Selective Transformations of Cycloalkanes via Carbon-Carbon Bond Cleavage

• Project/Area Number: 17065013
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyoto University
• Principal Investigator: NISHIMURA Takahiro Kyoto University, 大学院・理学研究科, 講師 (50335197)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥17,500,000 (Direct Cost: ¥17,500,000); Fiscal Year 2008: ¥5,000,000 (Direct Cost: ¥5,000,000); Fiscal Year 2007: ¥5,000,000 (Direct Cost: ¥5,000,000); Fiscal Year 2006: ¥5,000,000 (Direct Cost: ¥5,000,000); Fiscal Year 2005: ¥2,500,000 (Direct Cost: ¥2,500,000)
• Keywords: ロジウム / パラジウム / 炭素炭素結合開裂 / アルコール / アリール化 / アルキニル化 / 触媒反応 / 不斉合成 / アルキニルケトン / アルキニル脱離 / 遷移金属 / 転位反応 / 環状化合物 / 開環反応 / 第三級アルコール / アリール化反応 / 炭素-炭素結合開裂 / モリブデン / 異性化 / エンイン / シクロプロパン / ホモアリルアルコール / オキソ金属錯体 / バナジウム

Research Abstract

第三級アルコール類と遷移金属との反応において、炭素-炭素結合の選択的な切断により有機金属種を発生させ、新たな炭素-炭素結合の形成を触媒的に行うことに成功した。例えば、ロジウム触媒を用いて、第三級アルコールからアリール、アルケニルおよびアルキニル基を電子不足アルケンへ移動させることに成功した。また、不斉反応への展開も行い、高収率かつ高エナンチオ選択的に生成物を得た。

Research Products

• [Journal Article] ロジウム触媒によるアルキン、アレンおよび共役エノンのアルキニル化反応 (2008)
  • Author(s): 西村貴洋
  • Journal Title: 有機合成化学協会誌 66 Pages: 1160-1167
  • NAID: 10024409663
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes. (2008)
  • Author(s): Nishimura, T.; Tsurumaki, E.; Kawamoto, T.; Guo, X.-X.; Hayashi, T.
  • Journal Title: Org. Lett. 10 Pages: 4057-4060
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Terminal Alkynes to Diarylphosphinylallenes (2008)
  • Author(s): Nishimura, T.; Guo, X.-X.; Hayashi, T.
  • Journal Title: Chem. Asian J. 3 Pages: 1505-1510
  • Peer Reviewed
• [Journal Article] C_2-Symmetric Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Iridium-catalyzed Asymmetric Annulation of 1,3-Dienes with 2-Formylphenylboron Reagents. (2008)
  • Author(s): Nishimura, T.; Yasuhara, Y.; Nagaosa, M.; Hayashi, T.
  • Journal Title: Tetrahedron : Asymmetry 19 Pages: 1778-1783
  • Peer Reviewed
• [Journal Article] Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids. (2008)
  • Author(s): Nishimura, T.; Nagaosa, M.; Hayashi, T.
  • Journal Title: Chem. Lett. 37 Pages: 860-861
  • NAID: 10024281577
  • Peer Reviewed
• [Journal Article] Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones. (2008)
  • Author(s): Nishimura, T.; Guo, X.-X.; Uchiyama, N.; Katoh, T.; Hayashi
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 1576-1577
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Rearrangement of Aryl Bis(alkynyl) Carbinols to 3-Alkynyl-1-indanones. (2008)
  • Author(s): Shintani, R.; Takatsu, K.; Katoh, T.; Nishimura, T.; Hayashi, T.
  • Journal Title: Angew. Chem., Int. Ed. 47 Pages: 1447-1449
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes (2008)
  • Author(s): Nishimura, T. ; Tsurumaki, E. ; Kawamoto, T. ; Guo, X.-X. ; Hayashi, T.
  • Journal Title: Organic Letters 10 Pages: 4057-4060
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Addition of Terminal Alkynes to Diphenylphosphinylallenes (2008)
  • Author(s): Nishimura, T. ; Guo, X.-X. ; Hayashi, T.
  • Journal Title: Chemistry an Asian Journal 3 Pages: 1505-1510
  • Peer Reviewed
• [Journal Article] C_2-Symmetric Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Iridium-Catalyzed Asymmetric Annulation of 1,3-Dienes with 2-Formylphenylboron Reagents (2008)
  • Author(s): Nishimura, T. ; Yasuhara, Y. ; Hayashi, T.
  • Journal Title: Tetrahedron : Asymmetry 19 Pages: 1778-1783
  • Peer Reviewed
• [Journal Article] Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asynunetric1,4-Addition of Arylboronic Acids (2008)
  • Author(s): Nishimura, T. ; Nagaiisa, M. ; Hayashi, T.
  • Journal Title: Chemistry Letters 37 Pages: 860-861
  • Peer Reviewed
• [Journal Article] Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones (2008)
  • Author(s): Nishimura, T.; Guo, X.-X.; Uchiyama, N.; Katoh, T.; Hayashi, T.
  • Journal Title: Journal of the American Chemical Society 130 Pages: 1576-1577
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Rearrangement of Aryl Bis (alkynyl) Carbinols to 3-Alkynyl-1-indanones (2008)
  • Author(s): Shintani, R.; Takatsu, K.; Katoh, T.; Nishimura, T.; Hayashi, T.
  • Journal Title: Angewandte Chemie International Edition 47 Pages: 1447-1449
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes : An Alkynylrhodium(I) Intermediate Generated from the Hydroxorhodium(I) Complex [Rh(OH)(binap)]_2. (2007)
  • Author(s): Nishimura, T.; Guo, X-.X; Ohnishi, K.; Hayashi. T.
  • Journal Title: Adv. Synth. Catal. 349 Pages: 2669-2672
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols : Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones. (2007)
  • Author(s): Nishimura, T.; Katoh, T.; Takatsu, K.; Shintani, R.; Hayashi, T.
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 14158-14159
  • Peer Reviewed
• [Journal Article] Iridium-Catalyzed [3 + 2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids. A Catalytic Process Involving Regioselective 1,2-Addition. (2007)
  • Author(s): Nishimura, T.; Yasuhara, Y.; Hayashi, T.
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 7506-7507
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Aryl Transfer from Trisubstituted Aryl Methanols to α,β-Unsaturated Carbonyl Compounds. (2007)
  • Author(s): Nishimura, T.; Katoh, K.; Hayashi, T.
  • Journal Title: Angew. Chem., Int. Ed. 46 Pages: 4937-4939
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa- and Azabicyclic Alkenes. (2007)
  • Author(s): Nishimura, T.; Kawamoto, T.; Sasaki, K.; Tsurumaki, E.; Hayashi, T.
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 1492-1493
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols: Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones (2007)
  • Author(s): Nishimura, T.; Katoh, T.; Takatsu, K.; Shintani, R.; Hayashi, T.
  • Journal Title: Journal of the American Chemical Society 129 Pages: 14158-14159
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Aryl Transfer from tert-Arylmethanols to α,β-Unsaturated Carbonyl Compounds (2007)
  • Author(s): Takahiro Nishimura, Taisuke Katoh, and Tamio Hayashi
  • Journal Title: Angewandte Chemie International Edition 46 Pages: 4937-4939
  • Peer Reviewed
• [Journal Article] Iridium-Catalyzed [3+2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids. A Catalytic Process Involving Regioselective 1,2-Addition (2007)
  • Author(s): Nishimura, T.; Yasuhara, Y.; Hayashi, T.
  • Journal Title: Journal of the American Chemical Society 129 Pages: 2669-2672
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium (I) Intermediate Generated from the Hydroxorhodium (I) Complex [Rh (OH)(binap)]_2 (2007)
  • Author(s): Nishimura, T.; Guo, X.-X.; Ohnishi, K.; HaYashi, T.
  • Journal Title: Advanced Synthesis & Catalysis 349 Pages: 4937-4939
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Aryl Transfer from tert-Arylmethanols to α,β-Unsaturated Carbonyl Compounds (2007)
  • Author(s): Takahiro Nishimura, Taisuke Katoh, Tamio Hayashi
  • Journal Title: Angewandte Chemie International Edition (印刷中)
• [Journal Article] Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa- and Azabicyclic Alkenes (2007)
  • Author(s): Takahiro Nishimura, Takahiro Kawamoto, Keigo Sasaki, Eiji Tsurumaki, Tamio Hayashi
  • Journal Title: Journal of the American Chemical Society 129(6) Pages: 1492-1493
• [Journal Article] Highly Selective 1,6-Addition of Aryl Boronic Acids to α,β,γ,δ-Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex. (2006)
  • Author(s): Nishimura, T.; Yasuhara, Y.; Hayashi, T.
  • Journal Title: Angew. Chem., Int. Ed. 45 Pages: 5164-5166
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Asymmetric Hydroarylation of Diphenylphosphinylallenes with Arylboronic Acids. (2006)
  • Author(s): Nishimura, T.; Hirabayashi, S.; Yasuhara, Y.; Hayashi, T.
  • Journal Title: J. Am. Chem. Soc. 128 Pages: 2556-2557
  • Peer Reviewed
• [Journal Article] Highly Selective 1,6-Addition of Aryl Boronic Acids to α,β,γ,δ-Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex (2006)
  • Author(s): Takahiro Nishimura, Yuichi Yasuhara, Tamio Hayashi
  • Journal Title: Angewandte Chemie International Edition 45(31) Pages: 5164-5166
• [Journal Article] Rhodium-Catalyzed Asymmetric Hydroarylation of Diphenylphosphinylallenes with Arylboronic Acids (2006)
  • Author(s): Takahiro Nishimura, Sho Hirabayashi, Yuichi Yasuhara, Tamio Hayashi
  • Journal Title: Journal of the America Chemical Society 128巻8号 Pages: 2556-2557
• [Journal Article] Iridium-Catalyzed Ring Cleavage Reaction of Cyclobutanone O-Benzoyloximes Providing Nitriles (2005)
  • Author(s): Nishimura, T.; Yoshinaka, T.; Nishiguchi, Y.; Maeda, Y.; Uemura, S.
  • Journal Title: Org. Lett. 7 Pages: 2425-2427
  • Peer Reviewed
• [Journal Article] Molybdenum- and Rhenium-catalyzed Isomerization of Cyclopropanemethanols to Tetrahydrofurans. (2005)
  • Author(s): Maeda, Y.; Nishimura, T.; Uemura, S.
  • Journal Title: Chem. Lett. 34 Pages: 790-791
  • NAID: 10015663283
  • Peer Reviewed
• [Journal Article] Iridium-catalyzed Ring Cleavage Reaction of Cyclobutanone O-Benzoyloximes Providing Nitriles (2005)
  • Author(s): Takahiro Nishimura, Tomoaki Yoshinaka, Yoshiki Nishiguchi, Yasunari Maeda, Sakae Uemura
  • Journal Title: Organic Letters 7巻12号 Pages: 2425-2427
• [Journal Article] Molybdenum- and Rhenium-catalyzed Isomerization of Cyclopropanemethanols to Tetrahydrofurans (2005)
  • Author(s): Yasunari Maeda, Takahiro Nishimura, Sakae Uemura
  • Journal Title: Chemistry Letters 34巻6号 Pages: 790-791
  • NAID: 10015663283
• [Presentation] パラジウムを触媒とするオレフィンの酸化的アルキニル化反応 (2009)
  • Author(s): 西村貴洋、永長誠、林民生
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-30
• [Presentation] パラジウムを触媒とするオレフィンの酸化的アルキニル化反応 (2009)
  • Author(s): 西村貴洋、永長誠、林民生
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 東京
  • Year and Date: 2009-03-30
• [Presentation] Catalytic Organic Transformations via β-Aryl and Alkynyl Elimination on Metal Alkoxides. (2009)
  • Author(s): Nishimura, T.
  • Organizer: 2nd Japanese-Singapore Bilateral Symposium on Catalysis
  • Place of Presentation: Kyoto
  • Year and Date: 2009-01-06
• [Presentation] Catalytic Organic Transformations via β-Aryl and Alkynyl Elimination on Metal Alkoxides (2009)
  • Author(s): Nishimura, T.
  • Organizer: 2nd Japanese-Singapore Bilateral Symposium on Catalysis
  • Place of Presentation: 京都
  • Year and Date: 2009-01-06
• [Presentation] Rhodium-Catalyzed Asymmetric Alkynylations of Carbon-Carbon Unsaturated Bonds. (2008)
  • Author(s): Nishimura, T.
  • Organizer: UK/Japan Joint Symposium on Asymmetric Catalysis
  • Place of Presentation: Kyoto
  • Year and Date: 2008-12-09
• [Presentation] Rhodium-Catalyzed Asymmetric Alkynylations of Carbon-Carbon Unsaturated Bonds (2008)
  • Author(s): Nishimura, T.
  • Organizer: UK/Japan Joint Symposium on Asymmetric Catalysis
  • Place of Presentation: 京都
  • Year and Date: 2008-12-09
• [Presentation] ロジウム触媒を用いたシリルアセチレンによるエノンの不斉共役アルキニル化反応 (2008)
  • Author(s): 西村貴洋、林民生(他5名)
  • Organizer: 第55回有機金属化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-30
• [Presentation] イリジウム触媒による1,3-ジエンへのアリールボロン酸の高選択的付加反応 (2008)
  • Author(s): 西村貴洋、安原祐一、林民生
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-30
• [Presentation] ロジウムおよびイリジウムを触媒とする高選択的炭素-炭素結合形成法の開発 (2008)
  • Author(s): 西村貴洋
  • Organizer: 第25回有機合成化学セミナー
  • Place of Presentation: 熊本
  • Year and Date: 2008-09-08
• [Presentation] Rhodium-Catalyzed Asymmetric Synthesis of β-Alkynylketones. (2008)
  • Author(s): Nishimura, T.; Guo, X.-X.; Katoh, T.; Uchiyama, N.; Takatsu, K.; Shintani, R.; Hayashi, T.
  • Organizer: 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: Shiga
  • Year and Date: 2008-05-27
• [Presentation] C_2-Symmetric Tetrafluorobenzobarrelenes as Efficient Ligands for the Iridium-Catalyzed Asymmetric Annulation of 1,3-Dienes with 2-Formylphenylboron Reagents. (2008)
  • Author(s): Nishimura, T.; Yasuhara, Y.; Hayashi, T.
  • Organizer: 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: Shiga
  • Year and Date: 2008-05-27
• [Presentation] Preparation of C_2-Symmetric Tetrafluorobenzobarrelene Ligands and Their Use for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids. (2008)
  • Author(s): Nishimura, T.; Nagaosa, M.; Hayashi, T.
  • Organizer: 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: Shiga
  • Year and Date: 2008-05-27
• [Presentation] Rhodium-Catalyzed Asymmetric Synthesis of β-Alkynylketones (2008)
  • Author(s): Nishimura, T. ; Guo, X.-X.; Katoh, T. ; Uchiyama, N. ; Takatsu, K. ; Shintani, R. ; Hayashi, T.
  • Organizer: 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: 滋賀
  • Year and Date: 2008-05-27
• [Presentation] C, Symmetric Tetrafluorobenzobanelenes as Efficient Ligands for the Iridium-Catalyzed Asymmetric Annulation of 1,3-Dienes with 2-Formylphenylboron Reagents (2008)
  • Author(s): Nishimura, T. ; Yasuhara, Y. ; Hayashi, T.
  • Organizer: 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: 滋賀
  • Year and Date: 2008-05-27
• [Presentation] Preparation of C_2 Symmetric Tetrafluorobenzobarrelene Ligands and Their Use for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids (2008)
  • Author(s): Nishimura, T. ; Nagaosa, M. ; Hayashi, T.
  • Organizer: 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: 滋賀
  • Year and Date: 2008-05-27
• [Presentation] ロジウム触媒を用いるアルキニルアルケニルカルビノール類の不斉転位反応 (2008)
  • Author(s): 西村貴洋、加藤泰祐、高津慶士、新谷亮、林民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-30
• [Presentation] ロジウム触媒を用いるシリルアセチレンのエノンへの不斉付加反応 (2008)
  • Author(s): 西村貴洋、郭勲祥、内山七瀬、加藤泰祐、林民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-30
• [Presentation] ロジウム触媒を用いたアリールビス(アルキニル)カルビノールの3-アルキニル-1-インダノンへの転位反応 (2008)
  • Author(s): 新谷亮、高津慶士、加藤泰祐、西村貴洋、林民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-28
• [Presentation] Highly Selective Iridium-Catalyzed Addition of Arylboronic Acids to 1,3-Dienes. (2007)
  • Author(s): Nishimura, T.
  • Organizer: 4th Japanese-Sino Symposium on Organic Chemistry for Young Scientists
  • Place of Presentation: Chiba
  • Year and Date: 2007-09-25
• [Presentation] Rhodium-Catalyzed 1,4-Addition to α,β-Unsaturated Carbonyl Compounds with tert-Alcohols as Arylating Reagents. (2007)
  • Author(s): Nishimura, T.; Katoh, T.; Hayashi, T.
  • Organizer: 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 14)
  • Place of Presentation: Nara
  • Year and Date: 2007-08-05
• [Presentation] Rhodium-Catalyzed 1,4-Addition to α,β-Unsaturated Carbonyl Compounds with tert-Alcohols as Arylating Reagents (2007)
  • Author(s): Nishimura, T.; Katoh, T.; Hayashi, T.
  • Organizer: 14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 14)
  • Place of Presentation: 奈良
  • Year and Date: 2007-08-05
• [Presentation] ロジウム触媒を用いるアルキニルアルケニルカルビノール類の不斉転位反応 (2007)
  • Author(s): 西村貴洋、加藤泰祐、高津慶士、新谷 亮、林 民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2007-03-29
• [Presentation] ロジウム触媒を用いたアリールビス(アルキニル)カルビノールの3-アルキニル-1-インダノンへの転位反応 (2007)
  • Author(s): 新谷 亮、高津慶士、加藤泰祐、西村貴洋、林 民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2007-03-28
• [Presentation] 林民生 ロジウム触媒を用いた末端アルキンのアザベンゾノルボルナジエンへの開環を伴う不斉付加反応 (2007)
  • Author(s): 西村貴洋、鶴巻英治、林民生
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-27
• [Presentation] ロジウム触媒を用いる末端アルキンと内部アルキンの共二量化反応 (2007)
  • Author(s): 西村貴洋、大西康平、郭勲祥、林民生
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-27
• [Presentation] ロジウム触媒存在下、第三級アルコールをアリール化剤として用いるα,β-不飽和カルボニル化合物のヒドロアリール化反応 (2007)
  • Author(s): 西村貴洋、加藤泰祐、林民生
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-26
• [Presentation] ロジウム触媒を用いるオキサ-およびアザビシクロアルケンの不斉[3 + 2]環化二量化反応 (2007)
  • Author(s): 西村貴洋、川本教博、佐々木恵吾、鶴巻英治、林民生
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-26
• [Presentation] Rhodium- Catalyzed Asymmetric Addition of Arylboronic Acids to Diphenyl-phosphinylallenes. (2006)
  • Author(s): T. Nishimura, S. Hirabayashi, Y. Yasuhara, T. Hayashi
  • Organizer: The 10th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: Kyoto
  • Year and Date: 2006-11-16
• [Presentation] ロジウムを触媒とするジフェニルホスフィニルアレンの不斉ヒドロアリール化反応 (2006)
  • Author(s): 西村貴洋、平林祥、安原祐一、林民生
  • Organizer: 第53回有機金属化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2006-09-09
• [Presentation] ロジウム触媒を用いるアレニルホスフィンオキシド類のアリールボロン酸による不斉アリール化反応 (2006)
  • Author(s): 西村貴洋、平林 祥、安原祐一、林民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2006-03-29
• [Presentation] ロジウム触媒を用いるアレニルホスフィンオキシド類の不斉アルキニル化反応 (2006)
  • Author(s): 西村貴洋、郭勲祥、林民生
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2006-03-29
• [Presentation] モリブデンを触媒とするシクロプロピル基を有するプロパルギルアルコール類の選択的異性化反応 (2006)
  • Author(s): 芳仲朋亮、西村貴洋、植村榮
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2006-03-29
• [Presentation] Transition Metal- Catalyzed Organic Transformations Involving C-C Bond Cleavage. (2005)
  • Author(s): T. Nishimura.
  • Organizer: 4th Asian-European Symposium
  • Place of Presentation: Nagasaki
  • Year and Date: 2005-11-06