Precision Controlled Radical Polymerization of Alkenes

• Project/Area Number: 17065008
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Nagoya University
• Principal Investigator: KAMIGAITO Masami Nagoya University, 大学院・工学研究科, 教授 (00273475)
• Co-Investigator(Renkei-kenkyūsha): SATOH Kotaro 名古屋大学, 大学院・工学研究科, 講師 (70377810) ; NISHIYAMA Hisao 名古屋大学, 大学院・工学研究科, 教授 (40135421) ; ITO Jun-ichi 名古屋大学, 大学院・工学研究科, 助教 (20402480) ; OKAMOTO Yoshio 名古屋大学, 名誉教授 (60029501)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥26,900,000 (Direct Cost: ¥26,900,000); Fiscal Year 2008: ¥7,700,000 (Direct Cost: ¥7,700,000); Fiscal Year 2007: ¥7,700,000 (Direct Cost: ¥7,700,000); Fiscal Year 2006: ¥7,700,000 (Direct Cost: ¥7,700,000); Fiscal Year 2005: ¥3,800,000 (Direct Cost: ¥3,800,000)
• Keywords: ラジカル重合 / リビング重合 / 立体特異性重合 / アルケン / ラジカル付加 / 酸化還元 / 金属触媒 / 水素結合 / マンガン錯体 / 鉄触媒 / 位置特異性重合 / ステレオグラジェントポリマー / 連続還元 / 炭素-炭素結合形成 / 酸化反応

Research Abstract

本研究では、アルケンへの高選択的なラジカル付加反応を可能とする高度分子変換反応を構築し、ラジカル重合反応において分子量や立体構造が高度に制御された高分子の精密合成を行うことを目的とした。とくに、金属触媒などを用いたリビングラジカル重合と、水素結合などに基づく立体特異性ラジカル重合を組み合わせることで、生成ポリマーの分子量と立体構造の同時制御を検討した。さらに、触媒系を設計することで、実用化に適した力量あるリビングラジカル重合系の開発を行った。

Research Products

• [Journal Article] Mn_2(C0)_<10>-Induced Controlled/Living Radical Copolymerization of Methyl Acrylate andl-Hexene in Fluoroalcohol : High α-Olefin Content Copolymers with Controlled Molecular Weights (2009)
  • Author(s): Kazuhiko Koumura
  • Journal Title: Macromolecules 42(印刷中)
  • Peer Reviewed
• [Journal Article] Mn_2(C0)_<10>-Induced RAFT Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene (2009)
  • Author(s): Kazuhiko Koumura
  • Journal Title: Polym. J. 41(印刷中)
  • Peer Reviewed
• [Journal Article] Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity (2009)
  • Author(s): Harumi Murayama
  • Journal Title: ACS Symp. Ser. (印刷中)
  • Peer Reviewed
• [Journal Article] 合成高分子の構造精密制御 : ラジカル重合の制御と精密高分子合成 (2009)
  • Author(s): 上垣外正己
  • Journal Title: 化学と工業 62 Pages: 25-27
  • NAID: 10023990863
• [Journal Article] Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity (2009)
  • Author(s): Harumi Murayama
  • Journal Title: ACS Symp.Ser. (未定)(印刷中)
  • Peer Reviewed
• [Journal Article] Stereoregulation in Living Radical Polymerization (2008)
  • Author(s): M. Kamigaito, K. Satoh
  • Journal Title: Macromolecules 41 Pages: 269-272
  • Peer Reviewed
• [Journal Article] Regiospecific Radical Polymerization of Vinyl Methacrylate in the Presence of Lewis Acid into Soluble Polymers with Pendent Vinyl Ester Substituents (2008)
  • Author(s): Fumitaka Sugiyama
  • Journal Title: Macromolecules 41 Pages: 3042-3048
  • Peer Reviewed
• [Journal Article] Manganese-Based Controlled/Living Radical Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene : Highly Active, Versatile, and Photoresponsive Systems (2008)
  • Author(s): Kazuhiko Koumura
  • Journal Title: Macromolecules 41 Pages: 7359-7367
  • Peer Reviewed
• [Journal Article] Iron (III) Chloride/R-Cl/Tributylphosphine for Metal-Catalyzed Living Radical Polymerization : A Unique System with a Higher Oxidation State Iron Complex (2008)
  • Author(s): Kotaro Satoh
  • Journal Title: J. Polym. Sci., Part A, Polym. Chem. 46 Pages: 6358-6363
  • Peer Reviewed
• [Journal Article] Mn_2(CO)_<10>-Induced Controlled/Living Radical Copolymerization of Vinyl Acetate and Methyl Acrylate : Spontaneous Formation of Block Copolymers Consisting of Gradient and Homopolymer Segments (2008)
  • Author(s): Kazuhiko Koumura
  • Journal Title: J. Polym. Sci., Part A, Polym. Chem. 47 Pages: 1343-1353
  • Peer Reviewed
• [Journal Article] ラジカル重合における精密制御-分子量、立体構造、モノマーの配列の制御 (2008)
  • Author(s): 上垣外正己
  • Journal Title: 有機合成化学協会誌 66 Pages: 578-589
  • Peer Reviewed
• [Journal Article] リビングラジカル重合の基礎と展開 (2008)
  • Author(s): 上垣外正己
  • Journal Title: 色材協会誌 81 Pages: 459-470
  • NAID: 10024450610
  • Peer Reviewed
• [Journal Article] Stereoregulation in Living Radical Polymerization (2008)
  • Author(s): Masami Kamigaito
  • Journal Title: Macromolecules 41 Pages: 269-276
  • Peer Reviewed
• [Journal Article] Chiral (-)-DIOP Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions (2007)
  • Author(s): Y. Iizuka, Z. Li, K. Satoh, M. Kamigaito, Y. Okamoto, J.-i Ito, H. Nishiyama
  • Journal Title: Eur. J. Org. Chem Pages: 782-791
  • Peer Reviewed
• [Journal Article] A_xBA_x-Type Block-Graft Polymers with Soft Methacrylate Middle Segments and Hard Styrene Outer Grafts : Synthesis, Morphology, and Mechanical Properties (2007)
  • Author(s): Yu Miura
  • Journal Title: Chem.Asian J. 2 Pages: 662-672
  • Peer Reviewed
• [Journal Article] Chiral (-)-DIOP Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions (2007)
  • Author(s): Yusuke Iizuka
  • Journal Title: Eur. J. Org. Chem. 5 Pages: 782-791
• [Journal Article] Stereogradient Polymers by Ruthenium-Catalyzed Stereospecific Living Radical Copolymerization of Two Monomers with Different Stereospecificities and Reactivities (2006)
  • Author(s): Y. Miura, T. Shibata, K. Satoh, M. Kamigaito, Y. Okamoto
  • Journal Title: J. Am. Chem. Soc. 128 Pages: 16026-16027
  • Peer Reviewed
• [Journal Article] Triple Hydrogen Bonding for Stereospecific Radical Polymerization of a DAD Monomer and Simultaneous Control of Tacticity and Molecular Weight (2006)
  • Author(s): D. Wan, K. Satoh, M. Kamigaito
  • Journal Title: Macromolecules 39 Pages: 6882-6886
  • Peer Reviewed
• [Journal Article] Iodine Transfer Radical Polymerization of Vinyl Acetate in Fluoroalcohols for Simultaneous Control of Molecular Weight, Stereospecificity, and Regiospecificity (2006)
  • Author(s): K. Koumura, K. Satoh, M. Kamigaito, Y. Okamoto
  • Journal Title: Macromolecules 39 Pages: 4054-4061
  • Peer Reviewed
• [Journal Article] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity (2006)
  • Author(s): M. Kamigaito, K. Satoh
  • Journal Title: J. Polym. Sci., Part A, Polym. Chem. 44 Pages: 6147-6158
  • Peer Reviewed
• [Journal Article] Ruthenium-Catalyzed Living Radical Polymerization of Methyl and 2-Hydroxyethyl Methacrylates and Sequential Synthesis of Stereoblock Polymers (2006)
  • Author(s): T. Shibata, K. Satoh, M. Kamigaito, Y. Okamoto
  • Journal Title: J. Polym. Sci., Part A, Polym. Chem. 44 Pages: 3609-3615
  • Peer Reviewed
• [Journal Article] Iron-Catalyzed Radical Polymerization of Acrylamides in the Presence of Lewis Acid for Simulatenous Control of Molecular Weight and Tacticity (2006)
  • Author(s): Y. Sugiyama, K. Satoh, M. Kamigaito, Y. Okamoto
  • Journal Title: J. Polym. Sci., Part A, Polym. Chem. 44 Pages: 2086-2098
  • Peer Reviewed
• [Journal Article] Stereospecific Living Radical Polymerization (2006)
  • Author(s): M. Kamigaito, K. Satoh, D. Wan, K. Koumura, T. Shibata, Y. Okamoto
  • Journal Title: ACS Symp. Ser, 944 Pages: 26-39
  • NAID: 10017538048
  • Peer Reviewed
• [Journal Article] 立体特異性リビングラジカル重合 (2006)
  • Author(s): 上垣外正己、佐藤浩太郎
  • Journal Title: 高分子 55 Pages: 250-253
  • NAID: 10017538048
• [Journal Article] Stereogradient Polymers by Ruthenium-Catalyzed Stereospecific Living Radical Copolymerization of Two Monomers with Different Stereospecificities and Reactivities (2006)
  • Author(s): Yu Miura
  • Journal Title: J. Am. Chem. Soc. 128・50 Pages: 16026-16027
• [Journal Article] Triple Hydrogen Bonding for Stereospecific Radical Polymerization of a DAD Monomer and Simultaneous Control of Tacticity and Molecular Weight (2006)
  • Author(s): Decheng Wan
  • Journal Title: Macromolecules 39・20 Pages: 6882-6886
• [Journal Article] Iodine Transfer Radical Polymerization of Vinyl Acetate in Fluoroalcohols for Simultaneous Control of Molecular Weight, Stereospecificity, and Regiospecificity (2006)
  • Author(s): Kazuhiko Koumura
  • Journal Title: Macromolecules 39・12 Pages: 4054-4061
• [Journal Article] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity (2006)
  • Author(s): Masami Kamigaito
  • Journal Title: J. Polym. Sci., Part A : Polym. Chem. 44・21 Pages: 6147-6158
• [Journal Article] Simultaneous Control of the Stereospecificity and Molecular Weight in the Ruthenium-Catalyzed Living Radical Polymerization of Methyl and 2-Hydroxyethyl Methacrylates and Sequential Synthesis of Stereoblock Polymers (2006)
  • Author(s): Takuya Shibata
  • Journal Title: J. Polym. Sci., Part A : Polym. Chem. 44・11 Pages: 3609-3615
• [Journal Article] Iron-Catalyzed Radical Polymerization of Acrylamides in the Presence of Lewis Acid for Simultaneous Control of Molecular Weight and Tacticity (2006)
  • Author(s): Yuya Sugiyama
  • Journal Title: J.Polym.Sci., Part A : Polym.Chem. 44・6 Pages: 2086-2098
• [Journal Article] Stereospecific Living Radical Polymerization (2006)
  • Author(s): Masami Kamigaito
  • Journal Title: ACS Symposium Series (in press)
  • NAID: 10017538048
• [Journal Article] 立体特異性リビングラジカル重合 (2006)
  • Author(s): 上垣外 正己
  • Journal Title: 高分子 55・4 Pages: 250-253
  • NAID: 10017538048
• [Journal Article] キラルルテニウム錯体によるラジカル付加反応及びラジカル重合反応の制御 (2006)
  • Author(s): 飯塚 裕介
  • Journal Title: 高分子学会予稿集 55(印刷中)
• [Journal Article] Xanthate-Mediated Radical Polymerization of N-Vinylpyrrolidone in Fluoroalcohols for Simultaneous Control of Molecular Weight and Tacticity (2005)
  • Author(s): D. Wan, K. Satoh, M. Kamigaito, Y. Okamoto
  • Journal Title: Macromolecules 38 Pages: 10397-10405
  • Peer Reviewed
• [Journal Article] Xanthate-Mediated Radical Polymerization of N-Vinylpyrrolidone in Fluoroalcohols for Simultaneous Control of Molecular Weight and Tacticity (2005)
  • Author(s): Decheng Wan
  • Journal Title: Macromolecules 38・25 Pages: 10397-10405
• [Journal Article] Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity
  • Author(s): H. Murayama, K. Satoh, M. Kamigaito
  • Journal Title: ACS Symp. Ser. (in press)
  • Peer Reviewed
• [Presentation] Metal-Catalyzed Living Radical Polymerization and Radical Polyaddition (2009)
  • Author(s): Masami Kamigaito
  • Organizer: The 1 st G-COE International Symposium on Elucidation and Design of Materials and Molecular Functions
  • Place of Presentation: 名古屋大学
• [Presentation] Manganese-Based Photoinduced Living Radical Polymerization of Vinyl Acetate and Methyl Acrylate (2009)
  • Author(s): Kazuhiko Koumura
  • Organizer: The 1 st G-COE International Symposium on Elucidation and Design of Materials and Molecular Functions
  • Place of Presentation: 名古屋大学
• [Presentation] マンガン錯体を用いた酢酸ビニルとアクリル酸メチルのリビングラジカル共重合 (2009)
  • Author(s): 香村和彦
  • Organizer: 第2回物質化学フロンティアセミナー-ナノ物質科学の最前線 : 作る、見る、測る-
  • Place of Presentation: 名古屋大学
• [Presentation] 高分子の合成〜精密重合における最近の展開 (2008)
  • Author(s): 上垣外正己
  • Organizer: 第16回東海高分子基礎研修コース
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2008-10-20
• [Presentation] 遷移金属錯体によるリビングラジカル重合 (2008)
  • Author(s): 上垣外正己
  • Organizer: 日本油化学会東海支部油化学セミナー
  • Place of Presentation: 名古屋市工業研究所
  • Year and Date: 2008-06-12
• [Presentation] Manganese-Based Living Radical Copolymerization of Conjugated/Unconjugated Monomers (2008)
  • Author(s): Kazuhiko Koumura
  • Organizer: グローバルCOE成果報告会2008
  • Place of Presentation: 名古屋大学
  • Year and Date: 2008-06-11
• [Presentation] Control of Radical Polymerization for Precision Polymer Synthesis (2008)
  • Author(s): M. Kamigaito
  • Organizer: 2nd NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
  • Place of Presentation: Ann Arbor, USA
• [Presentation] 立体特異性リビングラジカル重合 : 分子量と立体構造の制御 (2008)
  • Author(s): 上垣外正己
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪市
• [Presentation] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity (2008)
  • Author(s): M. Kamigaito
  • Organizer: The 236th ACS National Meeting
  • Place of Presentation: Philadelphia, USA
• [Presentation] Stereospecific Living Radical Polymerization: Control of Molecular Weight and Stereochemistry (2008)
  • Author(s): M. Kamigaito
  • Organizer: NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
  • Place of Presentation: Nagoya, Japan
• [Presentation] Photoinduced Living Radical Polymerization with Highly Active Manganese Complex (2008)
  • Author(s): Kazuhiko Koumura
  • Organizer: Third International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: 大津市
• [Presentation] Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity (2008)
  • Author(s): Masami Kamigaito
  • Organizer: The 236 th ACS National Meeting
  • Place of Presentation: Philadelphia, USA
• [Presentation] Photoinduced Living Radical Polymerization with Highly Active Manganese Complex (2008)
  • Author(s): Kazuhiko Koumura
  • Organizer: The 236 th ACS National Meeting
  • Place of Presentation: Philadelphia, USA
• [Presentation] Photoinduced Controlled Radical Copolymerization of Conjugated/Unconjugated Monomers with Highly Active Manganese Complex (2008)
  • Author(s): Kazuhiko Koumura
  • Organizer: JAPAN-KOREA Polymer Young Scientist Symposium
  • Place of Presentation: 新潟県
• [Presentation] Control of Radical Polymerization for Precision Polymer Synthesis (2008)
  • Author(s): Masami Kamigaito
  • Organizer: 2 nd NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21 st Century
  • Place of Presentation: Ann Arbor, USA
• [Presentation] 立体特異性リビングラジカル重合 : 分子量と立体構造の制御 (2008)
  • Author(s): 上垣外正己
  • Organizer: 第57回高分子学会討論会
  • Place of Presentation: 大阪市立大学
• [Presentation] 金属触媒による活性化に基づくリビング重合 (2008)
  • Author(s): 上垣外正己
  • Organizer: 第57回高分子学会討論会
  • Place of Presentation: 大阪市立大学
• [Presentation] 高活性マンガン錯体による共役/非共役モノマーの光誘起リビングラジカル共重合 (2008)
  • Author(s): 香村和彦
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 塩化鉄を用いたリビングラジカル重合系の開発 (2008)
  • Author(s): 青嶋紘
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] ボロン酸を添加剤として用いた立体特異性ラジカル重合 (2008)
  • Author(s): 吉川奈保子
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] マンガン錯体を用いた共役/非共役モノマーの精密制御ラジカル共重合 (2008)
  • Author(s): 香村和彦
  • Organizer: 第125回東海高分子研究会講演会
  • Place of Presentation: 知多郡
• [Presentation] モノマーの構造と反応性を利用した多元配列制御ラジカル共重合 (2008)
  • Author(s): 香村和彦
  • Organizer: 第57回高分子学会討論会
  • Place of Presentation: 大阪市立大学
• [Presentation] 塩化鉄によるリビングラジカルおよびカチオン重合系の開発 (2008)
  • Author(s): 青嶋紘
  • Organizer: 第57回高分子学会討論会
  • Place of Presentation: 大阪市立大学
• [Presentation] マンガン錯体による共役/非共役モノマーの光誘起精密ラジカル共重合 (2008)
  • Author(s): 香村和彦
  • Organizer: 第39回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋大学
• [Presentation] Stereospecific Living Radical Polymerization : Control of Molecular Weight and Stereochemistry (2008)
  • Author(s): Masami Kamigaito
  • Organizer: NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
  • Place of Presentation: Nagoya, Japan
• [Presentation] Photoinduced Living Radical Polymerization with Manganese Catalys (2008)
  • Author(s): Kazuhiko Koumura
  • Organizer: NU-UM Joint Symposium on Supramacromolecular Material Science and Engineering in the 21st Century
  • Place of Presentation: Nagoya, Japan
• [Presentation] 精密ラジカル重合-分子量、立体構造、配列の制御 (2007)
  • Author(s): 上垣外正己
  • Organizer: 第73回千葉地域活動高分子研究交流講演会
  • Place of Presentation: 出光会館、千葉県
  • Year and Date: 2007-11-16
• [Presentation] 高分子の合成〜精密重合における最近の展開 (2007)
  • Author(s): 上垣外正己
  • Organizer: 第15回東海高分子基礎研修コース
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-10-18
• [Presentation] 遷移金属錯体によるリビングラジカル重合 (2007)
  • Author(s): 上垣外正己
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋市
  • Year and Date: 2007-09-25
• [Presentation] 遷移金属錯体によるリビングラジカル重合 (2007)
  • Author(s): 上垣外正己
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-25
• [Presentation] ラジカル重合における分子量、立体構造、配列の制御 (2007)
  • Author(s): 上垣外正己
  • Organizer: 技術情報協会セミナー
  • Place of Presentation: 北とぴあ、東京都
  • Year and Date: 2007-07-26
• [Presentation] アルケンへの高度なラジカル重合反応制御 : 分子量と立体構造の制御 (2007)
  • Author(s): 上垣外正己
  • Organizer: 炭素資源の高度分子変換 第3回公開シンポジウム
  • Place of Presentation: 北海道大学
  • Year and Date: 2007-06-18
• [Presentation] リビングラジカル重合における最近の展開 (2007)
  • Author(s): 上垣外正己
  • Organizer: 06-2高分子学会講演会
  • Place of Presentation: 東京都
  • Year and Date: 2007-01-26
• [Presentation] Stereospecific Living Radical Polymerization (2007)
  • Author(s): M. Kamigaito, K. Satoh
  • Organizer: Controlled/Living Polymerization(CLP07)
  • Place of Presentation: Antalya, Turkey
• [Presentation] チオウレア誘導体存在下での立体特異性リビングラジカル重合 (2007)
  • Author(s): 村山治美、佐藤浩太郎、上垣外正己
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋市
• [Presentation] アルケンへの高度なラジカル重合反応制御 : 分子量と立体構造の制御 (2007)
  • Author(s): 上垣外正己
  • Organizer: 炭素資源の高度分子変換第3回公開シンポジウム
  • Place of Presentation: 札幌市
• [Presentation] 水素結合性有機化合物を用いた立体特異性ラジカル重合 (2007)
  • Author(s): 村山治美、佐藤浩太郎、上垣外正己
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都市
• [Presentation] Stereospecific Living Radical Polymerization (2007)
  • Author(s): Masami Kamigaito
  • Organizer: Controlled/Living Polymerization (CLP07)
  • Place of Presentation: Antalya, Turkey
• [Presentation] Living Radical Polymerization with Manganese Catalyst (2007)
  • Author(s): Kazuhiko Koumura
  • Organizer: The 10th Pacific Polymer Conference (PPC10)
  • Place of Presentation: Kobe, Japan
• [Presentation] 高活性マンガン錯体による種々のモノマーのリビングラジガル重合 (2007)
  • Author(s): 香村和彦
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都国際会議場
• [Presentation] 水素結合性有機化合物を用いた立体特異性ラジカル重合 (2007)
  • Author(s): 村山治美
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都国際会議場
• [Presentation] マンガン錯体による非共役モノマーのリビングラジカル重合および共重合 (2007)
  • Author(s): 香村和彦
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
• [Presentation] チオウレア誘導体存在下での立体特異性リビングラジカル重合 (2007)
  • Author(s): 村山治美
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
• [Presentation] チオウレア誘導体を用いた立体特異性ラジカル重合 (2007)
  • Author(s): 村山治美
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学
• [Presentation] 立体特異性リビングラジカル重合-ラジカル重合における分子量と立体構造の同時制御 (2006)
  • Author(s): 上垣外正己
  • Organizer: 高分子同友会
  • Place of Presentation: 東京都
  • Year and Date: 2006-09-26
• [Presentation] キラル配位子を有する遷移金属錯体によるラジカル付加および精密ラジカル重合 (2006)
  • Author(s): 飯塚裕介、佐藤浩太郎、上垣外正己
  • Organizer: 第55回高分子討論会
  • Place of Presentation: 富山市
• [Presentation] 水素結合性化合物を用いた立体特異性ラジカル重合 (2006)
  • Author(s): 村山治美、佐藤浩太郎、上垣外正己
  • Organizer: 第55回高分子討論会
  • Place of Presentation: 富山市
• [Presentation] Living and Stereospecific Radical Polymerization and Precision Polymer Synthesis (2006)
  • Author(s): M. Kamigaito, K. Satoh, Y, Okamoto
  • Organizer: 12th International Conference on Polymers and Organic Chemistry(POC'06)
  • Place of Presentation: Okazaki, Japan
• [Presentation] 酢酸ビニルの立体特異性リビングラジカル重合 (2006)
  • Author(s): 香村和彦、佐藤浩太郎、上垣外正己、岡本佳男
  • Organizer: 第55回高分子学会年次大会
  • Place of Presentation: 名古屋市
• [Presentation] 多重水素結合を用いた立体特異性ラジカル重合 (2006)
  • Author(s): 万徳成、佐藤浩太郎、上垣外正己
  • Organizer: 第55回高分子学会年次大会
  • Place of Presentation: 名古屋市
• [Presentation] メタクリル酸2-ヒドロキシエチルの立体特異性リビングラジカル重合 (2006)
  • Author(s): 柴田拓哉、佐藤浩太郎、上垣外正己、岡本佳男
  • Organizer: 第55回高分子学会年次大会
  • Place of Presentation: 名古屋市
• [Presentation] キラルルテニウム錯体によるラジカル付加反応及びラジカル重合反応の制御 (2006)
  • Author(s): 飯塚裕介、李照明、佐藤浩太郎、上垣外正己、岡本佳男
  • Organizer: 第55回高分子学会年次大会
  • Place of Presentation: 名古屋市
• [Presentation] Living and Stereospecific Radical Polymerization: Simultaneous Control of Molecular Weight and Tacticity (2005)
  • Author(s): M. Kamigaito, K. Satoh, Y, Okamoto
  • Organizer: The 2005 International Chemical Congress of Pacific Basin Societies(Pacifichem 2005)
  • Place of Presentation: Honolulu, USA
• [Presentation] Metal-Catalyzed Living and Stereospecific Radical Polymerization (2005)
  • Author(s): M. Kamigaito
  • Organizer: Pacific Polymer Conference IX(PPC IX)
  • Place of Presentation: Maui, USA
• [Book] 極性ビニルモノマーの重合, 触媒便覧(触媒学会編) (2008)
  • Author(s): 上垣外正己
  • Total Pages: 5
  • Publisher: 講談社サイエンティフィク
• [Book] 新訂版触媒便覧 : 「極性ビニルモノマーの重合」 (2008)
  • Author(s): 上垣外正己
  • Total Pages: 5
  • Publisher: 触媒学会編、講談社サイエンティフィク
• [Book] 触媒年鑑触媒技術の動向と展望2008 (2008)
  • Author(s): 佐藤浩太郎
  • Total Pages: 14
  • Publisher: 触媒学会編
• [Book] 新訂版 触媒便覧 : 「極性ビニルモノマーの重合」 (2008)
  • Author(s): 上垣外正己
  • Total Pages: 5
  • Publisher: 触媒学会編,講談社サイエンティフィク
• [Book] 触媒年鑑 触媒技術の動向と展望2008 : 「リビングラジカル重合における遷移金属触媒の最近の展開」 (2008)
  • Author(s): 佐藤浩太郎
  • Total Pages: 14
  • Publisher: 触媒学会編,講談社サイエンティフィク
• [Remarks] ホームページ等
  • URL: http://chiral.apchem.nagoya-u.ac.jp/~living/index.html
• [Remarks]
  • URL: http://chiral.apchem.nagoya-u.ac.jp/~living/index.html
• [Remarks]
  • URL: http://chiral.apchem.nagoya-u.ac.jp/~living/index.html