Fabrication and Control of Superhierarchical Structures of Single Crystalline Conjugated Polymers

• Project/Area Number: 17067001
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Yamagata University
• Principal Investigator: OKADA Shuji Yamagata University, 大学院・理工学研究科, 教授 (30250848)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥29,200,000 (Direct Cost: ¥29,200,000); Fiscal Year 2008: ¥7,300,000 (Direct Cost: ¥7,300,000); Fiscal Year 2007: ¥7,300,000 (Direct Cost: ¥7,300,000); Fiscal Year 2006: ¥7,300,000 (Direct Cost: ¥7,300,000); Fiscal Year 2005: ¥7,300,000 (Direct Cost: ¥7,300,000)
• Keywords: 共役ポリマー / ポリジアセチレン / 固相重合 / 単結晶 / ナノ結晶 / 固有重合

Research Abstract

ブタジイン誘導体の固相重合によって得られるポリジアセチレンの光・電子特性向上を目的とした合成的研究では、固相重合性の向上、吸収の長波長化、混晶の作製、モノマーπ共役系中の共役三重結合導入位置の違いによる固相重合部位の制御などに成功した。また、ナノメートルサイズのポリジアセチレン単結晶への官能基の導入に初めて成功し、導入した官能基を手掛かりとして基板上への共有結合による固定化にも成功した。

Research Products

• [Journal Article] Synthesis and Solid-State Polymerization of a Methylene-Chain-Modified Butadiyne Derivative (2009)
  • Author(s): S. Inayama, S. Okada, T. Kimura, S. Shimada, H. Matsuda
  • Journal Title: Synth. Met. 159 Pages: 910-913
  • Peer Reviewed
• [Journal Article] Nanocrystal Fabrication of Acrylic Acid Derivatives with a Long-Alkyl Group and Their Solid-State Polymerization (2008)
  • Author(s): H. Abe, S. Okada, T. Kimura, S. Shimada, H. Matsuda, A. Masuhara, H. Kasai, and H. Oikawa
  • Journal Title: Mol. Cryst. Liq. Cryst. 492 Pages: 70-76
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of Triyne and Enediyne Derivatives with Sililar π-Conjugated Structures (2008)
  • Author(s): K. Mizukoshi, S. Okada, T. Kimura, S. Shimada, and H. Matsuda
  • Journal Title: Bull. Chem. Soc. Jpn. 81 Pages: 1028-1037
  • Peer Reviewed
• [Journal Article] Nanocrystal Fabrication of Acrylic Acid Derivatives with a Long-Alkyl Group and Their Solid-State Polymerization (2008)
  • Author(s): H. Abe
  • Journal Title: Mol. Cryst. Liq. Cryst. 492 Pages: 70-76
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of Triyne and Enediyne Derivati ves with Similar π-Conjugated Structures (2008)
  • Author(s): K. Mizukoshi
  • Journal Title: Bull. Chem. Soc. Jpn. 81・8 Pages: 1028-1037
  • Peer Reviewed
• [Journal Article] Chemical Doping into Nanocrystals of Poly(diacetylene) (2008)
  • Author(s): K. Baba
  • Journal Title: Jpn. J. Appl. Phys. 47・5 Pages: 3769-3771
  • Peer Reviewed
• [Journal Article] Synthesis of Phenylbutadiynylpyridinium Derivatives for Nonlinear Optics (2007)
  • Author(s): S. Kan-no and S. Okada
  • Journal Title: Mol. Cryst. Liq. Cryst. 471 Pages: 365-371
  • Peer Reviewed
• [Journal Article] Synthesis of Phenylbutadiynylpyridinium Derivatives for Nonlinear Optics (2007)
  • Author(s): S., Kan-no
  • Journal Title: Mol.Cryst.Liq.Cryst. 471 Pages: 365-371
  • Peer Reviewed
• [Journal Article] Anisotropic Orientation Control of Nonpolar Organic Nanocrystal Dispersion by External Fields (2007)
  • Author(s): Y., Kaneko
  • Journal Title: Jpn.J.Appl.Phys. 46・10A Pages: 6893-6897
  • Peer Reviewed
• [Journal Article] Diacetylene Nanowire Crystals Prepared by Reprecipitation/Microwave-Irradiation Method (2007)
  • Author(s): K., Baba
  • Journal Title: Jpn.J.Appl.Phys. 46・11 Pages: 7558-7561
  • Peer Reviewed
• [Journal Article] Polymerization of a Butadiyne Derivative in Crystalline State Stimulated by Radical Initiators (2006)
  • Author(s): M. Arai and S. Okada
  • Journal Title: Chem. Lett. 35 Pages: 1012-1013
  • Peer Reviewed
• [Journal Article] Synthesis of Pyridylbutadiyne Derivatives and Improvement of Their Solid-State Polymerizability by Complexation with Alkanoic Acid (2006)
  • Author(s): H. Sato, S. Okada, T. Kimura, S. Shimada, H. Matsuda, and H. Nakanishi
  • Journal Title: Chem. Lett. 35 Pages: 412-413
  • Peer Reviewed
• [Journal Article] Synthesis of Pyridylbutadiyne Derivatives and Improvement of Their Solid-State Polymerizability by Complexation with Alkanoic Acid (2006)
  • Author(s): H.Sato
  • Journal Title: Chem.Lett. 35・4 Pages: 412-413
• [Journal Article] Polymerization of a Butadiyne Derivative in Crystalline State Stimulated by Radical Initiators (2006)
  • Author(s): M.Arai
  • Journal Title: Chem.Lett. 35・9 Pages: 1012-1013
• [Journal Article] Solid-State Polymerization Behavior of 1,3-Bis(3-quinolyl)-1,4-butadiyne (2006)
  • Author(s): T.Li
  • Journal Title: Polym.Bull 57・5 Pages: 737-746
• [Journal Article] Synthesis and Characterization of Monodispersed Polymer/Polydiacetylene Nanocrystals Composite Particles (2005)
  • Author(s): Z.Wei
  • Journal Title: J.Nanosci. Nanotechnol. 5・6 Pages: 937-944
• [Journal Article] Fabrication of Diacetylene Nanofibers and their Dynamic Behavior in the Course of Solid-State Polymerization (2005)
  • Author(s): K.Baba
  • Journal Title: Mol. Cryst. Liq. Cryst. 445 Pages: 161-166
• [Presentation] ヘキサトリイン誘導体とその三重結合の一部を二重結合に置換した誘導体の固相重合 (2008)
  • Author(s): 岡田修司
  • Organizer: 第17回有機結晶シンポジウム
  • Place of Presentation: 大阪大学吹田キャンパス
  • Year and Date: 2008-11-14
• [Presentation] Solid-State Polymerization of Monophenylbutadiyne Derivatives (2008)
  • Author(s): S. Okada
  • Organizer: Korea-Japan Joint Forum 2008
  • Place of Presentation: 千歳科学技術大学
  • Year and Date: 2008-10-25
• [Presentation] Radical-Initiator-Induced Solid-State Polymerization of Butadiyne Nanocrystals in Water and Their Dispersion Stabilization (2008)
  • Author(s): S. Kato, S. Okada, A. Masuhara, H. Kawai, and H. Oikawa
  • Organizer: International Conference on Control of Super-Hierarchical Structures and Innovative Functions of Next-Generation Conjugated Polymers
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2008-10-21
• [Presentation] Synthesis and Solid-State Polymerization of a Methylene-Chain-Modified Butadivne Derivative (2008)
  • Author(s): S. Inayama
  • Organizer: International Conference on Control of Super-Hierarchical Structures and Innovative Functions of Next-Generation Coniugated Polymers
  • Place of Presentation: 淡路夢舞台国際会議場
  • Year and Date: 2008-10-21
• [Presentation] Radical-Initiator-Induced Solid-State Polymerization of Butadiyne Nanocryslals in Water and Their Dispersion Stabilization (2008)
  • Author(s): S. Kato
  • Organizer: International Conference on Control of Super-Hierarchical Structures and Innovative Functions of Next-Generation Conjugated Polymers
  • Place of Presentation: 淡路夢舞台国際会議場
  • Year and Date: 2008-10-21
• [Presentation] Synthesis of Polydiacetylenes Modified by Conjugated Side Chains or End Groups (2008)
  • Author(s): S. Okada
  • Organizer: International Conference on Advanced Functional Polymers and Self-Organized Materials 2008
  • Place of Presentation: Busan, Korea
  • Year and Date: 2008-09-24
• [Presentation] メチレン基の一部を酸素に置き換えたブタジイシ誘導体の合成と固相重合 (2008)
  • Author(s): 稲山智
  • Organizer: 第57回高分子学討論会
  • Place of Presentation: 大阪市立大学杉本キャンパス
  • Year and Date: 2008-09-24
• [Presentation] 両末端にトリアルコキシフェニルウレタン基を有するブタジインの固相重合 (2008)
  • Author(s): 高橋輪太郎
  • Organizer: 第57回高分子学討論会
  • Place of Presentation: 大阪市立大学杉本キャンパス
  • Year and Date: 2008-09-24
• [Presentation] Synthesis of Polydiacetylenes Modified by Conjugated Side Chains or End Groups (2008)
  • Author(s): S. Okada
  • Organizer: International Conference on Advanced Functional Polymers and Self-Omanized Materials 2008
  • Place of Presentation: Busan, Korea
  • Year and Date: 2008-09-24
• [Presentation] Initiator-Induced Solid-State Polymerization of Diacetylene Nanociystals (2008)
  • Author(s): S. Okada
  • Organizer: Symposium on "Organic Micro-and Nano-crystals"
  • Place of Presentation: 東北大学多元物質科学研究所
  • Year and Date: 2008-08-22
• [Presentation] Modification of Polydiacetylenes in Side Chains and Ends (2008)
  • Author(s): S. Okada
  • Organizer: The 5th International Symposium on Advanced Materials in Asia-Pacific Rim
  • Place of Presentation: Zhengzhou, China
  • Year and Date: 2008-08-17
• [Presentation] Synthesis of Polydiacetylene Derivatives with Bathochromic-Shifted Absorption Bands (2008)
  • Author(s): S. Okada, S. Inayama, and K. Mizukoshi
  • Organizer: The International Conference on Science and Technology of Synthetic Metals 2008
  • Place of Presentation: Porto de Galinhas, Brazil
  • Year and Date: 2008-07-07
• [Presentation] ラジカル開始剤を用いたポリジアセチレンナノ結晶の合成と界面活性剤添加効果 (2008)
  • Author(s): 加藤修平
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2008-05-29
• [Presentation] 側鎖構造が異なるヘキサイン誘導体の固相重合性 (2008)
  • Author(s): 稲山智
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2008-05-29
• [Presentation] Synthesis of Hexayne Derivatives and Their Solid-State (2008)
  • Author(s): S, Inayama
  • Organizer: The 8th International Symposium on Advanced Organic Photonics
  • Place of Presentation: 仙台
  • Year and Date: 2008-02-28
• [Presentation] Chemical Doping into Nanocrystals of Polydiacetylene (2008)
  • Author(s): K, Baba
  • Organizer: The 8th International Symposium on Advanced Organic Photonics
  • Place of Presentation: 仙台
  • Year and Date: 2008-02-28
• [Presentation] Nanocrystal Fabrication of Acrylic Acid Derivatives with a Long-Alkyl Group and Their Solid-State Polymerization (2007)
  • Author(s): S. Okada, H. Abe, T. Kimura, S. Shimada, H. Matsuda, A. Masuhara, H. Kasai, and H. Oikawa
  • Organizer: Korea-Japan Joint Forum 2007
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2007-09-27
• [Presentation] Nanocrystal Fabrication of Acrylic Acid Derivatives with a Long-Alkyl Group and Their Solid-State Polymerization (2007)
  • Author(s): S, Okada
  • Organizer: Korea-Japan Joint Forum 2007
  • Place of Presentation: Seoul,Korea
  • Year and Date: 2007-09-27
• [Presentation] 開始剤を用いたナノ結晶固相重合における界面活性剤の影響 (2007)
  • Author(s): 加藤修平
  • Organizer: 平成19年度化学協会東北大会
  • Place of Presentation: 山形
  • Year and Date: 2007-09-23
• [Presentation] フェ二ルブタジイ二ルピリジン誘導体の固相重合配列化の検討 (2007)
  • Author(s): 入江正晃
  • Organizer: 平成19年度化学協会東北大会
  • Place of Presentation: 山形
  • Year and Date: 2007-09-23
• [Presentation] ラジカル開始剤を用いたブタジイン誘導体の固相重合 (2007)
  • Author(s): 岡田修司
  • Organizer: 第56回高分子討諭会
  • Place of Presentation: 名古屋
  • Year and Date: 2007-09-21
• [Presentation] ポリジアセチレン微結晶配向膜における光キャリアダイナミクス (2007)
  • Author(s): 高橋裕
  • Organizer: 第1回分子科学討諭会
  • Place of Presentation: 仙台
  • Year and Date: 2007-09-18
• [Presentation] アクリル酸誘導体ナノ粒子の作製と固相重合4 (2007)
  • Author(s): 阿部仁史
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都
  • Year and Date: 2007-05-31
• [Presentation] フェ二ル置換トリイン・エンジイン誘導体の固相重合 (2007)
  • Author(s): 水越花奈
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都
  • Year and Date: 2007-05-30
• [Presentation] ヘキサイン誘導体の合成と固相重合 (2007)
  • Author(s): 稲山智
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都
  • Year and Date: 2007-05-30
• [Presentation] Synthesis of Polydiacetylene Derivatives with Extended π-Conjugation Systems for Third-Order Nonlinear Optics (2006)
  • Author(s): S. Okada, K. Mizukoshi, and S. Inayama
  • Organizer: The International Conference on Science and Technology of Synthetic Metals 2006
  • Place of Presentation: Dublin, Ireland
  • Year and Date: 2006-07-05
• [Presentation] Synthesis of Polydiacetylenes with Improved Optical Properties (2005)
  • Author(s): S. Okada, H. Kasai, H. Oikawa, H. Matsuda, and H. Nakanishi
  • Organizer: Pacific Polymer Federation IX
  • Place of Presentation: Maui, USA
  • Year and Date: 2005-12-13
• [Book] 次世代共役ポリマーの超階層制御と革新機能, 単結晶状共役ポリマーの超人階層制御の構築と制御 (2009)
  • Author(s): 岡田修司
  • Publisher: シーエムシー
• [Book] 次世代共役ポリマーの超階層制御と革新機能 (2008)
  • Author(s): 岡田修司
  • Publisher: シーエムシー
• [Book] 有機薄膜形成とデバイス応用展開(有機非線形光学材料) (2008)
  • Author(s): 岡田修司
  • Total Pages: 255
  • Publisher: シーエムシー
• [Book] 電子材料ハンドブック(有機非線形光学材料) (2006)
  • Author(s): 岡田修司
  • Total Pages: 1012
  • Publisher: 朝倉書店
• [Book] 有機結晶材料の最新技術, 非線形光学結晶 (2005)
  • Author(s): 岡田修司
  • Publisher: シーエムシー
• [Book] 有機結晶材料の最新技術(第19章 非線形光学結晶) (2005)
  • Author(s): 岡田修司
  • Total Pages: 301
  • Publisher: シーエムシー