo_7O_<24>] ・ 3H_2O against human gastric cancer model2006

    • Author(s)
      S. Mitsui, A. Ogata, H. Yanagie, H. Kasano, T. Hisa, T. Yamase, M. Eriguchi
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 353-358

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Ferromagnetic Exchange Interactions for Cu_6^<12+>-and Mn_6^<12+>-Hexagons Sandwiched by Two B-α [XW_9O_<33>]^<9->(X=As^<III> and Sb^<III>) Ligands in D_<3d->Symmetric Polyoxotungstates2006

    • Author(s)
      T. Yamase, K. Fukaya, H. Nojiri, Y. Ohshima
    • Journal Title

      Inorg. Chem 45

      Pages: 7698-7704

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Magnetic properties of the ferromagnetic ring-shaped single-molecule magnet Cu_62006

    • Author(s)
      Y. Ohshima, H. Nojiri, K. Fukaya, T. Yamase
    • Journal Title

      J. Phys., Conference Series 51

      Pages: 195-198

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 球、リングおよび関連構造のスーパーポリ酸の分子設計と興味深い物性2006

    • Author(s)
      山瀬利博
    • Journal Title

      現代化学 1月

      Pages: 42-49

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 希土類ポリ酸 : 蛍光体の分子モデルからスーパーナノリングクラスターヘの展開2006

    • Author(s)
      山瀬利博
    • Journal Title

      マテリアルインテグレーション、19、47-54 (2006) 19

      Pages: 47-54

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Anticancer activity of polyoxomolybdate2006

    • Author(s)
      H. Yanagie, A. Ogata, S. Mitsui, T. Hisa, T. Yamase, M. Eriguchi
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 349-352

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 31P-nmr and Isothermal Titration Calorimetry Studies on Polyoxomolybdates-catalyzed Hydroysis of ATP2006

    • Author(s)
      E. Ishikawa and T. Yamase
    • Journal Title

      J. Inorg. Biochem. 100

      Pages: 344-350

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Enhancement of Antibacterial Activity of β-lactam antibiotics by [P_2W_<18>O_<26>]^<6->,[SiMo_<12>O_<40>]^<4->, and [PTi_2W_<10>O_<40>]^<7->against methicillin-resistant and Vancomycin-resistant Staphylococcus Aureus2006

    • Author(s)
      M. Inoue, T. Suzuki, Y. Fujita, M. Oda, N. Matsumoto, and T. Yamase
    • Journal Title

      J. Inorg. Biochem. 100

      Pages: 1225-1233

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Regular Two-Dimensional Molecular Array of Photoluminescent Anderson-type Polyoxometalate Constructed by Langmuir-Blodgett Technique2006

    • Author(s)
      T. Ito, H. Yashiro, and T. Yamase
    • Journal Title

      Langmuir 22

      Pages: 2806-2810

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Two-Dimensional Photoluminescence Behavior of Langmuir-Blodgett Monolayers and Multilayers Composed of Decatungstoeuropate2006

    • Author(s)
      T. Itoh, H. Yashiro, and T. Yamase
    • Journal Title

      J. Cluster Sci. 17

      Pages: 375-387

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Prevention of the interaction between HVEM, herpes virus entry mediator, and gD, HSV envelope protein, by a Keggin polyoxotungstate, PM-192006

    • Author(s)
      Katsuaki Dan and Toshihiro Yamase
    • Journal Title

      Biomedecine & Pharmacotherapy 60

      Pages: 169-173

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synergistic Effect of Polyoxometalates in Combination with Oxacillin against Methicillin-resistant and Vancomycin-resistant Staphylococcus Aureus: a High Initial Inoculum of 1X10cuf/ml for in Vivo Test2006

    • Author(s)
      M. Inoue, T. Suzuki, Y. Fujita, M. Oda, N. Matsumoto, J. Iijima, and T. Yamase
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 220-226

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ferromagnetic Exchange Interactions for Cu_6^<12+> and Mn_6^<12+> Hexagons Sandwiched by Two B-a[XW_9O_<33>]^<9->(X=As^<III> and Sb^<III>)Ligands in D_<3d>-Symmetric Polyoxotungstates2006

    • Author(s)
      T. Yamase, K. Fukaya, H. Nojiri, and Y. Ohshima
    • Journal Title

      Inorg. Chem. 45

      Pages: 7698-7704

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Shucture of Ddouble Keggin-Ti/W-mixed Polyanion,[(A-β-GeTi_3W_9O_<37>)_2O_3]^<14-> and Multielectron-transfer-based Photocatalytic H_2-generation2006

    • Author(s)
      T. Yamase, X. Cao, and S. Yazaki
    • Journal Title

      J. Mol. Catal., A 262

      Pages: 119-127

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photoinduced Self-Assembly to Lanthanide-Containing Molybdenum Blue Superclusters and Molecular Design2006

    • Author(s)
      Toshihiro Yamase, Eri Ishikawa, Yohko Abe, Yutaka Yano
    • Journal Title

      J.Alloys & Compounds 208-412

      Pages: 693-700

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Molecular Luminescence spectroscopy of decatunstoeuropate Langumuir-Blodhett monolayerss2006

    • Author(s)
      Takeru Itoh, Toshihiro Yamase
    • Journal Title

      J.Alloys & Compounds 208-412

      Pages: 813-815

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structures and Photoluminescence of Another Crown-typed Polyoxotungstoeuropate [H_2O⊂{Eu(H_2O)_4}_2{Eu(H_2O)_2(AsW_9O_<33>)}_4]^<x-> in the Presence of Na^+ or Ca^<2+>2006

    • Author(s)
      Keisuke Fukaya, Toshihiro Yamase
    • Journal Title

      J.Alloys & Compounds 208-412

      Pages: 915-920

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Green/Yellowish-White Color-tunable Up-conversion Phosphor Prepared from Er/Yb-Polyoxoaluminoniobate Complex2005

    • Author(s)
      H. Naruke, T. Yamase
    • Journal Title

      J. Alloys &Compounds 391

      Pages: 302-306

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] The crystal structure of the monohydrate R_2Mo_6O_21・H_2O(R=Pr, Nd, Sm, and Eu) : a layer structure containing disordered[Mo_2O_7]^<2->groups2005

    • Author(s)
      H. Naruke, T. Yamase
    • Journal Title

      J. Solid State Chem. 178

      Pages: 702-708

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] A Novel Anti-tumor Agent, Polyoxomolybdate Induces Apoptotic Cell Death in AsPC-1 Human Pancreatic Cancer Cells '・ '2005

    • Author(s)
      Aya Ogata, Sayaka Mitsui, Hironobu Yanagie, Hiroyuki Kasano, Tomoyuki Hisa, Toshihiro Yamase, Masazumi Eriguchi
    • Journal Title

      Biomedicine & Pharmacotherapy 59

      Pages: 240-244

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Antimicrobial Activity of Highly Negative Charged Polyoxotungstates, K_27【KAs_4W_<44>O_<140>] and K_18【KSb_9W_<21>O_<86>], and Keggin-structural Polyoxotungstates Against Hellicobacter pylori2005

    • Author(s)
      Miyao Inoue, Keiko Segawa, Sahe. Matsunaga, Nobuhiro Matsumoto, Mayumi Oda, Toshihiro Yamase
    • Journal Title

      J. Inorg. Biochem. 99

      Pages: 1023-1031

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Photoreductive Self-assembly from [Mo_7O_<24>]^<6・> to Carboxylates-Coordinatined {M0_<142>} Mo-Blue Nano-ring in the Presence of Carboxylic Acids2005

    • Author(s)
      T. Yamase, Y. Yano, E. Ishikawa
    • Journal Title

      Langmuir 21

      Pages: 7823-7832

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Anti-tumor, Antiviral, and Antibacterial Activities of Polyoxometalatesfor Realizing an Inorganic Drug2005

    • Author(s)
      T. Yamase
    • Journal Title

      J. Mater. Chem. 15

      Pages: 4773-4782

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Effect of Spin Chirality on Magnetization in Triangular Rings2005

    • Author(s)
      H. Nojiri, E. Ishikawa, T. Yamase
    • Journal Title

      Theor. Phys. Suppl. 159

      Pages: 292-296

    • NAID

      210000128059

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Green/Yellowish-White Color-tunable Up-conversion Phosphor Prepared from Er/Yb-Polyoxoaluminoniobate Complex2005

    • Author(s)
      H. Naruke, T. Yamase
    • Journal Title

      J. Alloys & Compounds 391

      Pages: 302-306

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] The crystal structure of the monohydrate R_2Mo_6O_<21> ・ H_2O(R=Pr, Nd, Sm, and Eu) : a layer structure containing disordered [Mo_2O_7]^<2->groups2005

    • Author(s)
      H. Naruke, T. Yamase
    • Journal Title

      J. Solid State Chem 178

      Pages: 702-708

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] A Novel Anti-tumor Agent, Polyoxomolybdate Induces Apoptotic Cell Death in AsPC-1 Human Pancreatic Cancer Cells2005

    • Author(s)
      Aya Ogata, Sayaka Mitsui, Hironobu Yanagie, Hiroyuki Kasano, Tomoyuki Hisa, Toshihiro Yamase, Masazumi Eriguchi
    • Journal Title

      Biomedicine & Pharmacotherapy 59

      Pages: 240-244

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Antimicrobial Activity of Highly Negative Charged Polyoxotungstates, K_<27>[KAs_4W_<44>O_<140>] and K_<18>[KSb_9W_<21>O_<86>], and Keggin-structural Polyoxotungstates Against Hellicobacter pylori2005

    • Author(s)
      Miyao Inoue, Keiko Segawa, Sahe Matsunaga, Nobuhiro Matsumoto, Mayumi Oda, Toshihiro Yamase
    • Journal Title

      J. Inorg. Biochem. 99

      Pages: 1023-1031

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Photoreductive Self-assembly from[Mo_7O_<24>] <6-> to Carboxylates-Coordinatined {Mo_<142>} Mo-Blue Nano-ring in the Presence of Carboxylic Acids2005

    • Author(s)
      T. Yamase, Y. Yano, E. Ishikawa
    • Journal Title

      Langmuir 21

      Pages: 7823-7832

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Anti-tumor, Antiviral, and Antibacterial Activities of Polyoxometalates for Realizing an Inorganic Drug2005

    • Author(s)
      T. Yamase
    • Journal Title

      J. Mater. Chem. 15

      Pages: 4773-4782

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Effect of Spin Chirality on Magnetization in Triangular Rings2005

    • Author(s)
      H. Nojiri, E. Ishikawa, T. Yamase
    • Journal Title

      Prog. Theor. Phys. Suppl. 159

      Pages: 292-296

    • NAID

      210000128059

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Current status of anti-SARS agents2005

    • Author(s)
      S. Shigeta, T. Yamase
    • Journal Title

      Antiviral Chem. & Chemotherapy 16

      Pages: 23-32

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] The crystal structure of the monohydrate R_2Mo_6O_<21>・H_2O (R=Pr, Nd, Sm, and Eu) : a layer structure containing disordered [Mo_2O_7]^<2-> groups2005

    • Author(s)
      H.Naruke, T.Yamase
    • Journal Title

      J.Solid State Chem. 178

      Pages: 702-708

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A Novel Anti-tumor Agent, Polyoxomolybdate Induces Apoptotic Cell Death in AsPC-1 Human Pancreatic Cancer Cells2005

    • Author(s)
      A.Ogata, S.Mitsui, H.Yanagie, H.Kasano, T.Hisa, T.Yamase, M.Eriguchi
    • Journal Title

      Biomedicine & Pharmacotherapy 59

      Pages: 240-244

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Antimicrobial Activity of Highly Negative Charged Polyoxotungstates, K_<27>[KAs_4W_<44>O_<140>] and K_<18>[KSb_9W_<21>O_<86>], and Keggin-structural Polyoxotungstates Against Hellicobacter pylori2005

    • Author(s)
      M.Inoue, K.Segawa, S.Matsunaga, N.Matsumoto, M.Oda, T.Yamase
    • Journal Title

      J.Inorg.Biochem. 99

      Pages: 1023-1031

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Current Status of Anti-SARS Agents2005

    • Author(s)
      S.Shigeta, T.Yamase
    • Journal Title

      Antiviral Che.& Chemother 16

      Pages: 23-32

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Photoreductive Self-Assembly from [Mo_7O_<24>]^<6-> to Carboxylates-Coordinated {Mo_<42>} Mo-Blue Nanoring in the Presence of Carboxylic Acids2005

    • Author(s)
      Toshihiro Yamase, Yutaka Yano, Eri Ishikawa
    • Journal Title

      Langmuir 21

      Pages: 7823-7832

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Anti-tumor, -viral, and -bacterial activities of polyoxometalates for realizing an inorganic drug2005

    • Author(s)
      T.Yamase
    • Journal Title

      J.Mater.Chem. 15

      Pages: 4772-4782

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Antitumor activity of polyoxomolybdate, [NH_3Pr^i]_6[Mo_7O_<24>]・3H_2O. against human gastric cancer model

    • Author(s)
      S. Mitusi, A. Ogata, H. Yanagie, H. Kasano, T. Hisa, T. Yamase and M. Eriguchi
    • Journal Title

      Biomedicine & Pharmacotherapy 60

      Pages: 353-358

    • Related Report
      2006 Annual Research Report
  • [Presentation] 環状モリブデン酸塩の導電性に及ぼす雰囲気の影響2009

    • Author(s)
      斧谷宏明・成毛治朗・山瀬利博
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 希土類タングテン酸の合成法とアップコンバージョン青色発光2008

    • Author(s)
      成毛治朗・山瀬利博
    • Organizer
      第25回希土類討論会
    • Place of Presentation
      タワーホール船堀{東京}
    • Year and Date
      2008-05-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヌクレオチドが配位したポリモリブデン酸イオン[Mo_4O_<15>(GMP)_2]^4と[{Mo_<14>O_<43>(CMP)_4)}_2]^<22->の構造2008

    • Author(s)
      石川英里・山口晶・山瀬利博
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Co_4^<8+>菱形クラスターをサンドイッチしたα-β接合構造の新規ポリ酸[Co_4(H_2O)_2(PW_9O_<34>)_2]^<10->の構造と磁気的性質2008

    • Author(s)
      阿部紘子・山瀬利博
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] ボール状構造ポリ酸{Mo_<132>}の生成過程と有機化合物との特異的な相互作用に関する研究2008

    • Author(s)
      熊谷峻・山瀬利博
    • Organizer
      234^<th> American Chemical Society (ACS) National Meeting
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] エレクトロスプレーイオン化質量分析法によるナノリングポリ酸の光還元生成過程の検討2008

    • Author(s)
      伊藤建・山瀬利博
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] La^<3+>を含むMoブルーナノリングの光合成・モノマーとポリマー鎖2008

    • Author(s)
      山瀬利博・Prokop Petra Viviane
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 28電子還元されたナノリングMoブルー固体の近赤外域での光伝導性2008

    • Author(s)
      江原晶子・山瀬利博
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synergistic effect of polyoxometalates in combination with □-lactam antibiotics against MRSA or VRSA2008

    • Author(s)
      T. Yamase
    • Organizer
      Zing Conference, in Coordination Chemistry in Supramolecular Compounds and Materials
    • Place of Presentation
      Cancun, Mexico
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Photoinduced self-assembly to tube, chain, and other aggregate of molybdenum-blue nano-rings2008

    • Author(s)
      T. Yamase, P. Prokop, M. Iwatani, E. Ishikawa
    • Organizer
      XXI Congress of the International Union of Crystallography (IUCr2008)
    • Place of Presentation
      Osaka, Japan
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Synergistic effect of polyoxometalates in combination with β-lactam antibiotics against MRSA or VRSA2008

    • Author(s)
      T. Yamase
    • Organizer
      Zing Conference, in Coordination Chemistry in Supramolecular Compounds and Materials
    • Place of Presentation
      Cancun, Mexico.(invited lecture)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Synergistic effect of polyxometalates in combination with □-lactam antibiotics against MRSA or VRSA2008

    • Author(s)
      T. Yamase
    • Organizer
      Zing Conference, in Coordination Chemistry in Supramolecular Compounds and Materials
    • Place of Presentation
      Cancun, Mexico
    • Related Report
      2007 Annual Research Report
  • [Presentation] ^<139>La NMRとカロリーメトリによる欠損タイプ{Mo_<142>}MoブルーナノリングのLa^<3+>イオン取り込み反応に関する研究2007

    • Author(s)
      石川英里・山瀬利博
    • Organizer
      第24回希土類討論会
    • Place of Presentation
      九州大学医学部百年講堂(福岡)
    • Year and Date
      2007-05-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] Antitumor activity and photoconductivity of photochemically-induced 12- and 28-electron reduced aggregates derived from [M07O_<24>]^<6->2007

    • Author(s)
      T. Yamase
    • Organizer
      234^<th> American Chemical Society (ACS)National Meeting
    • Place of Presentation
      Boston, MA, U. S. A.
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Microcalorimetric investigation on formation. of the ellipsoidal Mo-blue ring coordinated by La^<3+> cations2007

    • Author(s)
      E. Ishikawa, T. Yamase
    • Organizer
      234^<th> American Chemical Society (ACS)National Meeting
    • Place of Presentation
      Boston, MA, U. S. A.
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Wide range (400-2300 nm)light-sensitive nano-ring Mo-blues as a novel photoconductor2007

    • Author(s)
      T. Yamase
    • Organizer
      5^<th> National Symposium and Conference on Solid State Chemistry and Applied Areas, ISCAS-2007
    • Place of Presentation
      Nagpur, India
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Antitumor activity and photoconductivity of photochemically-induced 12- and 28-electron reduced aggregates derived from [Mo_7O_<24>]^<6->2007

    • Author(s)
      T. Yamase
    • Organizer
      234^<th> American Chemical Society (ACS) National Meeting
    • Place of Presentation
      Boston, MA., U. S. A.(invited lecture)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Microcalorimetric investigation on formation of the ellipsoidal Mo-blue ring coordinated by La^<3+> cations2007

    • Author(s)
      E. Ishikawa, T. Yamase
    • Organizer
      234^<th> American Chemical Society (ACS) National Meeting
    • Place of Presentation
      Boston,MA., U. S. A.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Wide range (400-2300 nm) light-sensitive nano-ring Mo-blues as a novel photoconductor2007

    • Author(s)
      T. Yamase
    • Organizer
      5^<th> National Symposium and Conference on Solid State Chemistry and Applied Areas, ISCAS-2007
    • Place of Presentation
      Nagpur, India(plenary lecture)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Antitumor activity and photoconductivity of photochemically-induced 12- and 28-electron reduced aggregates derived from [Mo_7O_<24>]^<6->2007

    • Author(s)
      T. Yamase
    • Organizer
      234^<th> American Chemical Society (ACS) National Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Related Report
      2007 Annual Research Report
  • [Presentation] Microcalorimetric investigation on formatoin of the ellipsoidal Mo-blue ring coordinated by La^<3+> cations2007

    • Author(s)
      E. Ishikawa and T. Yamase
    • Organizer
      234^<th> American Chemical Society (ACS) National Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Related Report
      2007 Annual Research Report
  • [Presentation] Wide range (400-2300 nm) light-sensitive nano-ring Mo-blues as a novel photoconductor2007

    • Author(s)
      T. Yamase
    • Organizer
      5^<th> National Symposium and Conference on Solid State Chemistry and Applied Areas, ISCAS-2007
    • Place of Presentation
      Nagpur, India
    • Related Report
      2007 Annual Research Report
  • [Presentation] Clinical Significance of Bio-activities of Polyoxometalates2005

    • Author(s)
      T. Yamase
    • Organizer
      Polyoxometalate Chemistry for Molecular Desig and Nano-engineering (#261), Pacifichem2005
    • Place of Presentation
      Honolulu, Hawaii, U. S. A.
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Structures and Photoluminescence of Polyoxotungstoeuropates nanoclusters2005

    • Author(s)
      K. Fukaya, T. Yamase
    • Organizer
      Transition Metal Oxide Based Advanced MateriaIs : Design and Synthesis, Characterization, and Applications (#243), Pacifichem2005
    • Place of Presentation
      Honolulu, Hawaii, U. S. A.
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Magnetic hysteresis of spin-triangle-. prism-, and hexagon-sandwiching polyoxotungstates and photo induced self-, assembly to lanthanide-containing Mo-blues2005

    • Author(s)
      T. Yamase
    • Organizer
      Electronic Structure of Polyoxometalates. Interplay between Experiment and Theory (ESP'05)at the European Center of Atomic and Molecular Calculation (CECAM)workshop
    • Place of Presentation
      Lyon, France
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Molecular Design of Lanthanide-containing Polyoxometalate Superclusters2005

    • Author(s)
      T. Yamase
    • Organizer
      New Aspect of Polyoxometalate Chemistry, 11^<th> Asian Chemical Congress
    • Place of Presentation
      Soul, Korea
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Structures and Photoluminescence of Polyoxotungstoeuropates nanoclusters (invited lecture, organizer)2005

    • Author(s)
      K. Fukaya, T. Yamase
    • Organizer
      Transition Metal Oxide Based Advanced Materials : Design and Synthesis, Characterization, and Applications (#243), Pacifichem2005
    • Place of Presentation
      Honolulu, Hawaii, U. S. A.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Clinical Significance of Bio-activities of Polyoxometalates (invited lecture, organizer)2005

    • Author(s)
      T. Yamase
    • Organizer
      Polyoxometalate Chemistry for Molecular Design and Nano-en gineering (#261), Pacifichem2005
    • Place of Presentation
      Honolulu, Hawaii, U. S. A.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Magnetic hysteresis of spin-triangle-, prism-, and h exagon-sandwiching polyoxotungstates and photoinduced self-assembly to lanthanide-containing Mo-blues (invited lecture)2005

    • Author(s)
      T. Yamase
    • Organizer
      Electronic Structure of Polyoxometalates. Interplay between Experiment and Theory (ESP'05) at the European Center of Atomic and Molecular Calculation (CECAM) workshop
    • Place of Presentation
      Lyon, France
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Molecular Design of Lanthanide-containing Polyoxometalate Superclusters2005

    • Author(s)
      T. Yamase
    • Organizer
      New Aspect of Polyoxometalate Chemistry, 11^<th> Asian Chemical Congress
    • Place of Presentation
      Soul, Korea(invited lecture)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] Handbook of the Physics and Chemistry of Rare Earths : Chapter 243 : Luminescence of Polyoxometallolanthanoates and Photochemical Nano-ring Formation2009

    • Author(s)
      T. Yamase
    • Total Pages
      60
    • Publisher
      Elsevier
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] Luminescence of Polyoxometallolanthanoates and Photochemical Nanoring Formation、Handbook of the Physics and Chemistry of Rare Earth., K. A. Gschneidner, Jr., J.-C.G. Bunzli, and V.K. Pecharsky (Eds.), Vol.39, chapter 2432009

    • Author(s)
      T. Yamase
    • Total Pages
      60
    • Publisher
      Elsevier B. V., Netherlands : North-Holland
    • Related Report
      2007 Annual Research Report
  • [Book] 「ナノリング金属酸化物クラスター(ポリ酸)の分子磁性と分子設計」固体物理、4 2巻、No. 4932007

    • Author(s)
      山瀬利博
    • Total Pages
      10
    • Publisher
      アグネ技術センター
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] ナノリング金属酸化物クラスター(ポリ酸)の分子磁性と分子設計」固体物理、3月45-542007

    • Author(s)
      山瀬利博
    • Total Pages
      10
    • Publisher
      アグネ技術センター
    • Related Report
      2007 Annual Research Report
  • [Book] 「球、リングおよび関連構造のスーパーポリ酸の分子設計と興味深い物性」現代化学、新年号。 No. 4182006

    • Author(s)
      山瀬利博
    • Total Pages
      8
    • Publisher
      東京化学同人
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 「希土類ポリ酸 : 蛍光体の分子モデルからスーパーナノリングクラスターヘの展開」マテジアルインテグレーション2006

    • Author(s)
      山瀬利博
    • Total Pages
      8
    • Publisher
      株式会社CSセンター -
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] “Anticancer activity of polyoxomolybdate", Biomedicine & Pharmacotherapy2006

    • Author(s)
      H. Yanagie, A. Ogata, S. Mitsui, T. Hisa, T. Yamase, M. Eriguchi
    • Total Pages
      4
    • Publisher
      Elsevier
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] Anticancer Activity of Polyoxomolybdate, Biomedicine & Pharmacotherapy, 602006

    • Author(s)
      H. Yanagie, A. Ogata, S. Mitsui, T. Hisa, T. Yamase, M Eriguchi
    • Total Pages
      3
    • Publisher
      Elsevier
    • Related Report
      2006 Annual Research Report
  • [Book] 球やリングの形をしたスーパーポリ酸の分子設計と興味深い物性 現代化学、1月 42-492006

    • Author(s)
      山瀬利博
    • Total Pages
      8
    • Publisher
      東京化学同人
    • Related Report
      2005 Annual Research Report
  • [Book] 希土類ポリ酸:蛍光体の分子モデルからスーパーナノリングクラスターへの展開、マテリアルインテグレーション192006

    • Author(s)
      山瀬利博
    • Total Pages
      8
    • Publisher
      TIC
    • Related Report
      2005 Annual Research Report
  • [Book] "Current status of anti-SARS agents", Antiviral Chem. & Chemotherapy2005

    • Author(s)
      S. Shigeta, T. Yamase
    • Total Pages
      10
    • Publisher
      International Medical Press
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 抗PRSP剤2008

    • Inventor(s)
      山瀬利博, 島安治
    • Industrial Property Rights Holder
      山瀬利博
    • Acquisition Date
      2008-06-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 抗PRSP剤2008

    • Inventor(s)
      山瀬利博、島安治
    • Industrial Property Rights Holder
      山瀬利博
    • Acquisition Date
      2008-06-20
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 養毛・育毛剤2006

    • Inventor(s)
      団 克昭, 山瀬利博
    • Industrial Property Rights Holder
      慶應大学, 東京工業大学
    • Industrial Property Number
      2006-011541
    • Filing Date
      2006-02-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 養毛・育毛剤2006

    • Inventor(s)
      団 克昭, 山瀬 利博
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2006-011541
    • Filing Date
      2006-02-01
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 抗VRSA剤2005

    • Inventor(s)
      山瀬利博
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2005-205986
    • Filing Date
      2005-07-14
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 抗後天性免疫不全症候群ウイルス剤2005

    • Inventor(s)
      山瀬利博, 奥田研爾, 松井清彦
    • Industrial Property Rights Holder
      東京工業大学, 横浜市立大学
    • Industrial Property Number
      2005-239877
    • Filing Date
      2005-08-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 神経様突起伸張促進剤2005

    • Inventor(s)
      山瀬利博
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2005-288448
    • Filing Date
      2005-09-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 神経様突起伸張促進剤2005

    • Inventor(s)
      山瀬 利博
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2005-288448
    • Filing Date
      2005-09-30
    • Related Report
      2005 Annual Research Report

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Published: 2005-04-01   Modified: 2018-03-28  

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