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Precision Controlled Radical Polymerization of Alkenes

Research Project

Project/Area Number 17065008
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionNagoya University

Principal Investigator

KAMIGAITO Masami  Nagoya University, 大学院・工学研究科, 教授 (00273475)

Co-Investigator(Renkei-kenkyūsha) SATOH Kotaro  名古屋大学, 大学院・工学研究科, 講師 (70377810)
NISHIYAMA Hisao  名古屋大学, 大学院・工学研究科, 教授 (40135421)
ITO Jun-ichi  名古屋大学, 大学院・工学研究科, 助教 (20402480)
OKAMOTO Yoshio  名古屋大学, 名誉教授 (60029501)
Project Period (FY) 2005 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥26,900,000 (Direct Cost: ¥26,900,000)
Fiscal Year 2008: ¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 2007: ¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 2006: ¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 2005: ¥3,800,000 (Direct Cost: ¥3,800,000)
Keywordsラジカル重合 / リビング重合 / 立体特異性重合 / アルケン / ラジカル付加 / 酸化還元 / 金属触媒 / 水素結合 / マンガン錯体 / 鉄触媒 / 位置特異性重合 / ステレオグラジェントポリマー / 連続還元 / 炭素-炭素結合形成 / 酸化反応
Research Abstract

本研究では、アルケンへの高選択的なラジカル付加反応を可能とする高度分子変換反応を構築し、ラジカル重合反応において分子量や立体構造が高度に制御された高分子の精密合成を行うことを目的とした。とくに、金属触媒などを用いたリビングラジカル重合と、水素結合などに基づく立体特異性ラジカル重合を組み合わせることで、生成ポリマーの分子量と立体構造の同時制御を検討した。さらに、触媒系を設計することで、実用化に適した力量あるリビングラジカル重合系の開発を行った。

Report

(5 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (98 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (36 results) (of which Peer Reviewed: 23 results) Presentation (54 results) Book (5 results) Remarks (3 results)

  • [Journal Article] Mn_2(C0)_<10>-Induced Controlled/Living Radical Copolymerization of Methyl Acrylate andl-Hexene in Fluoroalcohol : High α-Olefin Content Copolymers with Controlled Molecular Weights2009

    • Author(s)
      Kazuhiko Koumura
    • Journal Title

      Macromolecules 42(印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mn_2(C0)_<10>-Induced RAFT Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene2009

    • Author(s)
      Kazuhiko Koumura
    • Journal Title

      Polym. J. 41(印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity2009

    • Author(s)
      Harumi Murayama
    • Journal Title

      ACS Symp. Ser. (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 合成高分子の構造精密制御 : ラジカル重合の制御と精密高分子合成2009

    • Author(s)
      上垣外正己
    • Journal Title

      化学と工業 62

      Pages: 25-27

    • NAID

      10023990863

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity2009

    • Author(s)
      Harumi Murayama
    • Journal Title

      ACS Symp.Ser. (未定)(印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoregulation in Living Radical Polymerization2008

    • Author(s)
      M. Kamigaito, K. Satoh
    • Journal Title

      Macromolecules 41

      Pages: 269-272

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Regiospecific Radical Polymerization of Vinyl Methacrylate in the Presence of Lewis Acid into Soluble Polymers with Pendent Vinyl Ester Substituents2008

    • Author(s)
      Fumitaka Sugiyama
    • Journal Title

      Macromolecules 41

      Pages: 3042-3048

    • Related Report
      2008 Annual Research Report 2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Manganese-Based Controlled/Living Radical Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene : Highly Active, Versatile, and Photoresponsive Systems2008

    • Author(s)
      Kazuhiko Koumura
    • Journal Title

      Macromolecules 41

      Pages: 7359-7367

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron (III) Chloride/R-Cl/Tributylphosphine for Metal-Catalyzed Living Radical Polymerization : A Unique System with a Higher Oxidation State Iron Complex2008

    • Author(s)
      Kotaro Satoh
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem. 46

      Pages: 6358-6363

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mn_2(CO)_<10>-Induced Controlled/Living Radical Copolymerization of Vinyl Acetate and Methyl Acrylate : Spontaneous Formation of Block Copolymers Consisting of Gradient and Homopolymer Segments2008

    • Author(s)
      Kazuhiko Koumura
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem. 47

      Pages: 1343-1353

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ラジカル重合における精密制御-分子量、立体構造、モノマーの配列の制御2008

    • Author(s)
      上垣外正己
    • Journal Title

      有機合成化学協会誌 66

      Pages: 578-589

    • Related Report
      2008 Annual Research Report 2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] リビングラジカル重合の基礎と展開2008

    • Author(s)
      上垣外正己
    • Journal Title

      色材協会誌 81

      Pages: 459-470

    • NAID

      10024450610

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoregulation in Living Radical Polymerization2008

    • Author(s)
      Masami Kamigaito
    • Journal Title

      Macromolecules 41

      Pages: 269-276

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral (-)-DIOP Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions2007

    • Author(s)
      Y. Iizuka, Z. Li, K. Satoh, M. Kamigaito, Y. Okamoto, J.-i Ito, H. Nishiyama
    • Journal Title

      Eur. J. Org. Chem

      Pages: 782-791

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A_xBA_x-Type Block-Graft Polymers with Soft Methacrylate Middle Segments and Hard Styrene Outer Grafts : Synthesis, Morphology, and Mechanical Properties2007

    • Author(s)
      Yu Miura
    • Journal Title

      Chem.Asian J. 2

      Pages: 662-672

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral (-)-DIOP Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions2007

    • Author(s)
      Yusuke Iizuka
    • Journal Title

      Eur. J. Org. Chem. 5

      Pages: 782-791

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Stereogradient Polymers by Ruthenium-Catalyzed Stereospecific Living Radical Copolymerization of Two Monomers with Different Stereospecificities and Reactivities2006

    • Author(s)
      Y. Miura, T. Shibata, K. Satoh, M. Kamigaito, Y. Okamoto
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 16026-16027

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Triple Hydrogen Bonding for Stereospecific Radical Polymerization of a DAD Monomer and Simultaneous Control of Tacticity and Molecular Weight2006

    • Author(s)
      D. Wan, K. Satoh, M. Kamigaito
    • Journal Title

      Macromolecules 39

      Pages: 6882-6886

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Iodine Transfer Radical Polymerization of Vinyl Acetate in Fluoroalcohols for Simultaneous Control of Molecular Weight, Stereospecificity, and Regiospecificity2006

    • Author(s)
      K. Koumura, K. Satoh, M. Kamigaito, Y. Okamoto
    • Journal Title

      Macromolecules 39

      Pages: 4054-4061

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity2006

    • Author(s)
      M. Kamigaito, K. Satoh
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem. 44

      Pages: 6147-6158

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium-Catalyzed Living Radical Polymerization of Methyl and 2-Hydroxyethyl Methacrylates and Sequential Synthesis of Stereoblock Polymers2006

    • Author(s)
      T. Shibata, K. Satoh, M. Kamigaito, Y. Okamoto
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem. 44

      Pages: 3609-3615

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed Radical Polymerization of Acrylamides in the Presence of Lewis Acid for Simulatenous Control of Molecular Weight and Tacticity2006

    • Author(s)
      Y. Sugiyama, K. Satoh, M. Kamigaito, Y. Okamoto
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem. 44

      Pages: 2086-2098

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stereospecific Living Radical Polymerization2006

    • Author(s)
      M. Kamigaito, K. Satoh, D. Wan, K. Koumura, T. Shibata, Y. Okamoto
    • Journal Title

      ACS Symp. Ser, 944

      Pages: 26-39

    • NAID

      10017538048

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 立体特異性リビングラジカル重合2006

    • Author(s)
      上垣外正己、佐藤浩太郎
    • Journal Title

      高分子 55

      Pages: 250-253

    • NAID

      10017538048

    • Related Report
      2008 Final Research Report
  • [Journal Article] Stereogradient Polymers by Ruthenium-Catalyzed Stereospecific Living Radical Copolymerization of Two Monomers with Different Stereospecificities and Reactivities2006

    • Author(s)
      Yu Miura
    • Journal Title

      J. Am. Chem. Soc. 128・50

      Pages: 16026-16027

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Triple Hydrogen Bonding for Stereospecific Radical Polymerization of a DAD Monomer and Simultaneous Control of Tacticity and Molecular Weight2006

    • Author(s)
      Decheng Wan
    • Journal Title

      Macromolecules 39・20

      Pages: 6882-6886

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Iodine Transfer Radical Polymerization of Vinyl Acetate in Fluoroalcohols for Simultaneous Control of Molecular Weight, Stereospecificity, and Regiospecificity2006

    • Author(s)
      Kazuhiko Koumura
    • Journal Title

      Macromolecules 39・12

      Pages: 4054-4061

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity2006

    • Author(s)
      Masami Kamigaito
    • Journal Title

      J. Polym. Sci., Part A : Polym. Chem. 44・21

      Pages: 6147-6158

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Simultaneous Control of the Stereospecificity and Molecular Weight in the Ruthenium-Catalyzed Living Radical Polymerization of Methyl and 2-Hydroxyethyl Methacrylates and Sequential Synthesis of Stereoblock Polymers2006

    • Author(s)
      Takuya Shibata
    • Journal Title

      J. Polym. Sci., Part A : Polym. Chem. 44・11

      Pages: 3609-3615

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Iron-Catalyzed Radical Polymerization of Acrylamides in the Presence of Lewis Acid for Simultaneous Control of Molecular Weight and Tacticity2006

    • Author(s)
      Yuya Sugiyama
    • Journal Title

      J.Polym.Sci., Part A : Polym.Chem. 44・6

      Pages: 2086-2098

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Stereospecific Living Radical Polymerization2006

    • Author(s)
      Masami Kamigaito
    • Journal Title

      ACS Symposium Series (in press)

    • NAID

      10017538048

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 立体特異性リビングラジカル重合2006

    • Author(s)
      上垣外 正己
    • Journal Title

      高分子 55・4

      Pages: 250-253

    • NAID

      10017538048

    • Related Report
      2005 Annual Research Report
  • [Journal Article] キラルルテニウム錯体によるラジカル付加反応及びラジカル重合反応の制御2006

    • Author(s)
      飯塚 裕介
    • Journal Title

      高分子学会予稿集 55(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Xanthate-Mediated Radical Polymerization of N-Vinylpyrrolidone in Fluoroalcohols for Simultaneous Control of Molecular Weight and Tacticity2005

    • Author(s)
      D. Wan, K. Satoh, M. Kamigaito, Y. Okamoto
    • Journal Title

      Macromolecules 38

      Pages: 10397-10405

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Xanthate-Mediated Radical Polymerization of N-Vinylpyrrolidone in Fluoroalcohols for Simultaneous Control of Molecular Weight and Tacticity2005

    • Author(s)
      Decheng Wan
    • Journal Title

      Macromolecules 38・25

      Pages: 10397-10405

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity

    • Author(s)
      H. Murayama, K. Satoh, M. Kamigaito
    • Journal Title

      ACS Symp. Ser. (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Presentation] Metal-Catalyzed Living Radical Polymerization and Radical Polyaddition2009

    • Author(s)
      Masami Kamigaito
    • Organizer
      The 1 st G-COE International Symposium on Elucidation and Design of Materials and Molecular Functions
    • Place of Presentation
      名古屋大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] Manganese-Based Photoinduced Living Radical Polymerization of Vinyl Acetate and Methyl Acrylate2009

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      The 1 st G-COE International Symposium on Elucidation and Design of Materials and Molecular Functions
    • Place of Presentation
      名古屋大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] マンガン錯体を用いた酢酸ビニルとアクリル酸メチルのリビングラジカル共重合2009

    • Author(s)
      香村和彦
    • Organizer
      第2回物質化学フロンティアセミナー-ナノ物質科学の最前線 : 作る、見る、測る-
    • Place of Presentation
      名古屋大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高分子の合成〜精密重合における最近の展開2008

    • Author(s)
      上垣外正己
    • Organizer
      第16回東海高分子基礎研修コース
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2008-10-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 遷移金属錯体によるリビングラジカル重合2008

    • Author(s)
      上垣外正己
    • Organizer
      日本油化学会東海支部油化学セミナー
    • Place of Presentation
      名古屋市工業研究所
    • Year and Date
      2008-06-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] Manganese-Based Living Radical Copolymerization of Conjugated/Unconjugated Monomers2008

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      グローバルCOE成果報告会2008
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-06-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] Control of Radical Polymerization for Precision Polymer Synthesis2008

    • Author(s)
      M. Kamigaito
    • Organizer
      2nd NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
    • Place of Presentation
      Ann Arbor, USA
    • Related Report
      2008 Final Research Report
  • [Presentation] 立体特異性リビングラジカル重合 : 分子量と立体構造の制御2008

    • Author(s)
      上垣外正己
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市
    • Related Report
      2008 Final Research Report
  • [Presentation] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity2008

    • Author(s)
      M. Kamigaito
    • Organizer
      The 236th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] Stereospecific Living Radical Polymerization: Control of Molecular Weight and Stereochemistry2008

    • Author(s)
      M. Kamigaito
    • Organizer
      NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Photoinduced Living Radical Polymerization with Highly Active Manganese Complex2008

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      Third International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
    • Place of Presentation
      大津市
    • Related Report
      2008 Annual Research Report
  • [Presentation] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity2008

    • Author(s)
      Masami Kamigaito
    • Organizer
      The 236 th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Photoinduced Living Radical Polymerization with Highly Active Manganese Complex2008

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      The 236 th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Photoinduced Controlled Radical Copolymerization of Conjugated/Unconjugated Monomers with Highly Active Manganese Complex2008

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      JAPAN-KOREA Polymer Young Scientist Symposium
    • Place of Presentation
      新潟県
    • Related Report
      2008 Annual Research Report
  • [Presentation] Control of Radical Polymerization for Precision Polymer Synthesis2008

    • Author(s)
      Masami Kamigaito
    • Organizer
      2 nd NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21 st Century
    • Place of Presentation
      Ann Arbor, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] 立体特異性リビングラジカル重合 : 分子量と立体構造の制御2008

    • Author(s)
      上垣外正己
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report 2007 Annual Research Report
  • [Presentation] 金属触媒による活性化に基づくリビング重合2008

    • Author(s)
      上垣外正己
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高活性マンガン錯体による共役/非共役モノマーの光誘起リビングラジカル共重合2008

    • Author(s)
      香村和彦
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2008 Annual Research Report
  • [Presentation] 塩化鉄を用いたリビングラジカル重合系の開発2008

    • Author(s)
      青嶋紘
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2008 Annual Research Report
  • [Presentation] ボロン酸を添加剤として用いた立体特異性ラジカル重合2008

    • Author(s)
      吉川奈保子
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2008 Annual Research Report
  • [Presentation] マンガン錯体を用いた共役/非共役モノマーの精密制御ラジカル共重合2008

    • Author(s)
      香村和彦
    • Organizer
      第125回東海高分子研究会講演会
    • Place of Presentation
      知多郡
    • Related Report
      2008 Annual Research Report
  • [Presentation] モノマーの構造と反応性を利用した多元配列制御ラジカル共重合2008

    • Author(s)
      香村和彦
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 塩化鉄によるリビングラジカルおよびカチオン重合系の開発2008

    • Author(s)
      青嶋紘
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] マンガン錯体による共役/非共役モノマーの光誘起精密ラジカル共重合2008

    • Author(s)
      香村和彦
    • Organizer
      第39回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] Stereospecific Living Radical Polymerization : Control of Molecular Weight and Stereochemistry2008

    • Author(s)
      Masami Kamigaito
    • Organizer
      NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] Photoinduced Living Radical Polymerization with Manganese Catalys2008

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 精密ラジカル重合-分子量、立体構造、配列の制御2007

    • Author(s)
      上垣外正己
    • Organizer
      第73回千葉地域活動高分子研究交流講演会
    • Place of Presentation
      出光会館、千葉県
    • Year and Date
      2007-11-16
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高分子の合成〜精密重合における最近の展開2007

    • Author(s)
      上垣外正己
    • Organizer
      第15回東海高分子基礎研修コース
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-10-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] 遷移金属錯体によるリビングラジカル重合2007

    • Author(s)
      上垣外正己
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋市
    • Year and Date
      2007-09-25
    • Related Report
      2008 Final Research Report
  • [Presentation] 遷移金属錯体によるリビングラジカル重合2007

    • Author(s)
      上垣外正己
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] ラジカル重合における分子量、立体構造、配列の制御2007

    • Author(s)
      上垣外正己
    • Organizer
      技術情報協会セミナー
    • Place of Presentation
      北とぴあ、東京都
    • Year and Date
      2007-07-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] アルケンへの高度なラジカル重合反応制御 : 分子量と立体構造の制御2007

    • Author(s)
      上垣外正己
    • Organizer
      炭素資源の高度分子変換 第3回公開シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-06-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] リビングラジカル重合における最近の展開2007

    • Author(s)
      上垣外正己
    • Organizer
      06-2高分子学会講演会
    • Place of Presentation
      東京都
    • Year and Date
      2007-01-26
    • Related Report
      2008 Final Research Report
  • [Presentation] Stereospecific Living Radical Polymerization2007

    • Author(s)
      M. Kamigaito, K. Satoh
    • Organizer
      Controlled/Living Polymerization(CLP07)
    • Place of Presentation
      Antalya, Turkey
    • Related Report
      2008 Final Research Report
  • [Presentation] チオウレア誘導体存在下での立体特異性リビングラジカル重合2007

    • Author(s)
      村山治美、佐藤浩太郎、上垣外正己
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋市
    • Related Report
      2008 Final Research Report
  • [Presentation] アルケンへの高度なラジカル重合反応制御 : 分子量と立体構造の制御2007

    • Author(s)
      上垣外正己
    • Organizer
      炭素資源の高度分子変換第3回公開シンポジウム
    • Place of Presentation
      札幌市
    • Related Report
      2008 Final Research Report
  • [Presentation] 水素結合性有機化合物を用いた立体特異性ラジカル重合2007

    • Author(s)
      村山治美、佐藤浩太郎、上垣外正己
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都市
    • Related Report
      2008 Final Research Report
  • [Presentation] Stereospecific Living Radical Polymerization2007

    • Author(s)
      Masami Kamigaito
    • Organizer
      Controlled/Living Polymerization (CLP07)
    • Place of Presentation
      Antalya, Turkey
    • Related Report
      2007 Annual Research Report
  • [Presentation] Living Radical Polymerization with Manganese Catalyst2007

    • Author(s)
      Kazuhiko Koumura
    • Organizer
      The 10th Pacific Polymer Conference (PPC10)
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高活性マンガン錯体による種々のモノマーのリビングラジガル重合2007

    • Author(s)
      香村和彦
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水素結合性有機化合物を用いた立体特異性ラジカル重合2007

    • Author(s)
      村山治美
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2007 Annual Research Report
  • [Presentation] マンガン錯体による非共役モノマーのリビングラジカル重合および共重合2007

    • Author(s)
      香村和彦
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] チオウレア誘導体存在下での立体特異性リビングラジカル重合2007

    • Author(s)
      村山治美
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] チオウレア誘導体を用いた立体特異性ラジカル重合2007

    • Author(s)
      村山治美
    • Organizer
      第38回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] 立体特異性リビングラジカル重合-ラジカル重合における分子量と立体構造の同時制御2006

    • Author(s)
      上垣外正己
    • Organizer
      高分子同友会
    • Place of Presentation
      東京都
    • Year and Date
      2006-09-26
    • Related Report
      2008 Final Research Report
  • [Presentation] キラル配位子を有する遷移金属錯体によるラジカル付加および精密ラジカル重合2006

    • Author(s)
      飯塚裕介、佐藤浩太郎、上垣外正己
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山市
    • Related Report
      2008 Final Research Report
  • [Presentation] 水素結合性化合物を用いた立体特異性ラジカル重合2006

    • Author(s)
      村山治美、佐藤浩太郎、上垣外正己
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山市
    • Related Report
      2008 Final Research Report
  • [Presentation] Living and Stereospecific Radical Polymerization and Precision Polymer Synthesis2006

    • Author(s)
      M. Kamigaito, K. Satoh, Y, Okamoto
    • Organizer
      12th International Conference on Polymers and Organic Chemistry(POC'06)
    • Place of Presentation
      Okazaki, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] 酢酸ビニルの立体特異性リビングラジカル重合2006

    • Author(s)
      香村和彦、佐藤浩太郎、上垣外正己、岡本佳男
    • Organizer
      第55回高分子学会年次大会
    • Place of Presentation
      名古屋市
    • Related Report
      2008 Final Research Report
  • [Presentation] 多重水素結合を用いた立体特異性ラジカル重合2006

    • Author(s)
      万徳成、佐藤浩太郎、上垣外正己
    • Organizer
      第55回高分子学会年次大会
    • Place of Presentation
      名古屋市
    • Related Report
      2008 Final Research Report
  • [Presentation] メタクリル酸2-ヒドロキシエチルの立体特異性リビングラジカル重合2006

    • Author(s)
      柴田拓哉、佐藤浩太郎、上垣外正己、岡本佳男
    • Organizer
      第55回高分子学会年次大会
    • Place of Presentation
      名古屋市
    • Related Report
      2008 Final Research Report
  • [Presentation] キラルルテニウム錯体によるラジカル付加反応及びラジカル重合反応の制御2006

    • Author(s)
      飯塚裕介、李照明、佐藤浩太郎、上垣外正己、岡本佳男
    • Organizer
      第55回高分子学会年次大会
    • Place of Presentation
      名古屋市
    • Related Report
      2008 Final Research Report
  • [Presentation] Living and Stereospecific Radical Polymerization: Simultaneous Control of Molecular Weight and Tacticity2005

    • Author(s)
      M. Kamigaito, K. Satoh, Y, Okamoto
    • Organizer
      The 2005 International Chemical Congress of Pacific Basin Societies(Pacifichem 2005)
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2008 Final Research Report
  • [Presentation] Metal-Catalyzed Living and Stereospecific Radical Polymerization2005

    • Author(s)
      M. Kamigaito
    • Organizer
      Pacific Polymer Conference IX(PPC IX)
    • Place of Presentation
      Maui, USA
    • Related Report
      2008 Final Research Report
  • [Book] 極性ビニルモノマーの重合, 触媒便覧(触媒学会編)2008

    • Author(s)
      上垣外正己
    • Total Pages
      5
    • Publisher
      講談社サイエンティフィク
    • Related Report
      2008 Final Research Report
  • [Book] 新訂版触媒便覧 : 「極性ビニルモノマーの重合」2008

    • Author(s)
      上垣外正己
    • Total Pages
      5
    • Publisher
      触媒学会編、講談社サイエンティフィク
    • Related Report
      2008 Annual Research Report
  • [Book] 触媒年鑑触媒技術の動向と展望20082008

    • Author(s)
      佐藤浩太郎
    • Total Pages
      14
    • Publisher
      触媒学会編
    • Related Report
      2008 Annual Research Report
  • [Book] 新訂版 触媒便覧 : 「極性ビニルモノマーの重合」2008

    • Author(s)
      上垣外正己
    • Total Pages
      5
    • Publisher
      触媒学会編,講談社サイエンティフィク
    • Related Report
      2007 Annual Research Report
  • [Book] 触媒年鑑 触媒技術の動向と展望2008 : 「リビングラジカル重合における遷移金属触媒の最近の展開」2008

    • Author(s)
      佐藤浩太郎
    • Total Pages
      14
    • Publisher
      触媒学会編,講談社サイエンティフィク
    • Related Report
      2007 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://chiral.apchem.nagoya-u.ac.jp/~living/index.html

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://chiral.apchem.nagoya-u.ac.jp/~living/index.html

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://chiral.apchem.nagoya-u.ac.jp/~living/index.html

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2005-04-01   Modified: 2018-03-28  

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