Construction of Nobel Aromatic Acetylene and Advanced Molecular Transformation
Project/Area Number |
17065020
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Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
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Research Institution | Okayama University of Science |
Principal Investigator |
OTERA Junzo Okayama University of Science, 工学部, 教授 (20131617)
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Co-Investigator(Kenkyū-buntansha) |
ORITA Akihiro 岡山理科大学, 工学部, 教授 (30262033)
|
Project Period (FY) |
2005 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
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Budget Amount *help |
¥87,000,000 (Direct Cost: ¥87,000,000)
Fiscal Year 2008: ¥17,400,000 (Direct Cost: ¥17,400,000)
Fiscal Year 2007: ¥17,400,000 (Direct Cost: ¥17,400,000)
Fiscal Year 2006: ¥17,400,000 (Direct Cost: ¥17,400,000)
Fiscal Year 2005: ¥34,800,000 (Direct Cost: ¥34,800,000)
|
Keywords | 芳香族 / アセチレン / 分子変換 / 炭素-炭素結合 / ワンポットプロセス / π-電子 / 二重脱離反応 / スルホン / アルデヒド / 蛍光 / ワンポット |
Research Abstract |
スルホンとアルデヒドに塩基を逐次滴下するワンポット反応を確立し各種芳香族アセチレンを合成した。さらに塩基に工夫を加えることにより、究極のアセチレン合成法を確立した。また、合成されたフェニレンエチニレン化合物が有機材料として有望であることが判明した。
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Report
(6 results)
Research Products
(159 results)
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[Journal Article] Metallocene Bis(perfluoroalkanesulfonate)s as Air-Stable Cationic Lewis Acids2009
Author(s)
Qiu, R.; Zhang, G.; Xu, X.; Zou, K.; Shao, L.; Fang, D.; Li, Y.; Orita, A.; Saijo, R.; Mineyama, H.; Suenobu, T.; Fukuzumi, S.; An, D. -L.; Otera, J.
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Journal Title
J. Organomet. Chem. 694
Pages: 1524-1528
Related Report
Peer Reviewed
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[Journal Article] Synthesis and Spectroscopic Studies of Various Arylene Ethnylene Fluorophores.2007
Author(s)
Shao, G., Orita, A., Nishijima, K., Ishimaru, K., Takezaki, M., Wakamatsu, K., Gleiter, R., Otera, J.
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Journal Title
Chem. Asian J.
Pages: 231-234
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[Journal Article] Organotin perfluorooctanesulfonates as air-stable Lewis acid catalysts. Synthesis, Characterization, and Catalysis2006
Author(s)
An, D.L.; Peng, Z.; Orita, A.; Kurita, A.; Man-e, S.; Ohkubo, K.; Li, X.; Fukuzumi, S.; Otera, J.
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Journal Title
Chem. Eur. J. 12
Pages: 1642-1647
Related Report
Peer Reviewed
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[Journal Article] Organotin perfluorooctanesulfonates as air-stable Lewis acid catalysts. Synthesis, Characterization, and Catalysis2006
Author(s)
An, D. L.; Peng, Z.; Orita, A.; Kurita, A.; Man-e, S.; Ohkubo, K.; Li, X.; Fukuzumi, S.; Otera, J.
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Journal Title
Chem. Eur. J. 12
Pages: 1642-1647
Related Report
Peer Reviewed
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[Journal Article] Organotin perfluorooctanesulfonates as air-stable Lewis acid catalysts. Synthesis, Characterization, and Catalysis.2006
Author(s)
An, D.L., Peng, Z., Orita, A., Kurita, A., Man-e, S., Ohkubo, K., Li, X., Fukuzumi, S., Otera, J.
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Journal Title
Chem. Eur. J. 12
Pages: 1642-1647
Related Report
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[Journal Article] Photoluminescence Enhancement in Tetrakis(arylethnyl)silanes.2006
Author(s)
Shao, G., Orita, A., Nishijima, K., Ishimaru, K., Takezaki, M., Wakamatsu, K., Otera, J.
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Journal Title
Chem. Lett. 35
Pages: 1284-1285
Related Report
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[Journal Article] Optical and Electronic Properties of Bis(4-(phenylethynyl)phenyl)ethynes and Their Applications for Organic Field-effect Transistors.2006
Author(s)
Oyamada, T., Shao, G., Uchiuzou, H., Nakanotani, H., Orita, A., Otera, J., Yahiro, M., Adachi, C.
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Journal Title
Related Report
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[Journal Article] Synthesis and properties of 1, 6, 7, 12, 13, 18, 19, 24-octamethyl acenaphthyleno[b, l]tetraphenylene2005
Author(s)
Elliott, E.L.; Orita, A.; Hasegawa, D.; Gantzel, P.; Otera, J.; Siegel, S.
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Journal Title
Org. Biomol. Chem. 3
Pages: 581-583
Related Report
Peer Reviewed
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[Journal Article] Siegel, S. Synthesis and properties of 1,6,7,12,13,18,19,24-octamethyl acenaphthyleno[b,l]tetraphenylene2005
Author(s)
Elliott, E. L.; Orita, A. ; Hasegawa, D.; Gantzel, P.; Otera, J
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Journal Title
Org. Biomol. Chem 3
Pages: 581-583
Related Report
Peer Reviewed
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[Journal Article] Synthesis and properties of 1,6,7,12,13,18,19,24-octamethyl-dibenzo[def, par]tetraphenylene2005
Author(s)
E.L.Elliott, A.Orita, D.Hasegawa, P.Gantzel, J.Otera, J.S.Siegel
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Journal Title
Org.Biomol.Chem. 3
Pages: 581-583
Related Report
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[Journal Article] Metallocene Bis(perfluoroalkanesulfonate)s as Air-Stablen Cationic Lewis Acids
Author(s)
Qiu, R.; Zhang, G.; Xu, X.; Zou, K.; Shao, L.; Fang, D.; Li, Y.; Orita, A.; Saijo, R.; Mineyama, H.; Suenobu, T.; Fukuzumi, S.;Otera, J
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Journal Title
J. Organomet. Chem. (in press)
Related Report
Peer Reviewed
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[Journal Article] Electrical Properties of 1,4-Bis(4-(phenylethynyl)phenylethynyl)benzene and its Application for Organic Light Emitting Diodes.
Author(s)
Fenenko, L., Shao, G., Orita, A., Yahiro, M., Otera, J., Svechnikov, S.
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Journal Title
Related Report
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[Journal Article] Synthesis and Spectroscopic Studies on Arylethnylsilanes.
Author(s)
Shao, G., Orita, A., Nishijima, K., Ishimaru, K., Takezaki, M., Wakamatsu, K., Gleiter, R., Otera, J.
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Journal Title
Chem. Asian J. (in press)
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