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Super-Hierarchical Structures with Novel Functionality

Research Project

Project/Area Number 17067012
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionNara Institute of Science and Technology

Principal Investigator

FUJIKI Michiya  Nara Institute of Science and Technology, 物質創成科学研究科, 教授 (00346313)

Co-Investigator(Kenkyū-buntansha) KWAK Giseop  奈良先端科学技術大学院大学, 物質創成科学研究科, 助手 (70362845)
NAITO Masanobu  奈良先端科学技術大学院大学, 物質創成科学研究科, 助教授 (30346316)
ONOUCHI Hisanari  奈良先端科学技術大学院大学, 物質創成科学研究科, 助教授 (40418736)
Project Period (FY) 2005 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥34,200,000 (Direct Cost: ¥34,200,000)
Fiscal Year 2008: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 2007: ¥9,000,000 (Direct Cost: ¥9,000,000)
Fiscal Year 2006: ¥9,000,000 (Direct Cost: ¥9,000,000)
Fiscal Year 2005: ¥8,200,000 (Direct Cost: ¥8,200,000)
Keywordsナノ材料 / 光物性 / 複合材料・物性 / 共役高分子 / セラミックス / 電子機能
Research Abstract

シグマ共役高分子・パイ共役高分子の超階層構造化と革新機能化へ向け、(1)階層的高分子場による弱い相互作用の検出・増幅・固定、(2)特異なトポロジー構造制御と物性・機能相関解明、(3)弱い相互作用によって構築されたポリシランから発光性シリコンセラミック変換の可能性を明らかにすした。非古典的な弱い相互作用をシグマ共役・パイ共役高分子材料システム構築の設計概念に予めプログラムすると、高分子、金属、セラミクスそれぞれ単独では実現が困難であった、分子情報→分子情報変換(発生、転写、増幅、記録、反転、消去)、分子情報→電磁場変換(分子→光・電子・熱)、ケイ素高分子→セラミックス物質変換できる可能性を示した。具体的には、1.CH/π相互作用による発光性高分子複合体の設計と発光イメージング(薄膜・ファイバー化)、強誘電性非発光性高分子/蛍光分子、発光性高分子/蛍光分子、発光性高分子/発光性高分子などの複合膜を作製し、誘電率の温度変化と発光スペクトル挙動・発光分子構造・配向構造相関を解明し、感熱性多色発光機能薄膜、蛍光イメージング薄膜・多孔質電界紡糸ファイバーへ発展できた。2.弱いCH/Si 間相互作用による発光性シリコン超階層構造体可溶性2次元有機ケイ素高分子(ポリシリン)のCH/Si 相互作用とSi-C 結合の熱解裂反応の精密制御により2~3次元的階層構造を持つ可視-近赤外域で発光する新規シリコン材料の創成に成功した。このように、弱い相互作用をキー概念として材料設計した高分子階層構造体が発光波長や強度変調などの機能を有することが明らかになった。これらの成果はACSのHeartCutとしての研究ハイライト、Elsevier のNanoTodayのトピックス紹介、Macromol. Rapid Commun.の表紙に掲載されるなどの対外的評価を得た。
シグマ共役高分子・パイ共役高分子の超階層構造化と革新機能化へ向け、(1)階層的高分子場による弱い相互作用の検出・増幅・固定、(2)特異なトポロジー構造制御と物性・機能相関解明、(3)弱い相互作用によって構築されたポリシランから発光性シリコンセラミック変換の可能性を明らかにすした。非古典的な弱い相互作用をシグマ共役・パイ共役高分子材料システム構築の設計概念に予めプログラムすると、高分子、金属、セラミクスそれぞれ単独では実現が困難であった、分子情報→分子情報変換(発生、転写、増幅、記録、反転、消去)、分子情報→電磁場変換(分子→光・電子・熱)、ケイ素高分子→セラミックス物質変換できる可能性を示した。具体的には、1.CH/π相互作用による発光性高分子複合体の設計と発光イメージング(薄膜・ファイバー化)、強誘電性非発光性高分子/蛍光分子、発光性高分子/蛍光分子、発光性高分子/発光性高分子などの複合膜を作製し、誘電率の温度変化と発光スペクトル挙動・発光分子構造・配向構造相関を解明し、感熱性多色発光機能薄膜、蛍光イメージング薄膜・多孔質電界紡糸ファイバーへ発展できた。2.弱いCH/Si 間相互作用による発光性シリコン超階層構造体可溶性2次元有機ケイ素高分子(ポリシリン)のCH/Si 相互作用とSi-C 結合の熱解裂反応の精密制御により2~3次元的階層構造を持つ可視-近赤外域で発光する新規シリコン材料の創成に成功した。このように、弱い相互作用をキー概念として材料設計した高分子階層構造体が発光波長や強度変調などの機能を有することが明らかになった。これらの成果はACSのHeartCutとしての研究ハイライト、Elsevier のNanoTodayのトピックス紹介、Macromol. Rapid Commun.の表紙に掲載されるなどの対外的評価を得た。

Report

(5 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (86 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (39 results) (of which Peer Reviewed: 26 results) Presentation (30 results) Book (12 results) Remarks (4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Chemical Degelation of Polysilane Organogel by Selective Scission of Silicon Main Chain by Fluoride Anion2009

    • Author(s)
      M. Naito, T. Kawabe, M. Nakamura, K. Wakayama, W. Chung, K. Yasui, M. Fujiki
    • Journal Title

      Chem. Lett.

      Pages: 414-415

    • NAID

      10025121508

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] doi:10.1016/j.synthmet.2009

    • Author(s)
      M. Naito, M. Nakamura, T. Kawabe, W. Chung, M. Fujiki
    • Journal Title

      Synth. Met.

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Phthalocyanine Ultrathin film via Layer-by-Layer Assembly2009

    • Author(s)
      C. Woojung, M. Naito, R. Fujii, M. Morisue, M. Fujiki
    • Journal Title

      Thin Solid Film (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Full-Visible- Spectrum Emitters from Pyrolysis of Soluble Si-Si Bonded Network Polymers2009

    • Author(s)
      M. Fujiki, Y. Kawamoto, M. Kato, Y. Fujimoto, T. Saito, S. Hososhima, G. Kwak
    • Journal Title

      Chem. Mater. (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of phthalocyanine ultrathin film via layer-by-layer assembly2009

    • Author(s)
      W. Chung
    • Journal Title

      Thin Solid Films (In press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly(fluoroalkylsilane-b-dialkylsilane)-basedchemosensorymaterialforfluoride withhighsensitivity, selectivity and solubility2009

    • Author(s)
      M. Naito
    • Journal Title

      Synthetic Metals (In press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Degelation of Polysilane Organogel by Selective Scission of Silicon Main Chain by Fluoride Anion2009

    • Author(s)
      M. Naito
    • Journal Title

      Chemistry Letters

      Pages: 414-415

    • NAID

      10025121508

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polysilanes on surfaces2008

    • Author(s)
      M. Naito, M. Fujiki
    • Journal Title

      Soft Matter 4

      Pages: 211-223

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-classical Forces : Seemingly Insignificant But a Powerful Tool to Control Macromolecular Structures2008

    • Author(s)
      M. Fujiki, A. Saxena
    • Journal Title

      J. Polym. Sci. A : Polym. Chem. 46

      Pages: 4637-4650

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stiffness- and Conformation- Dependent Polymer Wrapping onto Single-Walled Carbon Nanotubes2008

    • Author(s)
      M. Naito. M. Fujiki
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 16697-16703

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Polar Laser Dyes Dispersed in Polymer Matrices: Reverification of Charge Transfer Character and New Optical Functions2008

    • Author(s)
      G. Kwak, C. Okada, M. Fujiki, H. Takeda, T. Nishida, T. Shiosaki
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 1753-1756

    • NAID

      40015945483

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Polysilane Organogel via Hierarchically Amplified Weak Intra-/Inter-chain Si/FC and van der Waals Interactions2008

    • Author(s)
      T. Kawabe, M. Naito, M. Fujiki
    • Journal Title

      Polym. J. 40

      Pages: 317-326

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multiblock Polysilane Copolymers : One-Pot Wurtz Synthesis, Fluoride Anion-Induced Block- Selective Scission Experiments, and Spectro-scopic Characterization2008

    • Author(s)
      T. Kawabe, M. Naito, M. Fujiki
    • Journal Title

      Macromolecules 41

      Pages: 1952-1960

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Polyfluorene, Nano- rings and Nano-dots on Mica Surfaces : Evaporation Induced Polymer SelfAssembly and Photoluminescence Properties of The Assemblies2008

    • Author(s)
      Y, Liu, M. Takanori, Y. Nakano, M. Naito, M. Fujiki
    • Journal Title

      Soft Matter 4

      Pages: 2396-2401

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stiffness- and Conformation-Dependent Polymer Wrapping onto Single-Walled Carbon Nanotubes2008

    • Author(s)
      Naito. M
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 16697-16703

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polyfluorene nano-rings and nano-dots on mica surfaces : evaporation-inducedpolymer self-assembly and photoluminescence properties of the assemblies2008

    • Author(s)
      Liu Y
    • Journal Title

      Soft Matter 4

      Pages: 2396-2401

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stiffness- and Conformation-Dependent Polymer Wrapping onto Single-Walled Carbon Nanotubes2008

    • Author(s)
      Naito, M
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 16697-16703

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polyfluorene nano-rings and nano-dots on mica surfaces : evaporation-induced polymer self-assembly and photoluminescence properties of the assemblies2008

    • Author(s)
      Liu Y
    • Journal Title

      Journal of Polymer Science, Part A : Polymer Chemistry 46

      Pages: 4637-4650

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Organized Phthalocyanine Assembly onto Gold Surface : through Spontaneous Polymerization2007

    • Author(s)
      M. Ishikawa, M. Naito, M. Fujiki
    • Journal Title

      Chem. Lett. 36

      Pages: 304-305

    • NAID

      10018522962

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Circularly Polarized Luminescence of a Fluorescent Chiral Binaphtyleneperylene- biscarboxy diimide Dimer2007

    • Author(s)
      T. Kawai, K. Kawamura, H. Tsumatori, M. Ishikawa, M. Naito, M. Fujiki, T. Nakashima
    • Journal Title

      Chem Phys Chem. 8

      Pages: 1465-1468

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrahigh Molecular Weight Poly(dipheny-lacetylene) bearing n-Octadecylsilylene Moiety : Smectic Liquid Crystallinity and Unexpected Inversed Optical Anisotropy2007

    • Author(s)
      G. Kwak, M. Minakuchi, T. Sakaguchi, T. Masuda, M. Fujiki
    • Journal Title

      Chem. Mater. 19

      Pages: 3654-3661

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Weak Non-covalent Si/F-C Interactions Stabilized Fluoroalkylated Rod-like Polysilanes As Ultrasensitive Chemosensors2006

    • Author(s)
      A. Saxena, R. Rai, S. -Y. Kim, M. Fujiki, M. Naito, K. Okoshi, G. Kwak
    • Journal Title

      J. Polym. Sci : Part A : Polym. Chem. 44

      Pages: 5060-5075

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanoporous, Honeycom-structured Network Fibers Spun from Semi-flexible, Ultrahigh-Molecular Weight, Di-substituted Aromatic Polyacetylenes : Super-hierarchical Structure and Unique Optical Anisotrop2006

    • Author(s)
      G. Kwak, S. Fukao, M. Fujiki, T. Sakaguchi, T. Masuda
    • Journal Title

      Chem. Mater. 18

      Pages: 5537-5542

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mono- and Multicolor FL Image Patterning Based on Highly Luminous Diphenyl-acetylene Polymer Derivative by Facile Photobleaching2006

    • Author(s)
      G. Kwak, M. Fujiki, T. Sakaguchi, T. Masuda
    • Journal Title

      Macromolecules 39

      Pages: 319-323

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-Dependent, Static and Dynamic Fluorescence Properties of Disubstituted Acetylene Polymer Films2006

    • Author(s)
      G. Kwak, S. Fukao, M. Fujiki, T. Sakaguchi, T. Masuda
    • Journal Title

      Chem. Mater. 18

      Pages: 2081-2085

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Switching in Molecular Shapes: Main Chain Length Driven Rod-Circle Transition of Isolated Helical Polysilane2006

    • Author(s)
      A. Ohira, S.-Y. Kim, M. Fujiki, Y. Kawakami, M. Naito, G. Kwak, A. Saxena
    • Journal Title

      Chem. Commun.

      Pages: 2705-2707

    • NAID

      120005716817

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Polyacetylene Intermediate Bearing Reactive Benzylidene Malonate : Helix Induction, Inversion, and Recovery by Tandem Michael and Amidation Reactions with Chiral Nucleophiles and Water2006

    • Author(s)
      Giseop Kwak et al.
    • Journal Title

      Polym. J. 38

      Pages: 976-982

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Weak Noncovalent Si/F-C Interactions Stabilized Fluoroalkylated Rod-like Polysilanes As Ultrasensitive Chemosensors2006

    • Author(s)
      Anubhav Saxena et al.
    • Journal Title

      J. Polym. Sci : Part A : Polym. Chem. 44

      Pages: 5060-5075

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Switching in Molecular Shapes : Main Chain Length Driven Rod Circle Transition of Isolated Helical Polysilane2006

    • Author(s)
      Akihiro Ohira et al.
    • Journal Title

      Chem. Commun. 2006

      Pages: 2705-2707

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Temperature-Dependent, Static and Dynamic Fluorescence Properties of Disubstituted Acetylene Polymer Films2006

    • Author(s)
      Giseop Kwak et al.
    • Journal Title

      Chem. Mater. 18

      Pages: 2081-2085

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Mono- and Multicolor FL Image Patterning Based on Highly Luminous Diphenylacetylene Polymer Derivative by Facile Photobleaching2006

    • Author(s)
      Giseop Kwak et al.
    • Journal Title

      Macromolecules 39

      Pages: 319-323

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Energy Transfer from Locally Excited pai^* to Charge Transfer Ground States in a Silylene-pai Hetero-junction Polymer2006

    • Author(s)
      Giseop Kwak et al.
    • Journal Title

      Macromol. Rapid Commun. 27

      Pages: 1561-1564

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Nanoporous, Honeycom-structured Network Fibers Spun from Semi-flexible, Ultrahigh-Molecular Weight, Di-substituted Aromatic Polyacetylenes : Super-hierarchical Structure and Unique Optical Anisotropy2006

    • Author(s)
      Giseop Kwak et al.
    • Journal Title

      Chem. Mater. 18

      Pages: 5537-5542

    • Related Report
      2006 Annual Research Report
  • [Journal Article] ポリマーマトリックスにおける分子内電荷移動型色素の光物性と新奇機能の発現2006

    • Author(s)
      郭起燮 ら
    • Journal Title

      高分子加工 55(4)

      Pages: 8-13

    • NAID

      40007271821

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Mono- and Multicolor FL Image Patterning Based on Highly Luminous Diphenyl acetylene Polymer Derivative by Facile Photobleaching2006

    • Author(s)
      G.Kwak, M.Fujiki, T.Sakaguchi, T.Masuda
    • Journal Title

      Macromolecule 39

      Pages: 319-323

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Temperature-Dependent, Static and Dynamic Fluorescence Properties of Disubstituted Acetylene Polymer Films2006

    • Author(s)
      G.Kwak, M.Fujiki, T.Sakaguchi, T.Masuda
    • Journal Title

      Chem. Mater. 18(in press)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] ポリマーマトリックスにおける分子内電荷移動型色素の光物性と新奇機能の発現2006

    • Author(s)
      郭 起燮, 藤木道也
    • Journal Title

      高分子加工 55(4)(in press)

    • NAID

      40007271821

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Polysilanes on surfaces

    • Author(s)
      Masanobu Naito, Michiya Fujiki
    • Journal Title

      Soft Matter

    • Related Report
      2007 Annual Research Report
  • [Journal Article] Circularly Polarized Luminescence of a Fluorescent Chiral Binaphtyleneperylene- biscarboxy diimide Dimer

    • Author(s)
      Tsuyoshi Kawai, et. al.
    • Journal Title

      ChemPhysChem.

    • Related Report
      2007 Annual Research Report
  • [Presentation] 弱いSi/FC相互作用を利用したポリシランオルガノゲルの創成2008

    • Author(s)
      川部琢磨, 内藤呂信, 藤木道也
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Preparation and Chiroptical Properties of a Silicon Network Polymer with a Chiral Alkyl Group2008

    • Author(s)
      S. Fukao, M. Fujiki
    • Organizer
      IUPAC MACRO
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Self-Assembly-Assisted Spontaneous Polymerization of Soluble Silicon Phthalocyanine on Gold Surface2008

    • Author(s)
      M. Naito, M. Ishikawa, H. Onouchi, M. Fujiki
    • Organizer
      18th Iketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Generation and Switching of p-Conjugating Polymer Chirality in Organocoacervate2008

    • Author(s)
      Y. Nakano, Y. Liu, M. Fujiki
    • Organizer
      18th Iketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation and Supramolecular Structures of Soluble Cu (II) Phthalocyanines with Chiral Amide Groups2008

    • Author(s)
      H. Onouchi, A. Ishimaru, M. Naito, M. Fujiki
    • Organizer
      18th Iketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation and Self-assembled Structures of Phthalocyanines Bearing rialkoxylpenyl Pendants Through an Amide Linkage2008

    • Author(s)
      K. Nakamura, H. Onouchi, M. Naito, M. Fujiki, K. Ohta
    • Organizer
      18th Iketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Poly(fluoroalkylsilane)-based Chemosensor for Fluorine Anion2008

    • Author(s)
      M. Nakamura, M. Naito, T. Kawabe, H. Onouchi, A. Saxena, M. Fujiki
    • Organizer
      18th Iketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Preparation of Semiconducting Polysiloxane- phthalocyanine Ultrathin film via Layer-by-Layer Deposition2008

    • Author(s)
      C. Woojung, M. Naito, R. Fujii, M. Fujiki, M. Morisue
    • Organizer
      8th International Conference on Nano-Molecular Electronics (ICNME 2008)
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Generation and Switching of p-Conjugating Polymer Chirality in Organocoacervate2008

    • Author(s)
      Y. Nakano, Y. Liu, M. Fujiki
    • Organizer
      18th lketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation and Supramolecular Structures of Soluble Cu(II) Phthalocyanines with Chiral Amide Groups2008

    • Author(s)
      H. Onouchi, A. Ishimaru, M. Naito, M. Fujiki
    • Organizer
      18th Iketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation and Self-assembled Structures of Phthalocyanines Bearing rialkoxylpenyl Pendants Through an Amide Linkage2008

    • Author(s)
      K. Nakamura, H. Onouchi, M. Naito, M. Fujiki, K. Ohta
    • Organizer
      18th lketani Conference
    • Place of Presentation
      Awajishima, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation of Semiconducting Polysiloxane-phthalocyanine Ultrathin film viaLayer-by-Layer Deposition2008

    • Author(s)
      C. Woojung, M. Naito, R. Fujii, M. Fujiki, M. Morisue
    • Organizer
      8th International Conference on Nano-Molecular Electronics (ICNME 2008)
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Screw-Sense Switchable Quasi-One-Dimensional Silicon Wire with Quantized and Superposed Helicities2007

    • Author(s)
      Michiya Fujiki
    • Organizer
      The 2nd International Workshop onSuper-Hierarchical Structures
    • Place of Presentation
      Osaka
    • Year and Date
      2007-09-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] 超階層量子効果と14族半導体高分子(4);Wurtz法によるσ共役ポリスタナンの合成と光学特性2007

    • Author(s)
      秋月佑介, 川部琢磨, 藤木道也
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名工大
    • Year and Date
      2007-09-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] 超階層量子効果と14族半導体高分子(5)可溶性シリコンナノシートの特異な光学特性2007

    • Author(s)
      斉藤知来, 藤木道也
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名工大
    • Year and Date
      2007-09-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] 弱い相互作用による光学活性高分子の設計と構築(2):低分子キラリティー転写による光学活性ポリフルオレン超分子の構築と光学活性制御2007

    • Author(s)
      中野陽子, 劉揚, 藤木道也
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名工大
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] σ共役シリコンネットワークポリマーの合成と置換基効果2007

    • Author(s)
      斉藤知来, 尾之内久成, 内藤昌信, 藤木道也
    • Organizer
      第53回高分子研究発表会
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      2007-07-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 巨大環状共役高分子(3):直径100nmサークル構造形成と光学特性2007

    • Author(s)
      劉揚, 村尾貴憲, 中野陽子, 内藤昌信, 藤木道也
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] オルガノゲル形成能を有するフッ化アルキルポリシランマルチブロックコポリマー:分子内・分子間Si/FC,CHIFC相互作用の重要性とらせん超階層構造2007

    • Author(s)
      川部琢磨, 内藤昌信, 藤木道也
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 1段階Wurtz型反応によるマルチブロック型ポリシラン:TBAFを用いたブロック選択的切断法による平均ブロック長の決定2007

    • Author(s)
      川部琢磨, 内藤昌信, 藤木道也
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 可溶性フッ化アルミニウムフタロシアニンによる超分子化・高分子化2007

    • Author(s)
      越智 謙次, 藤木 道也, 石川 正明, 内藤 昌信, 尾之内 久成
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Chiroptical Inversion of Polythiophene Co-aggregates with Chiral and Achiral Side Chains2007

    • Author(s)
      Hisanari Onouchi, Kazuhiro Tanaka, Masanobu Naito, Michiya Fujiki
    • Organizer
      Pre-ISNAl2 in Nara
    • Place of Presentation
      Nara, Ikoma
    • Year and Date
      2007-02-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] Optically Active Silicon Network Polymer with Chiral Alkyl Side Group2007

    • Author(s)
      Satoshi Fukao, Tomoki Saito, Michiya Fujiki
    • Organizer
      Pre-ISNAl2 in Nara
    • Place of Presentation
      Nara, Ikoma
    • Year and Date
      2007-02-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] Circularly Polarized Light from Polyfluorene Stacks Induced by Limonenes2007

    • Author(s)
      Yoko Nakano, Yang Liu, Michiya Fujiki
    • Organizer
      Pre-ISNAl2 in Nara
    • Place of Presentation
      Nara, Ikoma
    • Year and Date
      2007-02-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] Fluoroalkylated Polysilane with Multi-block Sequences and Organogel Forming Ability2007

    • Author(s)
      Takuma Kawabe, Masanobu Naito, Michiya Fujiki
    • Organizer
      Pre-ISNAl2 in Nara
    • Place of Presentation
      Nara, Ikoma
    • Year and Date
      2007-02-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] Polythiophene Co-aggregates with Chiral and Achiral Side Groups: Chiroptical Amplification and Inversion Phenomena2007

    • Author(s)
      Hisanari Onouchi, Kazuhiro Tanaka, Masanobu Naito, Michiya Fujiki
    • Organizer
      Pre-ISNAl2 in Nara
    • Place of Presentation
      Nara, Ikoma
    • Year and Date
      2007-02-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] Preparation and Optical Properties of Silicon Network Polymer with Chiral Alkyl Side Group2007

    • Author(s)
      Satoshi Fukao, Michiya Fujiki
    • Organizer
      10thPacific Polymer Conference
    • Place of Presentation
      Kobe
    • Related Report
      2007 Annual Research Report
  • [Presentation] Chiroptical Generation of Polysilane Induced by Stirred Solutions2007

    • Author(s)
      Yasuko Nakamura, Yoko Nakano, Michiya Fujiki
    • Organizer
      ASiS-1 (1st Asian Silicon Symposium)
    • Place of Presentation
      Zao, Miyagi
    • Related Report
      2007 Annual Research Report
  • [Presentation] Switching in Photoluminescence Properties of Polysilane, Polygermane and Polystannane2007

    • Author(s)
      Yusuke Akizuki, Michiya Fujiki
    • Organizer
      ASiS-1 (1st Asian Silicon Symposium)
    • Place of Presentation
      Zao, Miyagi
    • Related Report
      2007 Annual Research Report
  • [Presentation] Chiroptical Inversion of Polythiophene Co-aggregates with Chiral and Achiral Side Chains2007

    • Author(s)
      Hisanari Onouchi, Kazuhiro Tanaka, Masanobu Naito, Michiya Fujiki
    • Organizer
      INTERNATIONAL CONFERENCE: Chirality at the Nanoscale
    • Place of Presentation
      Calipolis Hotel Sitges, Barcelona
    • Related Report
      2007 Annual Research Report
  • [Book] 第IV編 : 第1章 : 弱い相互作用による超構造の設計と超機能化 「次世代共役ポリマーの超階層制御と革新機能」2009

    • Author(s)
      藤木道也
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] Fluoroalkylated Rod-like Polysilanes : From Cooperative Weak Noncovalent Si/F-C Interactions to Ultra sensitive Chemosensors : Bottom-up Nanofabrication2009

    • Author(s)
      A. Saxena, R. Rai, S. -Y. Kim, M. Fujiki, M. Naito, K. Okoshi
    • Publisher
      American Scientific Publishers
    • Related Report
      2008 Final Research Report
  • [Book] 第IV編 : 第1章 : 弱い相互作用による超構造の設計と超機能化「次世代共役ポリマーの超階層制御と革新機能」2009

    • Author(s)
      藤木道也
    • Total Pages
      500
    • Publisher
      シーエムシー出版(東京)
    • Related Report
      2008 Annual Research Report
  • [Book] Fluoroalkylated Rod-like Polysilanes : From Cooperative Weak Noncovalent Si/F-CInteract ions to Ultra sensitive Chemosensors : Bottom-up Nanofabrication (Volume 2 Chapter 14, p.353-372)2009

    • Author(s)
      A. Saxena, R. Rai, S.-Y. Kim, M. Fujiki, M. Naito, K. Okoshi
    • Total Pages
      500
    • Publisher
      American Scientific Publishers
    • Related Report
      2008 Annual Research Report
  • [Book] Helix Generation, Amplification, Switching, and Memory of Chromophoric Polymers (Soai, K., Ed., Amplification of Chirality)2008

    • Author(s)
      M. Fujiki
    • Publisher
      Springer
    • Related Report
      2008 Final Research Report
  • [Book] 分子認識と超分子 (早下隆士, 築部浩編著)2008

    • Author(s)
      藤木道也, 尾之内久成
    • Publisher
      三共出版
    • Related Report
      2008 Final Research Report
  • [Book] Helix Generation, Amplification, Switching, and Memory of Chromophoric Polymers(Soai. K., Ed. Amplification of Chirality)2008

    • Author(s)
      M. Fujiki
    • Total Pages
      500
    • Publisher
      Springer
    • Related Report
      2008 Annual Research Report
  • [Book] 分担執筆4章:高分子化学と分子認識, 早下隆士、築部浩編著, "分子認識と超分子"2007

    • Author(s)
      尾之内久成, 藤木道也
    • Total Pages
      16
    • Publisher
      三共出版(東京)
    • Related Report
      2007 Annual Research Report
  • [Book] 分担執筆:ポリシラン, 下村政嗣・山口智彦監修"自己組織化ナノマテリアル2007

    • Author(s)
      藤木道也, 内藤昌信
    • Total Pages
      4
    • Publisher
      フロンティア出版(東京)
    • Related Report
      2007 Annual Research Report
  • [Book] Fluoroalkylated Rod-like Polysilanes: From Cooperative Weak Noncovalent Si/F-C Interactions to Ultrasensitive Chemosensors, Katsuhiko Ariga and H. S. Nalwa (Eds) Bottom-up Nano-fabrication: Supramolecules, Self-Assemblies, and Organized Films (ISBN: 1-58883-079-9)2007

    • Author(s)
      Anubhav Saxena, Roopali Rai, Sun-Young Kim, Michiya Fujiki, Masanobu Naito, Kento Okoshi
    • Total Pages
      16
    • Publisher
      American Scientific Publishers, 25650 North Lewis Way, Stevenson Ranch, California 91381-1439, USA)
    • Related Report
      2007 Annual Research Report
  • [Book] 分担執筆 : "機能性ポリシランを用いた分子ワイヤ"、"進化する有機半導体 : 「有機エレクトロニクス創成に向けた光・電子デバイスへの応用技術開発の最先端」2006

    • Author(s)
      藤木道也
    • Publisher
      エヌ・ティー・エス(東京)
    • Related Report
      2006 Annual Research Report
  • [Book] 下村政嗣, 山口智彦 監修"自己組織化ナノマテリアル"2006

    • Author(s)
      藤木道也, 内藤昌信
    • Publisher
      フロンティア出版(印刷中)
    • Related Report
      2005 Annual Research Report
  • [Remarks]

    • URL

      http://mswebs.naist.jp/LABs/fujiki/fujiki/

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://mswebs.naist.jp/LABs/fujiki/fujiki/researchreport.html

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://mswebs.naist.ip/LABs/fujiki/fuiiki/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://mswebs.naist.ip/LABs/fuiiki/fuiiki/researchreport.html

    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 蛍光色変換性組成物、該組織物を使用した蛍光色変換方法およびデバイス2005

    • Inventor(s)
      藤木, 郭, 岡田
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学
    • Industrial Property Number
      2005-131793
    • Filing Date
      2005-05-09
    • Related Report
      2005 Annual Research Report

URL: 

Published: 2005-04-01   Modified: 2018-03-28  

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